**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10034-93-2 |HYDRAZINE SULFATE | >99 | 233-110-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T C
Risk Phrases: 22 34 42/43 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns. May cause sensitization by
inhalation and skin contact. May cause cancer.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. May cause severe
irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May cause liver and kidney damage. May
cause corrosion and permanent tissue destruction of the esophagus
and digestive tract. Exposure may cause anemia and other blood
abnormalities. May be harmful if swallowed.
Inhalation:
May cause allergic respiratory reaction. May cause severe
respiratory tract irritation and possible burns.
Chronic:
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. May cause
liver and kidney damage. May cause cancer according to animal
studies. Repeated exposure may cause allergic respiratory reaction
(asthma).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation. Use only in a chemical fume hood. Avoid
mechanical shock and friction.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed. Storage under a nitrogen
blanket has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 10034-93-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: decomposes
Freezing/Melting Point: 254 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.378
Molecular Formula: H4N2.H2SO4
Molecular Weight: 130.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Substance is shock
sensitive and thermally unstable.
Conditions to Avoid:
Mechanical shock, incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10034-93-2: MV9625000
LD50/LC50:
CAS# 10034-93-2: Draize test, rabbit, eye: 20 mg/24H Moderate; Oral,
mouse: LD50 = 434 mg/kg; Oral, rat: LD50 = 601 mg/kg.
Carcinogenicity:
HYDRAZINE SULFATE -
California: carcinogen, initial date 1/1/88
NTP: Suspect carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C
Risk Phrases:
R 45 May cause cancer.
R 22 Harmful if swallowed.
R 34 Causes burns.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 10034-93-2: No information available.
Canada
CAS# 10034-93-2 is listed on Canada's DSL List.
CAS# 10034-93-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10034-93-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/24/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Methylpicolinic acid, 98%
| 4021-07-2 |
|
2-Amino-3-Chlorobenzoic Acid, 97%
| 6388-47-2 |
|
TRANS-4-AMINOCYCLOHEXANOL , 97%
| 27489-62-9 |
|
(R)-(-)-Baclofen
| 69308-37-8 |
|
2-Hydroxymethyl-15-crown-5, 96%
| 75507-25-4 |
|
Glycerol 99.5+%, Spectrophotometric Grade
| 56-81-5 |
|
Ethyl Trans-2-Amino-4-Cyclohexene-1-Carboxylate Hydrochloride, 98%
| 142547-16-8 |
|
cis-2-Amino-1-Cyclopentanecarboxamide, 98%
| 135053-11-1 |
|
4-Amino-1,2,2,6,6-pentamethylpiperidine, 99%
| 0-01-1 |
|
4-NITROTHIOPHENOL, 95%
| 1849-36-1 |
|
Glycine, p.a.
| 56-40-6 |
|
D-Glycogen
| 9005-79-2 |
|
Diphenylmethylsilane
| 776-76-1 |
|
cis-2-Amino-4-Cyclohexene-1-Carboxamide, 98%
| 111302-96-6 |
|
Benzyl Chloroacetate, 98%
| 140-18-1 |
|
1-Chloro-3-Nitrobenzene, 98%
| 121-73-3 |
|
Hydrogen tetrachloroaurate(III), trihydrate, reagent ACS
| 16903-35-8 |
|
4-Chlorobenzenesulfonyl isocyanate, 97%
| 5769-15-3 |
|
Oxytetracycline dihydrate
| 6153-64-6 |
|
Guanidine Hydrochloride, 99% (Titr.)
| 50-01-1 |
|
Cis-2-Benzylaminomethyl-1-Cyclopentanol Hydrochloride, 98%
| 20520-98-3 |
|
Cis-2-Benzylaminomethyl-1-Cyclooctanol Hydrochloride, 98%
| 98516-20-2 |
|
3-Amino-3-(p-methoxyphenyl)-1-propanol, 98%
| 68208-24-2 |
|
6-Methoxy-1-Indanone
| 13623-25-1 |
|
Ethyl 2-amino-1-cyclohexene-1-carboxylate, 98%
| 1128-00-3 |
|
cis-2-(tert.-Butoxycarbonylamino)-cyclohexanecarboxylic acid, 98%
| 0-01-1 |
|
Cis-2-(Benzyloxycarbonylamino)-Cyclohexanecarboxylic Acid, 98%
| 54867-08-2 |
|
Cis-2-(Benzyloxycarbonylamino)-4-Cyclohexene-1-Carboxylic Acid, 98%
| 124753-65-7 |
|
Heptane, sequenation grade, 99%
| 108-87-2 |
|
Hexadecane
| 544-76-3 |
|
Cetyltrimethylammonium Bromide (Techn)
| 57-09-0 |
|
Hexamethylenetetramine, 98.5%, contains an anticaking agent
| 100-97-0 |
|
3-Amino-3-(p-Tolyl)Propionic Acid, 98%
| 68208-18-4 |
|
3-Amino-3-(p-Chlorophenyl)Propionic Acid, 98%
| 19947-39-8 |
|
3-Amino-3-(p-Methoxyphenyl)Propionic Acid, 98%
| 5678-45-5 |
|
1,2,3,4-Tetrahydroisoquinoline-1-Acetic Acid, 98%
| 105400-81-5 |
|
6,7-Diethoxy-1,2,3,4-Tetrahydroisoquinoline-1-Acetic Acid
| 0-01-1 |
|
1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid, 98%
| 67123-97-1 |
|
4-Trans-Phenylcyclohexane-(1R,2-cis)-Dicarboxylic Anhydride
| 0-01-1 |
|
4-Trans-Phenylcyclohexane-(1R,2-cis)-Dicarboxylic Imide
| 0-01-1 |
|
3-(p-Chlorobenzoyl)-2-Methylpropionic Acid, 98%
| 52240-20-7 |
|
n-Hexane
| 110-54-3 |
|
3-(p-Chlorobenzoyl)-Butyric Acid, 98%
| 36978-49-1 |
|
2,2-Dimethyl-3-Hydroxyl-3-(p-Tolyl)-Propionic Acid, 98%
| 0-01-1 |
|
2,2-Dimethyl-3-Hydroxy-3-(p-Methoxyphenyl)-Propionic Acid, 98%
| 64284-35-1 |
|
Hexanes, p.a.
| 110-54-3 |
|
2-(Dimethylaminomethyl)-1-Cyclohexanone Hydrochloride, 98%
| 42036-65-7 |
|
Hydrazine, 99% (titr.)
| 302-01-2 |
|
Hydrazine Sulfate, Reagent acs, 99+% (titr.)
| 10034-93-2 |
|
Hydrobromic Acid, Techn., 33 wt. % Solution in Glacial Acetic Acid
| 64-19-7 |
|
|