**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 814-49-3 |Diethyl chlorophosphate | 95 | 212-396-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 26/27/28 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.
Potential Health Effects
Eye:
May cause eye irritation. Contact of the eye with the undiluted
compound may result in death.
Skin:
May cause skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
May be fatal if swallowed. May cause gastrointestinal irritation
with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation. Aspiration may cause
respiratory swelling and pneumonitis.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Induce vomiting only when instructed to do so by a
physician.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Discard contaminated shoes. Use only with
adequate ventilation. Keep away from heat and flame. Do not breathe
vapor or mist.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 814-49-3:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 0.1 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 81 deg C @ 6 mm Hg
Freezing/Melting Point: -60 deg C
Autoignition Temperature: Not available.
Flash Point: 61 deg C ( 141.80 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: 120 deg C
Solubility in water: Decomposes.
Specific Gravity/Density: 1.1940 g/cm3
Molecular Formula: C4H10ClO3P
Molecular Weight: 172.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, chloride fumes, phosphorous
fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 814-49-3: TD1400000
LD50/LC50:
CAS# 814-49-3: Draize test, rabbit, skin: 500 mg/24H Mild; Oral,
mouse: LD50 = 100 mg/kg; Oral, rat: LD50 = 11 mg/kg; Skin, rabbit:
LD50 = 8 uL/kg.
Carcinogenicity:
Diethyl chlorophosphate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3278
Packing Group: II
IMO
Shipping Name: ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing Group: II
RID/ADR
Shipping Name: ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 814-49-3: No information available.
Canada
CAS# 814-49-3 is listed on Canada's NDSL List.
CAS# 814-49-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 814-49-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/19/1998 Revision #3 Date: 5/05/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
NBD-F
| 29270-56-2 |
|
2,2,2-Tribromoethanol, 99% (GC)
| 75-80-9 |
|
Ethyl iodoacetate (pract)
| 623-48-3 |
|
Isovaleric acid, 99%
| 503-74-2 |
|
n-Acetylmuramic acid, 97%
| 10597-89-4 |
|
2,5-Pyrazinedicarboxylic Acid Dihydrate, 97%
| 0-01-1 |
|
Aleuritic Acid, 95%
| 533-87-9 |
|
4-Nitro-DL-Phenylalanine, Hydrate, 99%
| 2922-40-9 |
|
4'-Bromo-4-Chlorobutyrophenone, 99%
| 4559-96-0 |
|
Tetracosanoic Acid, 99%(GC)
| 557-59-5 |
|
Phthalhydrazide, 99%
| 1445-69-8 |
|
Monoacetin (Contains Mixed Analogs), ca. 40% as Monoacetin
| 26446-35-5 |
|
N-Alpha-P-Tosyl-L-Arginine Methyl Ester Hydrochloride ,99%
| 1784-03-8 |
|
4,5-Diphenyl-4-Oxazoline-2-Thione, 98%
| 6670-13-9 |
|
1,2-Dibromo-3,5-Difluorobenzene, 99%
| 139215-43-3 |
|
3',4'-(Didodecyloxy)acetophenone, 97% (GC)
| 0-00-1 |
|
Coumarin 500, Laser Grade, 98% (UV-Vis)
| 52840-38-7 |
|
Spermidine, 99%
| 124-20-9 |
|
Potassium hexafluorophosphate, 99%
| 17084-13-8 |
|
3'-Aminoacetanilide Hydrochloride (Pract)
| 621-35-2 |
|
1-Naphthylacetonitrile, 97%
| 132-75-2 |
|
3-Chloropropionic acid, 98%
| 107-94-8 |
|
4-Bromophenylhydrazine Hydrochloride, 98% (uv-vis)
| 622-88-8 |
|
1-Adamantanol, 99%
| 768-95-6 |
|
2-Nitrobiphenyl, 97%
| 85-99-4 |
|
Dicobalt Octacarbonyl
| 10210-68-1 |
|
2,4-Dimethoxypyrimidine, 99+%
| 3551-55-1 |
|
5-Aminovaleric Acid Hydrochloride, 98%
| 627-95-2 |
|
4,9-Dioxa-1,12-Dodecanediamine, 97%
| 7300-34-7 |
|
9-Hydroxy-9-fluorenecarboxylic acid, 94%
| 467-69-6 |
|
2-Nitro-m-xylene, 99%
| 81-20-9 |
|
Iodoacetonitrile, 95%
| 624-75-9 |
|
3-Phenyl-5-isoxalone, 97%
| 1076-59-1 |
|
2,4,6,-Triphenylpyrylium chloride, 98% (titr.)
| 40836-01-9 |
|
Cis,cis,cis,cis-1,2,3,4-cyclopentanetetra carboxylic acid, 98%
| 3786-91-2 |
|
L-2,4-Diaminobutyric Acid Dihydrochloride 98%
| 1883-09-6 |
|
Triheptylamine, 96% (GC)
| 2411-36-1 |
|
Diethyl chlorophosphate, 95%
| 814-49-3 |
|
E-1,3-Dichloropropene, 97%
| 542-75-6 |
|
P-Hexylphenol, 99% (GC)
| 2446-69-7 |
|
(2,5-Dimethoxyphenyl)acetic acid, 97%
| 1758-25-4 |
|
2-Methyllactic acid, 99+% (Titr.)
| 594-61-6 |
|
2-Bromolauric acid, 95%
| 111-56-8 |
|
Fumaric acid monoethyl ester, 95%
| 2459-05-4 |
|
5-Chloroindole-2-carboxylic acid, 98%
| 10517-21-2 |
|
Dimethyl chlorothiophospate, 97%
| 2524-03-0 |
|
Gamma-Benzyl L-Glutamate, 99+%
| 1676-73-9 |
|
4'-Isocyanatobenzo-18-Crown-6, 99%
| 0-01-1 |
|
Lithium tri-sec-butylborohydride 1M solution in THF
| 109-99-9 |
|
Adenosine, 99+%
| 58-61-7 |
|
|