**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 10326-27-9 |Barium chloride dihydrate | > 99 | unlisted |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 25 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Harmful by inhalation.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain. May cause
conjunctivitis.
Skin:
Causes skin irritation. Prolonged contact with the skin, especially
if the skin is wet or moist, causes necrosis.
Ingestion:
Harmful if swallowed. May cause kidney damage. The barium ion is a
muscle poison causing stimulation and then paralysis. Initial
symptoms are gastrointestinal, including nausea, vomiting, colic, and
diarrhea, followed by myocardial and general muscular stimulation
with tingling in the extremities.
Inhalation:
Causes respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Do NOT use mouth-to-mouth resuscitation.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Substance is noncombustible; use agent most
appropriate to extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Minimize dust generation and accumulation.
Avoid contact with eyes, skin, and clothing. Do not ingest or
inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 10326-27-9:
United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE
Malaysia: (listed as barium): 0.5 mg/m3 TWA
Netherlands: (listed as barium): 0.5 mg/m3 MAC
Spain: (listed as barium): 0.5 mg/m3 VLA-ED
CAS# 10361-37-2:
United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE
Malaysia: (listed as barium): 0.5 mg/m3 TWA
Netherlands: (listed as barium): 0.5 mg/m3 MAC
Russia: 0.3 mg/m3 TWA
Spain: (listed as barium): 0.5 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: odorless
pH: 5-8 (5% soln)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 1560 deg C
Freezing/Melting Point: 962 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 59% @ 100C
Specific Gravity/Density: 3.86
Molecular Formula: BaCl2.2H2O
Molecular Weight: 244.28
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Incompatible with bromine trifluoride and 2-furan percarboxylic acid
(explodes at room temperature). Reacts violently with sulfuric acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10326-27-9: CQ8751000
CAS# 10361-37-2: CQ8750000
LD50/LC50:
Not available.
CAS# 10361-37-2: Oral, mouse: LD50 = 150 mg/kg; Oral, rat: LD50 =
118 mg/kg; Oral, rat: LD50 = 397 mg/kg.
Carcinogenicity:
Barium chloride dihydrate -
Not listed by ACGIH, IARC, or NTP.
Barium chloride anhydrous -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
IMO
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
RID/ADR
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 20 Harmful by inhalation.
R 25 Toxic if swallowed.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10326-27-9: 1
CAS# 10361-37-2: 1
Canada
CAS# 10361-37-2 is listed on Canada's DSL List.
CAS# 10326-27-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 10361-37-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10326-27-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 10361-37-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 4/23/1999 Revision #6 Date: 8/18/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 0-01-1 |
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3,6-Dihydroxypyridazine, 99%
| 123-33-1 |
|
Barium Chloride, Anhydrous
| 10361-37-2 |
|
Barium chloride dihydrate
| 10326-27-9 |
|
Barium Chloride Solution 10%
| 64-02-8 |
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(R)-(-)-N-alpha-Benzyl-N-beta-BOC-D-hydrazinoalanine,
| 0-01-1 |
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4-Nitrophenyl chloroacetate
| 79328-69-1 |
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(4-Bromomethylbenzyl)triphenylphosphonium bromide
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Artemisinin, 98%
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4-Amino-5-Chloro-2-Methoxybenzoic Acid, 98+%
| 7206-70-4 |
|
4-Iodophenoxyacetic Acid, 90%
| 1878-94-0 |
|
Benzyloxyacetaldehyde, 98%
| 60656-87-3 |
|
4-Aminopyrimidine, 98%
| 591-54-8 |
|
4-Carbethoxy-2-Ethyl-3-Methyl-2-Cyclohexen-1-One, Tech.
| 51051-65-1 |
|
2-Methoxycyclohexanone
| 7429-44-9 |
|
3-Methoxy-2,4,5-trifluorobenzoic acid, 97%
| 11281-65-5 |
|
N-Benzoylphenylenediamine, 98%
| 17625-83-1 |
|
3-Amino-4-methoxy-N-(3-trifluoromethylphenyl)benzamide, 98%
| 24304-49-2 |
|
2,4-Dichloro-6,7-dimethoxyquinazoline, 97%
| 27631-29-4 |
|
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| 0-01-1 |
|
Sulforhodamine B, laser grade
| 2609-88-3 |
|
2-Nitrophenyl Octyl Ether, 98%
| 37682-29-4 |
|
1,3-Dimethyltetravinyldisiloxane, 95%
| 16045-78-6 |
|
Ethyl 6,7,8-trifluoro-4-oxohydroquinoline-3-carboxylate
| 79660-46-1 |
|
2-Chloro-5-picoline
| 18368-64-4 |
|
(3-Methylcyclohex-1-enylmethyl)trimethylsilane, 99%
| 0-01-1 |
|
Barium Diphenylamine 4-Sulfonate
| 6211-24-1 |
|
4-Hydroxy-3-nitrobenzonitrile, 97%
| 3272-08-0 |
|
(R)-(-)-1-Aminoindane, 97%
| 10277-74-4 |
|
(S)-(+)-1-Aminoindane, 97%
| 61341-86-4 |
|
6,7-Dimethoxy-2,4(1H,3H)-quinazolinedione, 97%
| 28888-44-0 |
|
2-Hydroxydiphenylmethane, 98%
| 28994-41-4 |
|
Sudan Orange G
| 2051-85-6 |
|
3-Amino-4-pyrazolecarboxamide hemisulfate, 95%
| 27511-79-1 |
|
3-Chloro-2-fluoroaniline, 98%
| 2106-04-9 |
|
4-Methylphthalonitrile, 98%
| 63089-50-9 |
|
1-Propanesulfonic acid sodium salt monohydrate, HPLC grade, 99+%
| 14533-63-2 |
|
Phenyltrimethylsilane, 99%
| 768-32-1 |
|
Potassium tetrachloropalladate(ii)
| 10025-98-6 |
|
1-Butanesulfonic acid sodium salt monohydrate, HPLC grade, 99+%
| 2386-54-1 |
|
Tetraethylammonium hydrogensulfate, HPLC grade, 99+%
| 16873-13-5 |
|
Tetramethylammonium hydrogensulfate, HPLC grade, 99+%
| 80526-82-5 |
|
Pyridine, Extra Dry, Water <50 ppm
| 110-86-1 |
|
(S)-cis-Verbenol
| 18881-04-4 |
|
Ethyl chlorothioformate
| 2941-64-2 |
|
Telomer H12 - THAM 5.7
| 0-01-1 |
|
Methyl nonadecafluorodecanoate, 94%
| 307-79-9 |
|
4-Bromo-2,3,5,6-tetrafluoropyridine, 98%
| 3511-90-8 |
|
2,2'-Dimethoxy-1,1'-binaphthyl, 98%
| 2960-93-2 |
|
DL-1,1'-Bi(2-naphthyl diacetate), 98%
| 0-01-1 |
|
|