**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 20624-25-3 |Sodium diethyldithiocarbamate trihydra| >99 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May be harmful if swallowed. Contact with stomach acid may liberate
carbon disulfide which primarily affects the nervous,
cardiovascular, and reproductive systems.
Inhalation:
Causes respiratory tract irritation.
Chronic:
May cause reproductive and fetal effects. Prolonged or repeated
exposure affects the nervous system.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid breathing dust.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store protected from moisture. Refrigeration has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 148-18-5:
Germany: 2 mg/m3 TWA (inhalable fraction)
Netherlands: 2 mg/m3 MAC
CAS# 20624-25-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: very slightly yellow
Odor: Not available.
pH: 11.6 (10% aq soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 95-98.5 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C5H10NNaS2.3H2O
Molecular Weight: 225.31
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 148-18-5: EZ6475000
CAS# 20624-25-3: EZ6550000
LD50/LC50:
CAS# 148-18-5: Oral, mouse: LD50 = 1500 mg/kg; Oral, rabbit: LD50 =
500 mg/kg; Oral, rat: LD50 = 1500 mg/kg; Skin, rat: LD50 = >1 gm/kg.
CAS# 20624-25-3: Oral, mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 =
1500 mg/kg.
Carcinogenicity:
Sodium diethyldithiocarbamate, anhydrous -
Not listed by ACGIH, IARC, or NTP.
Sodium diethyldithiocarbamate trihydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 148-18-5: 3
CAS# 20624-25-3: 2
Canada
CAS# 148-18-5 is listed on Canada's DSL List.
CAS# 148-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 20624-25-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 148-18-5 is listed on the TSCA inventory.
CAS# 20624-25-3 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 10/15/1998 Revision #3 Date: 5/26/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
5-Formyl-2-furansulfonic acid, sodium salt, 98%
| 31795-44-5 |
|
1,10-Phenanthroline monohydrate, reagent ACS
| 66-71-7 |
|
Phenol Red Sodium Salt, Reagent ACS
| 34487-61-1 |
|
Phloxine B
| 18472-87-2 |
|
(1-Aminohexyl)phosphonic acid, 97%
| 63207-60-3 |
|
Pyruvic acid, sodium salt, 99+%
| 113-24-6 |
|
(1-Amino-2-methylpropyl)phosponic acid, 97%
| 18108-24-2 |
|
Rose bengal (cert)
| 632-69-9 |
|
Safranin O certified
| 477-73-6 |
|
(1-Amino-3-Methylbutyl)Phosphonic Acid, 97%
| 20459-60-3 |
|
Diethyldithiocarbamic acid, sodium salt, trihydrate
| 148-18-5 |
|
Sudan iii (cert)
| 85-86-9 |
|
Sudan IV (Cert), 95% (UV-VIS)
| 85-83-6 |
|
Sudan Black B (Cert), 99% (UV-VIS)
| 4197-25-5 |
|
Thenoyltrifluoroacetone, 99%
| 326-91-0 |
|
Thionin (Cert)
| 581-64-6 |
|
(1-Amino-2-methylbutyl)phosphonic acid, 97%
| 20459-61-4 |
|
Toluidine Blue O (Cert)
| 92-31-9 |
|
(1-Aminooctyl)phosphonic acid, 97%
| 94219-58-6 |
|
tris-(Hydroxymethyl)-aminomethane hydrochloride, 99+%
| 1185-53-1 |
|
Brilliant Blue G
| 6104-58-1 |
|
Ethidium Bromide, 95%
| 1239-45-8 |
|
Ponceau S
| 6226-79-5 |
|
Pyronin Y, certified
| 92-32-0 |
|
Nitro BT, 85% (Titr.)
| 298-83-9 |
|
(r,r)-Dithiothreitol, 98% (titr.)
| 3483-12-3 |
|
Dithioerythritol, 95% (Titr.)
| 6892-68-8 |
|
Guanidine Thiocyanate, 99% (Titr.)
| 593-84-0 |
|
D(+)-Biotin, 98%
| 58-85-5 |
|
2-(4-Morpholino)ethanesulfonic Acid, 99% (titr.)
| 4432-31-9 |
|
Diethylmethylphosphonate, 96%
| 683-08-9 |
|
2,2-Bis(Hydroxymethyl)-2,2',2"-Nitrilo- Triethanol, 99+%
| 6976-37-0 |
|
ACES, 96%
| 7365-82-4 |
|
HEPES, 99%
| 7365-45-9 |
|
Tricine, 98+%
| 5704-04-1 |
|
Caps (3-Cyclohexylamino-1-Propanesulfonic Acid), 99%
| 1135-40-6 |
|
4'-Bromoacetanilide, 98%
| 103-88-8 |
|
l-Isoleucine, 99%
| 73-32-5 |
|
l-Leucine, 99%
| 61-90-5 |
|
L-(+)-Ornithine-Hydrochloride, 99%
| 3184-13-2 |
|
l-Threonine, 98%
| 72-19-5 |
|
Benzamidine hydrochloride, 99% (titr.)
| 1670-14-0 |
|
2,3-Dihydrofuran, 98%
| 1191-99-7 |
|
Ches 98+%
| 103-47-9 |
|
FMOC-L-Asparagin Acid-Beta-T-Butylester, 98%
| 71989-14-5 |
|
2-Chloropyridine, 99%
| 109-09-1 |
|
N,N'-Diisopropylcarbodiimide, 99%
| 693-13-0 |
|
N,N-Diisopropylethylamine
| 7087-68-5 |
|
4-Dimethylaminopyridine, 99%
| 1122-58-3 |
|
D-Pantothenic Acid Calcium Salt, 97.5-102.0% (from Calcium Content,on
| 137-08-6 |
|
|