MATERIAL SAFETY DATA SHEET
R87111
13 00
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Section 1 鈭掆垝 PRODUCT AND COMPANY IDENTIFICATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
PRODUCT NUMBER HMIS CODES
Health 2*
R87111 Flammability 0
Reactivity 0
PRODUCT NAME
RUST TOUGH* Water鈭払ased Rust Preventive Enamel, Dk. Machinery Gray
MANUFACTURER鈥橲 NAME EMERGENCY TELEPHONE NO.
THE SHERWIN鈭扺ILLIAMS COMPANY (216) 566鈭?2917
Consumer Group 鈭? Industrial
Cleveland, OH 44115
DATE OF PREPARATION INFORMATION TELEPHONE NO.
01鈭扤OV鈭?02 (800) 247鈭?3266
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Section 2 鈭掆垝 COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
3 111鈭?76鈭?2 2鈭払utoxyethanol
ACGIH TLV 20 ppm (skin) 0.88 mm
OSHA PEL 20 ppm (skin)
3 112鈭?34鈭?5 2鈭?(2鈭払utoxyethoxy)鈭抏thanol
ACGIH TLV Not Available 0.06 mm
OSHA PEL Not Available
11 13463鈭?67鈭?7 Titanium Dioxide
ACGIH TLV 10 mg/m3 as Dust
OSHA PEL 10 mg/m3 Total Dust
OSHA PEL 5 mg/m3 Respirable Fraction
0.2 1333鈭?86鈭?4 Carbon Black
ACGIH TLV 3.5 mg/m3
OSHA PEL 3.5 mg/m3
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Section 3 鈭掆垝 HAZARDS IDENTIFICATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
ROUTES OF EXPOSURE
Exposure may be by INHALATION and/or SKIN or EYE contact, depending on
conditions of use. To minimize exposure, follow recommendations for proper
use, ventilation, and personal protective equipment.
EFFECTS OF OVEREXPOSURE
Irritation of eyes, skin and upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Continued on page 2
R87111 page 2
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Section 4 鈭掆垝 FIRST AID MEASURES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
If INHALED: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
If on SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re鈭抲se.
If in EYES: Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
If SWALLOWED: Do not induce vomiting.
Get medical attention immediately.
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Section 5 鈭掆垝 FIRE FIGHTING MEASURES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
FLASH POINT LEL UEL
Not Applicable N.A. N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build鈭抲p of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self鈭抍ontained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build鈭抲p and possible autoignition or explosion when exposed to
extreme heat.
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Section 6 鈭掆垝 ACCIDENTAL RELEASE MEASURES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
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Section 7 鈭掆垝 HANDLING AND STORAGE
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Continued on page 3
R87111 page 3
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Section 8 鈭掆垝 EXPOSURE CONTROLS/PERSONAL PROTECTION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
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Section 9 鈭掆垝 PHYSICAL AND CHEMICAL PROPERTIES
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
PRODUCT WEIGHT 9.26 lb/gal 1110 g/l
SPECIFIC GRAVITY 1.11
BOILING POINT 212 鈭? 477 F 100 鈭? 247 C
MELTING POINT Not Available
VOLATILE VOLUME 66 %
EVAPORATION RATE Slower than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
pH 9.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
1.68 lb/gal 202 g/l Less Federally Exempt Solvents
0.71 lb/gal 85 g/l Emitted VOC
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Section 10 鈭掆垝 STABILITY AND REACTIVITY
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
STABILITY 鈭掆垝 Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
Continued on page 4
R87111 page 4
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HAZARDOUS POLYMERIZATION
Will not occur
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Section 11 鈭掆垝 TOXICOLOGICAL INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
CHRONIC HEALTH HAZARDS
Carbon Black is classified by IARC as possibly carcinogenic to humans
(group 2B) based on experimental animal data, however, there is
insufficient evidence in humans for its carcinogenicity.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary and blood forming systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
TOXICOLOGY DATA
CAS No. Ingredient Name
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
111鈭?76鈭?2 2鈭払utoxyethanol
LC50 RAT 4HR Not Available
LD50 RAT 470 mg/kg
112鈭?34鈭?5 2鈭?(2鈭払utoxyethoxy)鈭抏thanol
LC50 RAT 4HR Not Available
LD50 RAT 5660 mg/kg
13463鈭?67鈭?7 Titanium Dioxide
LC50 RAT 4HR Not Available
LD50 RAT Not Available
1333鈭?86鈭?4 Carbon Black
LC50 RAT 4HR Not Available
LD50 RAT Not Available
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Section 12 鈭掆垝 ECOLOGICAL INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
ECOTOXICOLOGICAL INFORMATION
No data available.
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Section 13 鈭掆垝 DISPOSAL CONSIDERATIONS
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
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Section 14 鈭掆垝 TRANSPORT INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
No data available.
Continued on page 5
R87111 page 5
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Section 15 鈭掆垝 REGULATORY INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % by WT % Element
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
Glycol Ethers 6
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
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Section 16 鈭掆垝 OTHER INFORMATION
鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭掆垝鈭?
This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all of the information required by the
CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
o liability in connection with any use of this information.
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