**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-40-0 |Diethylene triamine | 100.0 | 203-865-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 21/22 34 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Causes burns. May
cause sensitization by skin contact.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May result in corneal injury. May cause
irreversible eye injury.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal tract burns. May cause corrosion and
permanent tissue destruction of the esophagus and digestive tract.
Inhalation:
May cause asthmatic attacks due to allergic sensitization of the
respiratory tract. Causes respiratory tract irritation with possible
burns.
Chronic:
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. Repeated
exposure may cause allergic respiratory reaction (asthma).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Use water spray to dilute spill to
a non-flammable mixture. Use water spray to disperse the gas/vapor.
Remove all sources of ignition. Provide ventilation. Do not get water
inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Store in a tightly closed container.
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Keep away from acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 111-40-0:
United Kingdom, WEL - TWA: 1 ppm TWA; 4.3 mg/m3 TWA
United Kingdom, WEL - STEL: 3 ppm STEL; 12.9 mg/m3 STEL
Belgium - TWA: 1 ppm VLE; 4.3 mg/m3 VLE
France - VME: 1 ppm VME; 4 mg/m3 VME
Malaysia: 1 ppm TWA; 4.2 mg/m3 TWA
Netherlands: 1 ppm MAC; 4 mg/m3 MAC
Spain: 1 ppm VLA-ED; 4.3 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to yellow
Odor: amine-like
pH: Strongly alkaline
Vapor Pressure: 0.37 mm Hg @ 20C
Viscosity: 0.0714 Ps 20 C
Boiling Point: 207 deg C
Freezing/Melting Point: -35 deg C
Autoignition Temperature: 395 deg C ( 743.00 deg F)
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: 2.0%
Explosion Limits, upper: 11.6%
Decomposition Temperature: Not available.
Solubility in water: soluble in water.
Specific Gravity/Density: .9586
Molecular Formula: C4H13N3
Molecular Weight: 103.1111
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Corrosive to copper and its alloys, ignites on contact with cellulose
nitrate of high surface area, forms a shock-sensitive explosive with
nitromethane, and is incompatible with acids, chlorine, halogenated
compounds, oxidizing agents and reactive organic compounds.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, amines.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-40-0: IE1225000
LD50/LC50:
CAS# 111-40-0: Dermal, guinea pig: LD50 = 170 uL/kg; Draize test,
rabbit, skin: 500 mg; Oral, rat: LD50 = 1080 mg/kg; Skin, rabbit:
LD50 = 1090 mg/kg.
Carcinogenicity:
Diethylene triamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Water flea Daphnia: EC50 = 330 mg/L; 24 Hr.; Unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIETHYLENETRIAMINE
Hazard Class: 8
UN Number: 2079
Packing Group: II
IMO
Shipping Name: DIETHYLENETRIAMINE
Hazard Class: 8
UN Number: 2079
Packing Group: II
RID/ADR
Shipping Name: DIETHYLENETRIAMINE
Hazard Class: 8
UN Number: 2079
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 111-40-0: 2
Canada
CAS# 111-40-0 is listed on Canada's DSL List.
CAS# 111-40-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-40-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/07/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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| ALL MSDS PAGES IN THIS GROUP
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|
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| 166964-33-6 |
|
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|
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| 19983-44-9 |
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| 20503-40-6 |
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| 1198-51-2 |
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| 23799-60-2 |
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| 17266-30-7 |
|
Methyl 2-(5-chlorobenzo[b]thiophen-3-yl)acetate, 97%
| 95834-67-6 |
|
2-(3-Methylbenzo[b]thiophen-2-yl)acetic acid, 97%
| 1505-52-8 |
|
5,6-Dihydrouracil, 98%
| 504-07-4 |
|
[(5-Chlorobenzo[b]thiophen-3-yl)methyl](triphenyl)phosphonium
| 175203-96-0 |
|
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| 118337-33-0 |
|
DL-Alpha-Phenylglycine, 99%
| 2835-06-5 |
|
2-Bromo-1-(5-chloro-3-methylbenzo[b]thiophen-2-yl)ethan-1-one, 95+%
| 175203-97-1 |
|
1-[(4-Methylphenyl)thio]acetone, 97%
| 1200-13-1 |
|
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| 51527-19-6 |
|
2-Chloro-1-(5-chloro-3-methylbenzo[b]thiophen-2-yl)ethan-1-one, 97%
| 156801-47-7 |
|
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| 111-40-0 |
|
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| 22053-74-3 |
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| 306935-52-4 |
|
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| 167832-66-8 |
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| 175204-02-1 |
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| 175204-04-3 |
|
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| 175204-09-8 |
|
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| 175204-10-1 |
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| 270262-89-0 |
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| 24386-17-2 |
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| 13577-19-0 |
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| 53730-99-7 |
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| 85864-84-2 |
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| 14938-58-0 |
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2-(2-Iodophenyl)acetic acid, 97%
| 18698-96-9 |
|
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| 1710-62-9 |
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| 1121-37-5 |
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