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MSDS 
:
 Barium Chloride Solution 10%
CAS 
:
 64-02-8
SYNONYMS 
:
 Barium dichloride.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 64-02-8 |Tetrasodium EDTA | < 0.1 | 200-573-9 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 87.9 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 10326-27-9 |Barium chloride dihydrate | 12 | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 10361-37-2 |Barium chloride anhydrous | - | 233-788-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat
symptomatically and supportively. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash hands before eating. Use with adequate ventilation. Avoid
contact with skin and eyes. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Appearance: clear, colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 212 deg F
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.0
Molecular Formula: Mixture
Molecular Weight: Not available

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Barium chloride is incompatible with bromine trifluoride and 2-furan
percarboxylic acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 64-02-8: AH5075000
CAS# 7732-18-5: ZC0110000
CAS# 10326-27-9: CQ8751000
CAS# 10361-37-2: CQ8750000
LD50/LC50:
CAS# 64-02-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Moderate.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 10326-27-9.
CAS# 10361-37-2: Oral, rat: LD50 = 118 mg/kg.
Carcinogenicity:
Tetrasodium EDTA -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Barium chloride dihydrate -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as **
Barium chloride anhydrous -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as **
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 64-02-8: 2
CAS# 7732-18-5: No information available.
CAS# 10326-27-9: 1
CAS# 10361-37-2: 1
United Kingdom Occupational Exposure Limits

Canada
CAS# 64-02-8 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 10361-37-2 is listed on Canada's DSL List.
CAS# 64-02-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 10326-27-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 10361-37-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10326-27-9: OEL-AUSTRALIA:TWA 0.5 mg(Ba)/m3
OEL-AUSTRIA:TWA 0.5 mg(Ba)/m3
OEL-BELGIUM:TWA 0.5 mg(Ba)/m3
OEL-DENMARK:TWA 0.5 mg(Ba)/m3
OEL-FINLAND:TWA 0.5 mg(Ba)/m3
OEL-GERMANY:TWA 0.5 mg(Ba)/m3 (total dust)
OEL-HUNGARY:STEL 0.5 mg(Ba)/m3
OEL-THE NETHERLANDS:TWA 0.5 mg(Ba)/m3
OEL-THE PHILIPPINES:TWA 0.5 mg(Ba)/m3
OEL-POLAND:TWA 0.5 mg(Ba)/m3;STEL 1.5 mg(Ba)/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ba)/m3;STEL 1 mg(Ba)/m
OEL-TURKEY:TWA 0.5 mg(Ba)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ba)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 10361-37-2: OEL-AUSTRALIA:TWA 0.5 mg(Ba)/m3
OEL-AUSTRIA:TWA 0.5 mg(Ba)/m3
OEL-BELGIUM:TWA 0.5 mg(Ba)/m3
OEL-DENMARK:TWA 0.5 mg(Ba)/m3
OEL-FINLAND:TWA 0.5 mg(Ba)/m3
OEL-GERMANY:TWA 0.5 mg(Ba)/m3 (total dust)
OEL-HUNGARY:STEL 0.5 mg(Ba)/m3
OEL-THE NETHERLANDS:TWA 0.5 mg(Ba)/m3
OEL-THE PHILIPPINES:TWA 0.5 mg(Ba)/m3
OEL-POLAND:TWA 0.5 mg(Ba)/m3;STEL 1.5 mg(Ba)/m3
OEL-RUSSIA:STEL 0.3 mg/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ba)/m3;STEL 1 mg(Ba)/m
OEL-TURKEY:TWA 0.5 mg(Ba)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ba)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 64-02-8 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 10326-27-9 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
CAS# 10361-37-2 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 12/30/1998 Revision #2 Date: 10/12/2001

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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NAMECAS
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4-Nitrophenyl chloroacetate 79328-69-1
(4-Bromomethylbenzyl)triphenylphosphonium bromide 0-01-1
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4-Amino-5-Chloro-2-Methoxybenzoic Acid, 98+% 7206-70-4
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4-Aminopyrimidine, 98% 591-54-8
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2-Methoxycyclohexanone 7429-44-9
3-Methoxy-2,4,5-trifluorobenzoic acid, 97% 11281-65-5
N-Benzoylphenylenediamine, 98% 17625-83-1
3-Amino-4-methoxy-N-(3-trifluoromethylphenyl)benzamide, 98% 24304-49-2
2,4-Dichloro-6,7-dimethoxyquinazoline, 97% 27631-29-4
(R)-(-)-N-alpha-Benzyl-N-beta-BOC-D-Hydrazinovaline 0-01-1
Sulforhodamine B, laser grade 2609-88-3
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1,3-Dimethyltetravinyldisiloxane, 95% 16045-78-6
Ethyl 6,7,8-trifluoro-4-oxohydroquinoline-3-carboxylate 79660-46-1
2-Chloro-5-picoline 18368-64-4
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6,7-Dimethoxy-2,4(1H,3H)-quinazolinedione, 97% 28888-44-0
2-Hydroxydiphenylmethane, 98% 28994-41-4
Sudan Orange G 2051-85-6
3-Amino-4-pyrazolecarboxamide hemisulfate, 95% 27511-79-1
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4-Methylphthalonitrile, 98% 63089-50-9
1-Propanesulfonic acid sodium salt monohydrate, HPLC grade, 99+% 14533-63-2
Phenyltrimethylsilane, 99% 768-32-1
Potassium tetrachloropalladate(ii) 10025-98-6
1-Butanesulfonic acid sodium salt monohydrate, HPLC grade, 99+% 2386-54-1
Tetraethylammonium hydrogensulfate, HPLC grade, 99+% 16873-13-5
Tetramethylammonium hydrogensulfate, HPLC grade, 99+% 80526-82-5
Pyridine, Extra Dry, Water <50 ppm 110-86-1
(S)-cis-Verbenol 18881-04-4
Ethyl chlorothioformate 2941-64-2
Telomer H12 - THAM 5.7 0-01-1
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2,2'-Dimethoxy-1,1'-binaphthyl, 98% 2960-93-2
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