**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-96-6 |3-Pyrroline | | 203-723-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Causes burns.Hygroscopic (absorbs moisture from
the air).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Containers may explode in the heat of a fire. Flammable liquid
and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 109-96-6:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light yellow
Odor: ammonia-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 90 - 91 deg C @760mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -18 deg C ( -0.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with water
Specific Gravity/Density: 0.910
Molecular Formula: C4H7N
Molecular Weight: 69.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-96-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Pyrroline -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2924
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 109-96-6: No information available.
Canada
CAS# 109-96-6 is listed on Canada's NDSL List.
CAS# 109-96-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-96-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/03/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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tert-Butyl 1-piperazinecarboxylate
| 57260-71-6 |
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Benzyl 1-piperazinecarboxylate
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|
1-N-BOC-Aminocyclopentanecarboxylic acid
| 35264-09-6 |
|
3-Fluoro-4-(trifluoromethyl)benzoic acid
| 115754-21-7 |
|
Brij?? 78
| 9005-00-9 |
|
7-Methylphthalide, 97%
| 2211-84-9 |
|
4-Aminobenzaldehyde
| 556-18-3 |
|
5-Phenylvaleric acid, 99%
| 2270-20-4 |
|
Aerosil 200
| 112945-52-5 |
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Brewers yeast
| 68876-77-7 |
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4-(Trimethylsilyl)-3-butyn-2-one
| 5930-98-3 |
|
Cinnamyl Chloride, 95% Trans
| 21087-29-6 |
|
1,7-Dihydroxynaphthalene, 98%
| 575-38-2 |
|
4-Methoxy-alpha-toluenethiol
| 6258-60-2 |
|
N-Butyl 2-Methylbutyrate, 98+%
| 15706-73-7 |
|
1-Naphthalenemethylamine
| 118-31-0 |
|
3,4-(Methylenedioxy)phenylacetonitrile
| 4439-02-5 |
|
Benzyl isocyanide, 98%
| 10340-91-7 |
|
2,5-Dichlorobenzenethiol, 98%
| 5858-18-4 |
|
Indazole, 96%
| 271-44-3 |
|
1-(2-Bromoethoxy)2-ethoxybenzene
| 3259-03-8 |
|
2,6-Di-tert-butylpyridine, 97%
| 585-48-8 |
|
p-Bromovalerophenone, 98%
| 7295-44-5 |
|
3-(Trifluoromethoxy)aniline, 97% (titr.)
| 1535-73-5 |
|
2-(4-Aminophenyl)-1,1,1,3,3,3-hexafluoro-2 -propanol
| 722-92-9 |
|
4-Hydroxy-6-methyl-3-nitro-2-pyridone
| 4966-90-9 |
|
2-Chloro-3-nitrobenzoic acid
| 3970-35-2 |
|
1,3-Diaminopropane, 99%
| 109-76-2 |
|
Citric acid, anhydrous
| 77-92-9 |
|
Cleaning Solution
| 1333-82-0 |
|
FOLIC ACID
| 59-30-3 |
|
Sodium hydroxide, solid, pellets
| 497-19-8 |
|
Clove Oil
| 8000-34-8 |
|
2,6-Dimethylbenzoic Acid, 99%
| 632-46-2 |
|
Octadecylamine hydrochloride, 99% (titr.)
| 1838-08-0 |
|
Bis(hexylene glycolato)diboron, 97%
| 230299-21-5 |
|
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
| 214360-73-3 |
|
5-Bromo-2-Chloropyrimidine
| 32779-36-5 |
|
4-Amino-2-chlorophenol
| 3964-52-1 |
|
5-Chloro-2-mercaptobenzothiazole, 90%
| 5331-91-9 |
|
4-Bromo-2-nitrophenol
| 7693-52-9 |
|
Benzoyleneurea
| 86-96-4 |
|
2-(Aminomethyl)benzimidazole dihydrochloride hydrate
| 5993-91-9 |
|
4-Chlorophenoxyacetyl chloride
| 4122-68-3 |
|
l-Histidine monohydrochloride, 1-hydrate, 98% (titr.)
| 5934-29-2 |
|
3-Amino-5-phenylpyrazole
| 1572-10-7 |
|
N-Benzyl-4-piperidone
| 3612-20-2 |
|
3,5-Dichlorobenzoyl chloride
| 2905-62-6 |
|
Methyl 3-formylbenzoate
| 52178-50-4 |
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3-Pyrroline
| 109-96-6 |
|
|