**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-09-1 |2-Chloropyridine | 99.0 | 203-646-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
Causes gastrointestinal tract irritation.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Use
with adequate ventilation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 109-09-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 3.7 mbar @ 25 C
Viscosity: Not available.
Boiling Point: 168.0 - 170.0 deg C
Freezing/Melting Point: -46 deg C
Autoignition Temperature: 585 deg C ( 1,085.00 deg F)
Flash Point: 64 deg C ( 147.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 27 g/l (20 c)
Specific Gravity/Density: 1.2100g/cm3
Molecular Formula: C5H4ClN
Molecular Weight: 113.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
nitrogen, chlorine, phosgene gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-09-1: US5950000
LD50/LC50:
CAS# 109-09-1: Oral, mouse: LD50 = 110 mg/kg; Skin, rabbit: LD50 =
64 mg/kg.
Carcinogenicity:
2-Chloropyridine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Do not allow to enter soil and watercourses. Avoid vapour emissions.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 2-CHLOROPYRIDINE
Hazard Class: 6.1
UN Number: 2822
Packing Group: II
IMO
Shipping Name: 2-CHLOROPYRIDINE
Hazard Class: 6.1
UN Number: 2822
Packing Group: II
RID/ADR
Shipping Name: 2-CHLOROPYRIDINE
Hazard Class: 6.1
UN Number: 2822
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 27 Take off immediately all contaminated clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 109-09-1: No information available.
Canada
CAS# 109-09-1 is listed on Canada's NDSL List.
CAS# 109-09-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-09-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/03/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
5-Formyl-2-furansulfonic acid, sodium salt, 98%
| 31795-44-5 |
|
1,10-Phenanthroline monohydrate, reagent ACS
| 66-71-7 |
|
Phenol Red Sodium Salt, Reagent ACS
| 34487-61-1 |
|
Phloxine B
| 18472-87-2 |
|
(1-Aminohexyl)phosphonic acid, 97%
| 63207-60-3 |
|
Pyruvic acid, sodium salt, 99+%
| 113-24-6 |
|
(1-Amino-2-methylpropyl)phosponic acid, 97%
| 18108-24-2 |
|
Rose bengal (cert)
| 632-69-9 |
|
Safranin O certified
| 477-73-6 |
|
(1-Amino-3-Methylbutyl)Phosphonic Acid, 97%
| 20459-60-3 |
|
Diethyldithiocarbamic acid, sodium salt, trihydrate
| 148-18-5 |
|
Sudan iii (cert)
| 85-86-9 |
|
Sudan IV (Cert), 95% (UV-VIS)
| 85-83-6 |
|
Sudan Black B (Cert), 99% (UV-VIS)
| 4197-25-5 |
|
Thenoyltrifluoroacetone, 99%
| 326-91-0 |
|
Thionin (Cert)
| 581-64-6 |
|
(1-Amino-2-methylbutyl)phosphonic acid, 97%
| 20459-61-4 |
|
Toluidine Blue O (Cert)
| 92-31-9 |
|
(1-Aminooctyl)phosphonic acid, 97%
| 94219-58-6 |
|
tris-(Hydroxymethyl)-aminomethane hydrochloride, 99+%
| 1185-53-1 |
|
Brilliant Blue G
| 6104-58-1 |
|
Ethidium Bromide, 95%
| 1239-45-8 |
|
Ponceau S
| 6226-79-5 |
|
Pyronin Y, certified
| 92-32-0 |
|
Nitro BT, 85% (Titr.)
| 298-83-9 |
|
(r,r)-Dithiothreitol, 98% (titr.)
| 3483-12-3 |
|
Dithioerythritol, 95% (Titr.)
| 6892-68-8 |
|
Guanidine Thiocyanate, 99% (Titr.)
| 593-84-0 |
|
D(+)-Biotin, 98%
| 58-85-5 |
|
2-(4-Morpholino)ethanesulfonic Acid, 99% (titr.)
| 4432-31-9 |
|
Diethylmethylphosphonate, 96%
| 683-08-9 |
|
2,2-Bis(Hydroxymethyl)-2,2',2"-Nitrilo- Triethanol, 99+%
| 6976-37-0 |
|
ACES, 96%
| 7365-82-4 |
|
HEPES, 99%
| 7365-45-9 |
|
Tricine, 98+%
| 5704-04-1 |
|
Caps (3-Cyclohexylamino-1-Propanesulfonic Acid), 99%
| 1135-40-6 |
|
4'-Bromoacetanilide, 98%
| 103-88-8 |
|
l-Isoleucine, 99%
| 73-32-5 |
|
l-Leucine, 99%
| 61-90-5 |
|
L-(+)-Ornithine-Hydrochloride, 99%
| 3184-13-2 |
|
l-Threonine, 98%
| 72-19-5 |
|
Benzamidine hydrochloride, 99% (titr.)
| 1670-14-0 |
|
2,3-Dihydrofuran, 98%
| 1191-99-7 |
|
Ches 98+%
| 103-47-9 |
|
FMOC-L-Asparagin Acid-Beta-T-Butylester, 98%
| 71989-14-5 |
|
2-Chloropyridine, 99%
| 109-09-1 |
|
N,N'-Diisopropylcarbodiimide, 99%
| 693-13-0 |
|
N,N-Diisopropylethylamine
| 7087-68-5 |
|
4-Dimethylaminopyridine, 99%
| 1122-58-3 |
|
D-Pantothenic Acid Calcium Salt, 97.5-102.0% (from Calcium Content,on
| 137-08-6 |
|
|