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MSDS Material Safety Data Sheet
CAS

69991-67-9

File Name: lesker_com---fomblin25-6rp_5-20-05.asp
Page 1                                          Fomblin YL-VAC 25/6 RP                 MATERIAL SAFETY DATA SHEET


Fomblin YL-VAC 25/6 RP
Kurt J. Lesker Company
1925 Worthington Ave.,
Clairton, PA 15025
412.387.9200


Section 1 - Chemical product and Company information
Date Prepared: May 20, 2005
Product Name: Fomblin YL-VAC 25/6 RP
Chemical Name: Mixture of (S) parafluoropropene and oxygen polymerized, amide derivative and
Propene, 1,1,2,3,3,3-hexafluoro, oxidized, polymerized
Chemical Family: Fluoropolymer
Synonyms: None
Emergency Telephone: 800-424-9300 (CHEMTREC, 24 hours)
856-853-8119

Emergency Overview:
Clear, colorless liquid. Thermal decomposition will generate hydrogen fluoride (HF), which is corrosive.


Section 2 - Compositional information
Name: CAS# Approximate Weight (% wt.):
(S) parafluoropropene and Not assigned Proprietary
oxygen polymerized, amide
derivative

Propene, 1,1,2,3,3,3-hexa- 69991-67-9 Proprietary
fluoro, oxidized, polymerized


Section 3 - Potential Health Effects
Effects of Overexposure:
Eye Contact
Eye contact may cause slight irritation.

Skin Contact
Skin contact may cause slight irritation.

Inhalation
Inhalation of vapors or mists may cause irritation of the mucous membranes and respiratory tract.

Ingestion
Not an expected exposure route. Ingestion may cause nausea and vomiting.


Section 4 - First Aid Measures
Eye Contact:
Flush eyes for 15 minutes with copious amounts of water, retracting eyelids often. Seek medical attention if irritation
persists.

Skin Contact:
Wash skin thoroughly with mild soap and water. Flush with lukewarm water for 15 minutes. Seek medical attention if
irritation persists.

Inhalation:
If symptoms of irritation or discomfort are experienced, or person is overcome by exposure, remove to fresh air. Give
oxygen or artificial respiration as needed.
Page 2 Fomblin YL-VAC 25/6 RP MATERIAL SAFETY DATA SHEET

Ingestion:
If conscious, drink three to four 8 ounce glasses of water or milk. Call a physician. If unconscious, immediately take
affected person to a hospital. Do not give anything by mouth to an unconscious person.


Section 5 - Fire Fighting Measures
Flash Point: Not Applicable
Lower Explosive Limit: Not Applicable
Upper Explosive Limit: Not Applicable
Autoignition Temperature: Not Applicable
Extinguishing Media: Water (spray or fog), foam, dry chemical or carbon dioxide (CO2).

Unusual Fire Hazards:
Fluoropolymers will degrade upon prolonged heating or in a fire, liberating hydrogen fluoride (HF) and carbonyl fluoride
(COF2). This gas is toxic if inhaled or it comes into contact with moist skin. HF has an ACGIH PEL TLV (8hr TWA)
of 0.5ppm and a ceiling limit of 2 ppm (1.7mg/m3). COF2 has an ACGIH TLV of 2 ppm (5.4 mg/m3) and an OSHA PEL
TWA of 2 ppm (5 mg/m3).

Fire Fighting Procedures:
Use self contained breathing apparatus (SCBA) and skin protection for acid gas exposure. Do not enter fire area without
proper protection. Fight fire from safe distance. If possible, air monitoring should be performed.


Section 6 - Accidental Release Measures
Releases: In case of a release or spill, absorb material onto vermiculite or similar inert absorbent. Use
Perfluorosolv0 PFS-1 Solvent to clean up any remaining liquid. Place spilled material into covered container for
disposal. Dispose of according to applicable local, state and federal regulations. Extinguish all ignition sources and
evacuate the area. Exercise caution; spill area may be slippery.


Section 7 - Handling and Storage
Wash hands after use and before handling food or applying cosmetics. Do not use tobacco products in the immediate
area. Keep containers closed. Keep away from heat, sparks and flames. Do not store near combustible materials.


Section 8 - Exposure Controls/Personal Protection
ACGIH Threshold Limit Value (8 hr. time weighted average)
None established

OSHA Permissible Exposure Limit (8 hr. time weighted average)
None established

Engineering Controls:
Ventilation Requirements:
Local Exhaust: Vent vapors or mists generated by processing away from operating personnel. Local exhaust ventilation
at a rate of 50 feet per minute.

