Material Safety Data Sheet: Simple Green庐 Stone Cleaner
Version No. 18401b Date of Issue: May 2007 ANSI-Z400.1-2003 Format
Section 1: PRODUCT & COMPANY IDENTIFICATION
Simple Green庐 Stone Cleaner
Product Name:
Simple Green庐 Stone Care Non-Abrasive Cleaner
Additional Names:
Manufacturer鈥檚 Product Code Numbers: 18405 鈥? 16 oz. Trigger 18401 鈥? 32 oz. Trigger
Company: Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
Telephone: 800-228-0709 鈼? 562-795-6000 Fax: 562-592-3830
Website www.simplegreen.com
Emergency Phone: Chem-Tel 24-Hour Emergency Service: 800-225-3924
Use of Product A ready-to-use daily cleaning product for surfaces made from natural stone, porcelain, ceramic, and
engineered surfaces including: Kitchen & bath counters, floors, walls, columns, statuary, handrails,
fireplace surrounds and mantels, etc.
Section 2: HAZARDS IDENTIFICATION
NONHAZARDOUS
Emergency Overview: CAUTION. Mild eye irritant.
Simple Green庐 Stone Cleaner is a clear liquid with a mild, sweet fruity-woody odor. It is non-flammable, non-
combustible, non-explosive, and non-reactive.
0
NFPA/HMIS Rating:
0
1 Health = 1 = slight
Fire, Reactivity, and Special = 0 = minimal
0
Mild Eye Irritant (due to mild defatting effects.)
Eye Contact:
No adverse effects expected under typical use conditions.
Skin Contact:
May cause mild stomach or intestinal upset if swallowed (due to slight detersive properties.)
Ingestion:
No adverse effects expected under typical use conditions.
Inhalation:
No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.
Carcinogens:
No medical conditions are known to be aggravated by exposure to Simple Green庐 Stone Cleaner.
Medical Conditions:
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Substances Present: NONE
SARA Substances Present: NONE
Volatile Organic Compounds: NONE
Reportable Ingredients: NONE
All surfactants present in this product meet European Union REACH standards for biodegradability.
Pg 1 of 4
Material Safety Data Sheet: SIMPLE GREEN庐 STONE CLEANER
Material Safety Data Sheet: Simple Green庐 Stone Cleaner
Version No. 18401b Date of Issue: May 2007 ANSI-Z400.1-2003 Format
Section 4: FIRST AID MEASURES
If in eyes: Flush with plenty of water. After 5 minutes of flushing, remove contact lenses, if present. Continue
flushing for at least 10 more minutes, moving lower and upper eyelids away from eye to flush out all
product. If irritation persists beyond 12 hours after contact, seek medical attention.
If ingested: Drink plenty of water to dilute. Mild stomach or intestinal upset may occur due to detersive properties.
FIRE FIGHTING MEASURES
Section 5:
This product is non-flammable, non combustible, and non-explosive. Any form of extinguishing media may be used on
and around Simple Green Stone Cleaner. Please refer to Personal Protective Equipment information found in Section 8:
EXPOSURE CONTROLS/PERSONAL PROTECTIVE EQUIPMENT.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for
dermal contact are needed. Wash hands thoroughly with soap and water after usage contact or cleaning up spill or leak.
Procedure to follow in case of spill or leak: Section off spill area so that people do not slip or fall. Identify source of
leak or spill and contain with sand, earth, or containment bin. Then proceed to clean up spill or leak.
Method for cleaning up: Recover all reusable material. Remainder from small spills (32 ounces or less) may be rinsed to
sanitary sewer. Remainder of large spills should be covered with inert absorbent material to soak up spill. Dispose of
absorbent material as non-hazardous waste. Wash area with an alkaline cleaner, rinse area with plenty of water and mop to
sanitary sewer. Make sure any floor area is no longer slippery before resuming public access.
Section 7: HANDLING AND STORAGE
No special handling is required. Avoid contact with eyes. Wash hands thoroughly after handling.
UN Number: Not required Dangerous Goods Class: Nonhazardous
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye contact: Access to eye bath or water source is recommended in case of eye contact. Thoroughly wash hands
after contact to prevent hand to eye transference.
Ventilation: No special ventilation is required during use. Large-scale uses indoors should provide an increased
rate of air exchange.
Wear glasses to prevent eye contact if splashing or spraying Simple Green庐 Stone Cleaner.
