**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 56-81-5 |Glycerol | 99.5+% | 200-289-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause headache.
Inhalation:
Low hazard for usual industrial handling. Inhalation of a mist of
this material may cause respiratory tract irritation.
Chronic:
May cause transient kidney disturbances.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use dry chemical,
carbon dioxide, or alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 56-81-5:
United Kingdom, WEL - TWA: 10 mg/m3 TWA (mist)
United Kingdom, WEL - STEL: 30 mg/m3 STEL (mist)
United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA
(respirable fraction)
Belgium - TWA: 10 mg/m3 VLE (mist)
France - VME: 10 mg/m3 VME
Malaysia: 10 mg/m3 TWA (mist)
Netherlands: 10 mg/m3 MAC (mist)
Spain: 10 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: faint odor
pH: Not available.
Vapor Pressure: .0025 mm Hg @ 5
Viscosity: 1069 mPas 20 deg C
Boiling Point: 290 deg C @ 760.00mm Hg
Freezing/Melting Point: 18 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 160 deg C ( 320.00 deg F)
Explosion Limits, lower: .90 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature: >290 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.2610g/cm3
Molecular Formula: C3H8O3
Molecular Weight: 92.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, acetic anhydride, strong acids, alliphatic
amines, potassium chlorates, isocyanates, hydrogen peroxides,
potassium permanganate.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 56-81-5: MA8050000
LD50/LC50:
CAS# 56-81-5: Draize test, rabbit, eye: 126 mg Mild; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H
Mild; Inhalation, rat: LC50 = >570 mg/m3/1H; Oral, mouse: LD50 =
4090 mg/kg; Oral, rabbit: LD50 = 27 gm/kg; Oral, rat: LD50 = 12600
mg/kg; Skin, rabbit: LD50 = >10 gm/kg.
Carcinogenicity:
Glycerol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Cas# 56-81-5:
LC50 (96 Hr.) rainbow trout = 50-67 mg/L; 12 degrees
C
LC50 (96 Hr.) goldfish = >5000 mg/L
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 56-81-5: 0
Canada
CAS# 56-81-5 is listed on Canada's DSL List.
CAS# 56-81-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56-81-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/20/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Methylpicolinic acid, 98%
| 4021-07-2 |
|
2-Amino-3-Chlorobenzoic Acid, 97%
| 6388-47-2 |
|
TRANS-4-AMINOCYCLOHEXANOL , 97%
| 27489-62-9 |
|
(R)-(-)-Baclofen
| 69308-37-8 |
|
2-Hydroxymethyl-15-crown-5, 96%
| 75507-25-4 |
|
Glycerol 99.5+%, Spectrophotometric Grade
| 56-81-5 |
|
Ethyl Trans-2-Amino-4-Cyclohexene-1-Carboxylate Hydrochloride, 98%
| 142547-16-8 |
|
cis-2-Amino-1-Cyclopentanecarboxamide, 98%
| 135053-11-1 |
|
4-Amino-1,2,2,6,6-pentamethylpiperidine, 99%
| 0-01-1 |
|
4-NITROTHIOPHENOL, 95%
| 1849-36-1 |
|
Glycine, p.a.
| 56-40-6 |
|
D-Glycogen
| 9005-79-2 |
|
Diphenylmethylsilane
| 776-76-1 |
|
cis-2-Amino-4-Cyclohexene-1-Carboxamide, 98%
| 111302-96-6 |
|
Benzyl Chloroacetate, 98%
| 140-18-1 |
|
1-Chloro-3-Nitrobenzene, 98%
| 121-73-3 |
|
Hydrogen tetrachloroaurate(III), trihydrate, reagent ACS
| 16903-35-8 |
|
4-Chlorobenzenesulfonyl isocyanate, 97%
| 5769-15-3 |
|
Oxytetracycline dihydrate
| 6153-64-6 |
|
Guanidine Hydrochloride, 99% (Titr.)
| 50-01-1 |
|
Cis-2-Benzylaminomethyl-1-Cyclopentanol Hydrochloride, 98%
| 20520-98-3 |
|
Cis-2-Benzylaminomethyl-1-Cyclooctanol Hydrochloride, 98%
| 98516-20-2 |
|
3-Amino-3-(p-methoxyphenyl)-1-propanol, 98%
| 68208-24-2 |
|
6-Methoxy-1-Indanone
| 13623-25-1 |
|
Ethyl 2-amino-1-cyclohexene-1-carboxylate, 98%
| 1128-00-3 |
|
cis-2-(tert.-Butoxycarbonylamino)-cyclohexanecarboxylic acid, 98%
| 0-01-1 |
|
Cis-2-(Benzyloxycarbonylamino)-Cyclohexanecarboxylic Acid, 98%
| 54867-08-2 |
|
Cis-2-(Benzyloxycarbonylamino)-4-Cyclohexene-1-Carboxylic Acid, 98%
| 124753-65-7 |
|
Heptane, sequenation grade, 99%
| 108-87-2 |
|
Hexadecane
| 544-76-3 |
|
Cetyltrimethylammonium Bromide (Techn)
| 57-09-0 |
|
Hexamethylenetetramine, 98.5%, contains an anticaking agent
| 100-97-0 |
|
3-Amino-3-(p-Tolyl)Propionic Acid, 98%
| 68208-18-4 |
|
3-Amino-3-(p-Chlorophenyl)Propionic Acid, 98%
| 19947-39-8 |
|
3-Amino-3-(p-Methoxyphenyl)Propionic Acid, 98%
| 5678-45-5 |
|
1,2,3,4-Tetrahydroisoquinoline-1-Acetic Acid, 98%
| 105400-81-5 |
|
6,7-Diethoxy-1,2,3,4-Tetrahydroisoquinoline-1-Acetic Acid
| 0-01-1 |
|
1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid, 98%
| 67123-97-1 |
|
4-Trans-Phenylcyclohexane-(1R,2-cis)-Dicarboxylic Anhydride
| 0-01-1 |
|
4-Trans-Phenylcyclohexane-(1R,2-cis)-Dicarboxylic Imide
| 0-01-1 |
|
3-(p-Chlorobenzoyl)-2-Methylpropionic Acid, 98%
| 52240-20-7 |
|
n-Hexane
| 110-54-3 |
|
3-(p-Chlorobenzoyl)-Butyric Acid, 98%
| 36978-49-1 |
|
2,2-Dimethyl-3-Hydroxyl-3-(p-Tolyl)-Propionic Acid, 98%
| 0-01-1 |
|
2,2-Dimethyl-3-Hydroxy-3-(p-Methoxyphenyl)-Propionic Acid, 98%
| 64284-35-1 |
|
Hexanes, p.a.
| 110-54-3 |
|
2-(Dimethylaminomethyl)-1-Cyclohexanone Hydrochloride, 98%
| 42036-65-7 |
|
Hydrazine, 99% (titr.)
| 302-01-2 |
|
Hydrazine Sulfate, Reagent acs, 99+% (titr.)
| 10034-93-2 |
|
Hydrobromic Acid, Techn., 33 wt. % Solution in Glacial Acetic Acid
| 64-19-7 |
|
|