Personal Protective Equipment:
Respiratory Protection:
No occupational exposure standards have been developed for this material. In situations where exposure to vapors or
mists is likely, NIOSH/MSHA approved acid and organic vapor respirators are recommended. Respirator use limitations
made by NIOSH/MSHA or the manufacturer must be observed. Respiratory protection programs must be in accordance
with 29 CFR 1910.134.

Eye/Face Protection:
ANSI Z87.1 approved safety glasses with side shields or equivalent, safety goggles.

Skin Protection:
Rubber or latex gloves recommended but not necessary.
Page 3 Fomblin YL-VAC 25/6 RP MATERIAL SAFETY DATA SHEET


Section 9 - Physical and Chemical Properties
Appearance: Clear Liquid
Color: Colorless
Odor: Odorless
Vapor Pressure: Not available
Vapor Density (Air=1): Not available
Boiling Point: Not available
Melting Point: Not available
Specific Gravity: Not available
Solubility in Water: Insoluble


Section 10 - Stability and Reactivity
Stability:
This material is stable.

Reactivity:
This material is not reactive.

Conditions to Avoid:
Heat, sparks, flames, and other ignition sources; avoid heating above 250o C/482 F.

Incompatibility/Materials to Avoid:
Strong alkaline compounds (alkaline hydroxides, ammonia, non-aqueous alkalis), halogenated compounds, Lewis acids
(AlCl3, SbF5, C F3), magnesium, aluminum and their alloys above 100 C/212 F.

Hazardous Decomposition Products:
Thermal decomposition of this product will generate hydrogen fluoride (HF), which is corrosive, causing burns on
contact with skin and other tissue.


Section 11 - Toxicological Information
Toxicology data listed are for propene, 1,1,2,3,3,3-hexafluoro, oxidized, polymerized:
Rat oral LD50: greater than 25.65 g/kg
Rat intraperitoneal LD50: greater than 25 g/kg
Rat dermal LD50: greater than 2 g/kg
Rabbit skin irritation: not irritating
Rabbit eye irritation: not irritating
Guinea pig sensitization: not a sensitizer


Section 12 - Ecological Information
No ecological information is available for this material.


Section 13 - Disposal Considerations
Waste Disposal: Material, as supplied, is not a hazardous waste. Incinerate in a high-temperature incinerator designed to
burn fluorine-containing materials, according to current federal, state and local regulations. Processing, use or
contamination may make this information inaccurate or incomplete.


SECTION 14 - Transportation information
Shipping Class: Not regulated by DOT.
Page 4 Fomblin YL-VAC 25/6 RP MATERIAL SAFETY DATA SHEET


Section 15 - Regulatory information
All components of this product are listed on the Toxic Substances Control Act (TSCA) Section 8(b) Chemical Inventory.
This product is not a "hazardous substance" as defined by the OSHA Hazard Communication Standard (29 CFR
1910.1200). This product is not a "controlled product" as defined by the Canadian Workplace Hazardous Materials
Information System (WHMIS).

SARA Section 302 Extremely Hazardous Substances: Not listed

SARA 311/312: Acute: No
Chronic: No
Fire: No
Reactivity: No
Sudden Release of Pressure: No

SARA Section 313 Toxic Chemicals: Not listed


Section 16 - Additional Information
NFPA Ratings (Scale of 0-4):
Health = 1
Fire = 0
Reactivity = 0

Material Safety Data Sheets contain country-specific regulatory information; therefore, the MSDS鈥檚 provided are for
use only by customers of Solvay Solexis, Inc. in North America. If you are located in a country other than Canada,
Mexico or the United States, please contact the Solvay Group company in your country for MSDS information
applicable to your location.

The previous information is based upon our current knowledge and experience of our product and is not exhaustive. It
applies to the product as defined by the specifications. In case of combinations or mixtures, one must confirm that no new
hazards are likely to exist. In any case, the user is not exempt from observing all legal, administrative and regulatory
procedures relating to the product, personal hygiene, and integrity of the work environment. (Unless noted to the contrary,
the technical information applies only to pure product).

To our actual knowledge, the information contained herein is accurate as of the date of this document. However,
neither Solvay Solexis, Inc. nor any of its affiliates makes any warranty, express or implied, or accepts any liability
in connection with this information or its use. This information is for use by technically skilled persons at their own
discretion and risk and does not relate to the use of this product in combination with any other substance or any other
process. This is not a license under any patent or other proprietary right. The user alone must finally determine
suitability of any information or material for any contemplated use, the manner of use and whether any patents are
infringed.

Trademarks and/or other Solvay Solexis, Inc. products referenced herein are either trademarks or registered
trademarks of Solvay Solexis, Inc. or its affiliates, unless otherwise indicated.

Solvay Solexis, Inc. All rights reserved. Copyright 2004

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