**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4122-68-3 |4-Chlorophenoxyacetyl chloride | ca. 100 | 223-923-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do
NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Use only in a chemical fume hood. This product may be under
pressure; cool before opening. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area. Store protected
from moisture. Store under nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4122-68-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 142 deg C @17mmHg
Freezing/Melting Point: 19 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.314
Molecular Formula: C8H6Cl2O2
Molecular Weight: 205.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Moisture sensitive.
Conditions to Avoid:
Excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Alcohols, oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4122-68-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Chlorophenoxyacetyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4122-68-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4122-68-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4122-68-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/03/2003 Revision #2 Date: 10/10/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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tert-Butyl 1-piperazinecarboxylate
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Benzyl 1-piperazinecarboxylate
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1-N-BOC-Aminocyclopentanecarboxylic acid
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3-Fluoro-4-(trifluoromethyl)benzoic acid
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Brij?? 78
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7-Methylphthalide, 97%
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4-Aminobenzaldehyde
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5-Phenylvaleric acid, 99%
| 2270-20-4 |
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Aerosil 200
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Brewers yeast
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4-(Trimethylsilyl)-3-butyn-2-one
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Cinnamyl Chloride, 95% Trans
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1,7-Dihydroxynaphthalene, 98%
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4-Methoxy-alpha-toluenethiol
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N-Butyl 2-Methylbutyrate, 98+%
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1-Naphthalenemethylamine
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|
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| 10340-91-7 |
|
2,5-Dichlorobenzenethiol, 98%
| 5858-18-4 |
|
Indazole, 96%
| 271-44-3 |
|
1-(2-Bromoethoxy)2-ethoxybenzene
| 3259-03-8 |
|
2,6-Di-tert-butylpyridine, 97%
| 585-48-8 |
|
p-Bromovalerophenone, 98%
| 7295-44-5 |
|
3-(Trifluoromethoxy)aniline, 97% (titr.)
| 1535-73-5 |
|
2-(4-Aminophenyl)-1,1,1,3,3,3-hexafluoro-2 -propanol
| 722-92-9 |
|
4-Hydroxy-6-methyl-3-nitro-2-pyridone
| 4966-90-9 |
|
2-Chloro-3-nitrobenzoic acid
| 3970-35-2 |
|
1,3-Diaminopropane, 99%
| 109-76-2 |
|
Citric acid, anhydrous
| 77-92-9 |
|
Cleaning Solution
| 1333-82-0 |
|
FOLIC ACID
| 59-30-3 |
|
Sodium hydroxide, solid, pellets
| 497-19-8 |
|
Clove Oil
| 8000-34-8 |
|
2,6-Dimethylbenzoic Acid, 99%
| 632-46-2 |
|
Octadecylamine hydrochloride, 99% (titr.)
| 1838-08-0 |
|
Bis(hexylene glycolato)diboron, 97%
| 230299-21-5 |
|
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
| 214360-73-3 |
|
5-Bromo-2-Chloropyrimidine
| 32779-36-5 |
|
4-Amino-2-chlorophenol
| 3964-52-1 |
|
5-Chloro-2-mercaptobenzothiazole, 90%
| 5331-91-9 |
|
4-Bromo-2-nitrophenol
| 7693-52-9 |
|
Benzoyleneurea
| 86-96-4 |
|
2-(Aminomethyl)benzimidazole dihydrochloride hydrate
| 5993-91-9 |
|
4-Chlorophenoxyacetyl chloride
| 4122-68-3 |
|
l-Histidine monohydrochloride, 1-hydrate, 98% (titr.)
| 5934-29-2 |
|
3-Amino-5-phenylpyrazole
| 1572-10-7 |
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| 3612-20-2 |
|
3,5-Dichlorobenzoyl chloride
| 2905-62-6 |
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Methyl 3-formylbenzoate
| 52178-50-4 |
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3-Pyrroline
| 109-96-6 |
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