**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10210-68-1 |Cobalt Carbonyl | 100 | 233-514-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 22 42/43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. May cause sensitization by
inhalation and skin contact.Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white
blood cell count. May cause respiratory tract irritation. In rare
instances, exposure may cause sensitization, resulting in
inflammation of the mucous membranes and in eczematous eruptions.
Chronic:
May cause kidney injury. Cobalt compounds may cause cancer based
upon animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
There exists several chelation agents. The determination of there
use should be made only by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. May
burn with invisible flame. Water Reactive. Material will react with
water and may release a flammable and/or toxic gas. Use water spray
to keep fire-exposed containers cool. Spontaneously ignitable in
air. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. May burn rapidly with
flare burning effect. May re-ignite after fire is extinguished.
Containers may explode if exposed to fire.
Extinguishing Media:
Do NOT use water directly on fire. Do NOT get water inside
containers. Contact professional fire-fighters immediately. Cool
containers with flooding quantities of water until well after fire
is out. For small fires, use dry chemical, soda ash, lime or sand.
For large fires, use dry sand, dry chemical, soda ash or lime or
withdraw from area and let fire burn.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Isolate area and
deny entry. Place under an inert atmosphere. Do not use combustible
materials such as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Use spark-proof tools and explosion
proof equipment. Avoid contact with eyes, skin, and clothing. Avoid
contact with skin and eyes. Avoid ingestion and inhalation. Handle
under an inert atmosphere. Store protected from air.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Keep away from water. Refrigerator/flammables. Keep containers
tightly closed. Do not expose to air. Store under an inert
atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
CAS# 10210-68-1:
United Kingdom, WEL - TWA: (listed as cobalt compounds): 0.1 mg/m
TWA (as Co)
United Kingdom, WEL - STEL: (listed as cobalt compounds): 0.3 mg/
STEL (as Co)
Belgium - TWA: 0.1 mg/m3 VLE (as Co)
France - VME: 0.1 mg/m3 VME (as Co)
Japan: (listed as cobalt compounds): 0.05 mg/m3 OEL (as Co)
Malaysia: 0.1 mg/m3 TWA (as Co)
Netherlands: 0.1 mg/m3 MAC (as Co)
Spain: 0.1 mg/m3 VLA-ED (as Co)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: dark orange
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 52 deg C
Freezing/Melting Point: 51.00 - 52.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: > 52 deg C
Solubility in water: insoluble
Specific Gravity/Density: 1.8100g/cm3
Molecular Formula: C8Co2O8
Molecular Weight: 341.8616
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Powder or liquid is
pyrophoric.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, exposure
to air, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, oxides of cobalt.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10210-68-1: GG0300000
LD50/LC50:
CAS# 10210-68-1: Inhalation, mouse: LC50 = 26900 ug/m3/2H;
Inhalation, rat: LC50 = 165 mg/m3; Oral, mouse: LD50 = 378 mg/kg;
Oral, rat: LD50 = 754 mg/kg.
Carcinogenicity:
Cobalt Carbonyl -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.*
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
IMO
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 10210-68-1: No information available.
Canada
CAS# 10210-68-1 is listed on Canada's DSL List.
CAS# 10210-68-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10210-68-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/01/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
NBD-F
| 29270-56-2 |
|
2,2,2-Tribromoethanol, 99% (GC)
| 75-80-9 |
|
Ethyl iodoacetate (pract)
| 623-48-3 |
|
Isovaleric acid, 99%
| 503-74-2 |
|
n-Acetylmuramic acid, 97%
| 10597-89-4 |
|
2,5-Pyrazinedicarboxylic Acid Dihydrate, 97%
| 0-01-1 |
|
Aleuritic Acid, 95%
| 533-87-9 |
|
4-Nitro-DL-Phenylalanine, Hydrate, 99%
| 2922-40-9 |
|
4'-Bromo-4-Chlorobutyrophenone, 99%
| 4559-96-0 |
|
Tetracosanoic Acid, 99%(GC)
| 557-59-5 |
|
Phthalhydrazide, 99%
| 1445-69-8 |
|
Monoacetin (Contains Mixed Analogs), ca. 40% as Monoacetin
| 26446-35-5 |
|
N-Alpha-P-Tosyl-L-Arginine Methyl Ester Hydrochloride ,99%
| 1784-03-8 |
|
4,5-Diphenyl-4-Oxazoline-2-Thione, 98%
| 6670-13-9 |
|
1,2-Dibromo-3,5-Difluorobenzene, 99%
| 139215-43-3 |
|
3',4'-(Didodecyloxy)acetophenone, 97% (GC)
| 0-00-1 |
|
Coumarin 500, Laser Grade, 98% (UV-Vis)
| 52840-38-7 |
|
Spermidine, 99%
| 124-20-9 |
|
Potassium hexafluorophosphate, 99%
| 17084-13-8 |
|
3'-Aminoacetanilide Hydrochloride (Pract)
| 621-35-2 |
|
1-Naphthylacetonitrile, 97%
| 132-75-2 |
|
3-Chloropropionic acid, 98%
| 107-94-8 |
|
4-Bromophenylhydrazine Hydrochloride, 98% (uv-vis)
| 622-88-8 |
|
1-Adamantanol, 99%
| 768-95-6 |
|
2-Nitrobiphenyl, 97%
| 85-99-4 |
|
Dicobalt Octacarbonyl
| 10210-68-1 |
|
2,4-Dimethoxypyrimidine, 99+%
| 3551-55-1 |
|
5-Aminovaleric Acid Hydrochloride, 98%
| 627-95-2 |
|
4,9-Dioxa-1,12-Dodecanediamine, 97%
| 7300-34-7 |
|
9-Hydroxy-9-fluorenecarboxylic acid, 94%
| 467-69-6 |
|
2-Nitro-m-xylene, 99%
| 81-20-9 |
|
Iodoacetonitrile, 95%
| 624-75-9 |
|
3-Phenyl-5-isoxalone, 97%
| 1076-59-1 |
|
2,4,6,-Triphenylpyrylium chloride, 98% (titr.)
| 40836-01-9 |
|
Cis,cis,cis,cis-1,2,3,4-cyclopentanetetra carboxylic acid, 98%
| 3786-91-2 |
|
L-2,4-Diaminobutyric Acid Dihydrochloride 98%
| 1883-09-6 |
|
Triheptylamine, 96% (GC)
| 2411-36-1 |
|
Diethyl chlorophosphate, 95%
| 814-49-3 |
|
E-1,3-Dichloropropene, 97%
| 542-75-6 |
|
P-Hexylphenol, 99% (GC)
| 2446-69-7 |
|
(2,5-Dimethoxyphenyl)acetic acid, 97%
| 1758-25-4 |
|
2-Methyllactic acid, 99+% (Titr.)
| 594-61-6 |
|
2-Bromolauric acid, 95%
| 111-56-8 |
|
Fumaric acid monoethyl ester, 95%
| 2459-05-4 |
|
5-Chloroindole-2-carboxylic acid, 98%
| 10517-21-2 |
|
Dimethyl chlorothiophospate, 97%
| 2524-03-0 |
|
Gamma-Benzyl L-Glutamate, 99+%
| 1676-73-9 |
|
4'-Isocyanatobenzo-18-Crown-6, 99%
| 0-01-1 |
|
Lithium tri-sec-butylborohydride 1M solution in THF
| 109-99-9 |
|
Adenosine, 99+%
| 58-61-7 |
|
|