Eye protection
Skin protection: Gloves or other skin protection are generally not needed under normal use conditions of Simple
Green庐 Stone Cleaner. Prolonged soaking in the product, repeated skin exposure over long periods of
time, pre-existing skin conditions such as dermatitis, or allergic response to contact with the product
may warrant the use of gloves.
General hygiene There are no known hazards associated with this material when used as recommended.
conditions:
The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.
Pg 2 of 4
Material Safety Data Sheet: SIMPLE GREEN庐 STONE CLEANER
Material Safety Data Sheet: Simple Green庐 Stone Cleaner
Version No. 18401b Date of Issue: May 2007 ANSI-Z400.1-2003 Format
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Clear no-color to pale straw liquid Mild fruity-woody smell
Appearance: Odor:
9 鈥? 11.5 8.33 lbs/gal
pH: Density:
1.0 Same as Water
Specific Gravity: Vapor Pressure:
> 80% 100%
Water Content: Water Solubility:
< 0.01% Dispersible in water
Insoluble Matter: Solubility:
o o
212 F (100.6 C) Equal to water
Boiling Point: Evaporation Rate:
Approximately 16oF (0 oC) Phosphate Free (< 0.5% by formula)
Freezing Point: Phosphate Content:
None (ASTM D-93) N/A
Flash Point: Flame Extension:
VOCs: 0 g/L per EPA Method 24 test results
Section 10: STABILITY AND REACTIVITY
Stability: Stable
Materials to Avoid: None known
Hazardous Decomposition Products: None expected
Section 11: TOXICOLOGICAL INFORMATION
Acute Toxicity: Oral LD50 (rat) >5.0 g/kg body weight Toxicity extrapolated from ingredients.
Dermal LD50 (rabbit) >2.0 g/kg body weight Animal testing not conducted
Eye Irritation: Mild, reversible eye irritation may occur based on relevant laboratory studies. This potential is
reduced by immediate rinsing of eyes in case of eye contact.
Dermal Irritation: Mild, reversible skin irritation may occur for those with dermal conditions or chemical sensitivities.
A 6-hour exposure to human skin under a patch did not produce irritation.
Repeat Exposure Via No toxic effects are associated with daily skin exposure. Skin irritation may, however, occur with
Skin Contact: repeated, prolonged exposure.
Reproductive Effects Based on relevant laboratory data for ingredients, no adverse effects on reproduction, fertility, or
Assessment: health of offspring are expected.
Section 12: ECOLOGICAL INFORMATION
Biodegradability: Based on data for ingredients, surfactants in this product are readily biodegradable.
Hazard to wild mammals: None, based on toxicology profile
Hazard to avian species: None, based on toxicology profile
Hazard to aquatic organisms: None, based on toxicology profile
Chemical Fate Information: Based on formula and biodegradability, the bioaccumulation potential is nil.
Additional information can be found in Section 15: REGULATORY INFORMATION.
Pg 3 of 4
Material Safety Data Sheet: SIMPLE GREEN庐 STONE CLEANER
Material Safety Data Sheet: Simple Green庐 Stone Cleaner
Version No. 18401b Date of Issue: May 2007 ANSI-Z400.1-2003 Format
Section 13: DISPOSAL CONSIDERATIONS
Appropriate Method for Disposal of Simple Green庐 Stone Cleaner
Unused Product: * Wrap container in newspaper and dispose in non-hazardous solid waste.
Empty Containers: *Triple-rinse with water and offer for recycling if available in your area. Otherwise,
dispose containers as non-hazardous waste.
*Dispose of used or unused product, and empty containers in accordance with the local, State, Provincial, and Federal
regulations for your location. Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or
storm drains.
Section 14: TRANSPORT INFORMATION
IATA Proper Shipping Name: Detergent Solution Hazard Class: Nonhazardous
Section 15: REGULATORY INFORMATION
Reportable components: None
All components are listed on: EINECS and TSCA Inventory
No components listed under: Clean Air Act Section 112
RCRA Status: Not a hazardous waste. CERCLA Status: No components listed
TSCA TIR Reporting: Not required / Not listed CA PROP. 65 Status: No components listed
Section 16: OTHER INFORMATION
Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. 鈥? TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Email: infoweb@simplegreen.com
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri] Fax: 562/592-3830
DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind.
Personnel handling this material must make independent determinations of the suitability and completeness of information
from all sources to assure proper use and disposal of this material and the safety and health of employees and customers.
Sunshine Makers, Inc. assumes no additional liability or responsibility resulting from the use of, or reliance on this
information.
Pg 4 of 4
Material Safety Data Sheet: SIMPLE GREEN庐 STONE CLEANER
|