**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-51-6 |Benzyl Alcohol | 99.0 | 202-859-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.Hygroscopic.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause
defatting of the skin and dermatitis. Causes redness and pain. May
be harmful if absorbed through the skin. Contact with the skin may
cause a local anesthetic effect.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May be harmful if swallowed.
Inhalation:
Vapors cause irritation of the respiratory system.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Blood benzyl alcohol and benzoic acid and urine hippuric acid may be
helpful in diagnosis.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
Use dry chemical, carbon dioxide, or alcohol-resistant foam. Water
spray may cause frothing.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Do
not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear, colorless
Odor: Faint aromatic odor
pH: Not available.
Vapor Pressure: 0.13 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 205 deg C
Freezing/Melting Point: -15 deg C
Autoignition Temperature: 435 deg C ( 815.00 deg F)
Flash Point: 213 deg F ( 100.56 deg C)
Explosion Limits, lower: 1.3
Explosion Limits, upper: 13.0
Decomposition Temperature: Not available.
Solubility in water: Moderately Soluble.
Specific Gravity/Density: 1.045
Molecular Formula: C7H8O
Molecular Weight: 108.0554
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, temperatures above 100C, exposure to moist
air or water.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents, sulfuric acid, acids, hydrogen
bromide gas + iron at >100C(exothermic polymerization), plastics.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-51-6: DN3150000
LD50/LC50:
CAS# 100-51-6: Draize test, rabbit, skin: 100 mg/24H Moderate; Oral,
mouse: LD50 = 1360 mg/kg; Oral, rabbit: LD50 = 1040 mg/kg; Oral, rat:
LD50 = 1230 mg/kg; Skin, rabbit: LD50 = 2 gm/kg.
Carcinogenicity:
Benzyl Alcohol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 46.41 mg/L; 96 Hr.; Static, Soft
WaterFish: Fathead Minnow: LC50 = 59.30 mg/L; 96 Hr.; Static, Hard
WaterFish: Bluegill/Sunfish: LC50 = 25.05 mg/L; 96 Hr.; Static, Hard
WaterFish: Goldfish: LC50 = 64.74 mg/L; 96 Hr.; Static, Hard
WaterWater flea Daphnia: EC50 = 400.0 mg/L; 48 Hr.; UnspecifiedWater
flea Daphnia: EC50 = 23.0 mg/L; 48 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 71.4 mg/L; 5,15,30 minutes;
Microtox test, 15 degrees Clog Pow:1.1 Fish toxicity: LC50 (48-96hr)
fathead minnow 770-460 mg/l, static bioassay at 18-22°C
[Verschueren, K. Handbook of Environmental Data of Organic Chemicals
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 100-51-6: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 100-51-6 is listed on Canada's DSL List.
CAS# 100-51-6 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 100-51-6: OEL-RUSSIA:STEL 5 mg/m3;Skin
US FEDERAL
TSCA
CAS# 100-51-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/30/1999 Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ammonium molybdate(VI) tetrahydrate, reagent ACS
| 12027-67-7 |
|
Ammonium molybdate(VI) tetrahydrate, coarse crystals, c.p.
| 12027-67-7 |
|
Benzyl Alcohol, 99%
| 100-51-6 |
|
Benzene, 99+%, Spectrophotometric Grade
| 71-43-2 |
|
Benzene, P.A.
| 71-43-2 |
|
Benzene, 99%
| 71-43-2 |
|
Benzene-D6, 99+ Atom % D
| 1076-43-3 |
|
Benzene-D6, 100.0 Atom % D, Packaged in 0. 50ml Ampules
| 1076-43-3 |
|
Benzene-D6, 99.5 Atom % D
| 1076-43-3 |
|
Benzene-D6, 99.5 Atom % D, Packaged in 1.0ml Ampules
| 1076-43-3 |
|
Benzene-D6, 99.5 Atom % D Contains 1 v/v% TMS
| 1076-43-3 |
|
Acetonitrile, 99%
| 75-05-8 |
|
2-Butanone, 99+%
| 78-93-3 |
|
2-Butanone, 99+%, Spectrophotometric Grade
| 78-93-3 |
|
Acetonitrile, Spectrophotometric Grade, 99+%
| 75-05-8 |
|
Acetonitrile, p.a.
| 75-05-8 |
|
Acetonitrile, for HPLC
| 75-05-8 |
|
Acetonitrile, for HPLC for U.V.
| 75-05-8 |
|
Acetonitrile, Nonaqueous Titr. Grade, 99+% (GC)
| 75-05-8 |
|
Chloroform, Reagent ACS, 99+% (GC)
| 67-66-3 |
|
Acetonitrile-D3, 99 Atom % D, Packaged in 1.00 ml Ampules
| 2206-26-0 |
|
Acetonitrile-D3, 99 Atom % D Contains 1 v/v% TMS
| 2206-26-0 |
|
Acetonitrile-D3, 99 Atom % D
| 2206-26-0 |
|
Acetonitrile, Reagent ACS, 99.5% (GC)
| 75-05-8 |
|
Triton X-100, scintillation grade
| 9002-93-1 |
|
Rhodamine B
| 81-88-9 |
|
Rhodamine B, 99+% (TLC)
| 81-88-9 |
|
Rhodamine B, Laser Grade, 99+% (UV-Vis)
| 81-88-9 |
|
Rhodamine 6g, 99% (uv-vis)
| 989-38-8 |
|
Rhodamine 6g, laser grade
| 989-38-8 |
|
Triton X-405, 70% solution in water
| 7732-18-5 |
|
Chloroform, 99+%, Spectrophotometric Grade
| 67-66-3 |
|
Chloroform, P.A.(Stabilized with ca. 1% Ethanol)
| 64-17-5 |
|
Chloroform, for HPLC, Stabilized with 25 ppm Amylene
| 67-66-3 |
|
Triton X-114
| 9036-19-5 |
|
DL-Alpha-Aminocaprylic Acid, 99%
| 2187-07-7 |
|
Chloroform-D, 100 Atom % D
| 865-49-6 |
|
Chloroform-D, 100 Atom % D, Packaged in 0. 50ml Ampules
| 865-49-6 |
|
Chloroform-D, 99.8 Atom % D, Packaged in 1.00ml Ampules
| 865-49-6 |
|
Chloroform-D, 99.8 Atom % D Contains 1% V/V TMS
| 75-76-3 |
|
Chloroform-D, 99.8 Atom % D Contains 0.03% TMS
| 75-76-3 |
|
Chloroform-D, 99.6+ Atom % D
| 865-49-6 |
|
alpha-Bromocinnamaldehyde, 98%
| 1775-27-5 |
|
Dimethylamine (26% in Water)
| 124-40-3 |
|
Isopropanol, Anhydrous, 99.8+%
| 67-63-0 |
|
Isopropanol, Reagent ACS
| 67-63-0 |
|
Isopropanol, 99+%, Spectrophotometric Grade
| 67-63-0 |
|
Isopropanol
| 67-63-0 |
|
2,4-Dichloro-1-Naphthol, 99%
| 2050-76-2 |
|
Isopropanol, Reagent ACS, Spectro Grade
| 67-63-0 |
|
|