**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10034-81-8 |Magnesium perchlorate, reagent ACS | ca. 100 | 233-108-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI O
Risk Phrases: 36/37/38 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Contact with
combustible material may cause fire.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. May cause
permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea,
vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. May cause acute pulmonary edema, asphyxia, chemical
pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Some oxidizers may react explosively
with hydrocarbons(fuel). May accelerate burning if involved in a
fire. Containers may explode when heated. Runoff to sewer may create
fire or explosion hazard.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Do NOT get water inside containers. Contact
professional fire-fighters immediately. For small fires, do NOT use
dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For
large fires flood fire with water from a distance.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Remove all sources of ignition. Provide
ventilation. Do not get water inside containers. Do not use
combustible materials such as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with clothing and other
combustible materials. Do not get on skin or in eyes. Do not ingest
or inhale. Do not allow contact with water. Keep from contact with
moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store in
a cool, dry, well-ventilated area away from incompatible substances.
Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 10034-81-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 251 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >250 deg C
Solubility in water: 993 g/L water (25C)
Specific Gravity/Density: 2.60 g/mL @ 25C
Molecular Formula: Mg(ClO4)2
Molecular Weight: 223.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Combines vigorously with water with the
evolution of heat.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture,
excess heat, combustible materials, organic materials, reducing
agents, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, moisture, organic matter, trimethyl phosphate,
alkenes, hydrazine, alcohols, metal powders, strong reducing agents,
strong acids, mineral acids, ammonia, butyl fluoride, phosphorus,
dimethyl sulfoxide, ethylene oxide, hydrocarbons.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of magnesium.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10034-81-8: SC8925000
LD50/LC50:
Not available.
Carcinogenicity:
Magnesium perchlorate, reagent ACS -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: MAGNESIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1475
Packing Group: II
IMO
Shipping Name: MAGNESIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1475
Packing Group: II
RID/ADR
Shipping Name: MAGNESIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1475
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 10034-81-8: 1
Canada
CAS# 10034-81-8 is listed on Canada's DSL List.
CAS# 10034-81-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10034-81-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Nalpha-BOC-D-ASPARAGINE, 98%
| 75647-01-7 |
|
3-Methyl-1-butanol
| 123-51-3 |
|
N-alpha-BOC-D-Glutamine, 98%
| 61348-28-5 |
|
N-Octyl isothiocyanate
| 4430-45-9 |
|
NALPHA-BOC-D-HISTIDINE, 98%
| 50654-94-9 |
|
1,6-Hexanediamine, 60 wt % Aqueous Soln.
| 124-09-4 |
|
Isopropyl Ether
| 108-20-3 |
|
L-Alanine
| 56-41-7 |
|
alpha-Ketoglutaric Acid
| 328-50-7 |
|
L-(+)-Lysine Monohydrochloride, 99+%
| 657-27-2 |
|
BOC-D-Leucine monohydrate, 98%
| 16937-99-8 |
|
l-(+)-Glutamine, 99%
| 56-85-9 |
|
l-(+)-Arginine hydrochloride, 98+%
| 1119-34-2 |
|
l-Valine, 97% (titr.)
| 72-18-4 |
|
L-Cystine, 96% (titr.)
| 56-89-3 |
|
L-(+)-Arginine, 98+%
| 74-79-3 |
|
BOC-D-Methionine, 98%
| 5241-66-7 |
|
BOC-L-Norleucine, 98%
| 6404-28-0 |
|
BOC-L-Norvaline, 98%
| 53308-95-5 |
|
BOC-D-Proline, 98%
| 37784-17-1 |
|
l(+)-Ascorbic acid, reagent acs
| 50-81-7 |
|
L(+)-Asparagine Monohydrate, 99%
| 5794-13-8 |
|
3'-Bromopropiophenone, 98%
| 19829-98-8 |
|
Lead Nitrate, Reagent ACS (Crystals)
| 10099-74-8 |
|
L-Aspartic acid-4-(4-methyl-7-coumarinylamide)
| 133628-73-6 |
|
1-(4-Fluorophenyl)piperazine, 98%
| 2252-63-3 |
|
Lead(II) oxide, 99.7%
| 1317-36-8 |
|
Lecithin, granular
| 8002-43-5 |
|
Light Green SF, Yellowish (Cert)
| 5141-20-8 |
|
5-Bromo-6-Chloro-3-Indolyl-beta-D-Glucuronide Cyclohexylammonium Salt
| 144110-43-0 |
|
4-Nitrophenyl-N-Acetyl-??-D-Galactosaminide
| 14948-96-0 |
|
Phenyl-beta-D-Glucuronide Hydrate, 99%
| 17685-05-1 |
|
4-Methylumbelliferyl-alpha-D-Mannopyranoside Hydrate, 99%
| 28541-83-5 |
|
alpha-Terpineol
| 98-55-5 |
|
Ligroine, boiling range 35 - 60 degree C
| 8032-32-4 |
|
Lithium Bromide, 99.999%
| 7550-35-8 |
|
Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran
| 100-59-4 |
|
1-Hydroxy-9-fluorenone, 99%
| 6344-60-1 |
|
Zinc Sulfide
| 1314-98-3 |
|
Lithium Carbonate, 99%
| 554-13-2 |
|
3-Indoxyl Phosphate Disodium Salt, 99%
| 3318-43-2 |
|
Magnesium Oxide, P.A.
| 1309-48-4 |
|
6,7-Diethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline hydrochloride,
| 94914-42-8 |
|
Magnesium perchlorate, reagent ACS
| 10034-81-8 |
|
Magnesium Sulfate, Anhydrous, 97% (titr.)
| 7487-88-9 |
|
Magnesium sulfate heptahydrate, p.a
| 7487-88-9 |
|
n-Pentyl propionate, 99+%
| 624-54-4 |
|
Maleic Acid, 99%
| 110-16-7 |
|
Malonic acid, 99%
| 141-82-2 |
|
2-Methyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline hydrochloride,
| 16135-43-6 |
|
|