**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 112-34-5 |Diethylene glycol monobutyl ether | 99 | 203-961-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes.
Potential Health Effects
Eye:
Causes eye irritation. May cause transient corneal injury.
Skin:
Causes skin irritation. May be absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
May cause kidney injury. Repeated exposure may cause central nervous
system damage. May cause cyanosis (bluish discoloration of skin due
to deficient oxygenation of the blood), acidosis, and quick, shallow
breathing.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
Administration of Sodium bicarbonate may be of value to treat
acidosis. Monitor kidney and liver function and arterial blood gases
closely.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Containers may explode when heated. Combustible
liquid and vapor.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Use spark-proof tools and explosion
proof equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Avoid ingestion and inhalation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 112-34-5:
Germany: 100 mg/m3 TWA
Netherlands: 9 ppm MAC; 50 mg/m3 MAC
Spain: 100 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Faint, mild, characteristic odor.
pH: Not available.
Vapor Pressure: .01 mm Hg @ 20 deg C
Viscosity: 0.0649 cps @ 20 deg C
Boiling Point: 231 deg C @ 760 mm Hg
Freezing/Melting Point: -68 deg C
Autoignition Temperature: 227.7 deg C ( 441.86 deg F)
Flash Point: 77.7 deg C ( 171.86 deg F)
Explosion Limits, lower: .70 vol %
Explosion Limits, upper: 5.30 vol %
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: .9536 @ 20C
Molecular Formula: C8H18O3
Molecular Weight: 162.23
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 112-34-5: KJ9100000
LD50/LC50:
CAS# 112-34-5: Draize test, rabbit, eye: 20 mg Severe; Draize test,
rabbit, eye: 20 mg/24H Moderate; Oral, mouse: LD50 = 2400 mg/kg;
Oral, mouse: LD50 = 6050 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg;
Oral, rat: LD50 = 5660 mg/kg; Oral, rat: LD50 = 4500 mg/kg; Skin,
rabbit: LD50 = 2700 mg/kg.
Oral, rat: LD50 = 1746-10502 mg/kg
Carcinogenicity:
Diethylene glycol monobutyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = 1300 mg/L; 96 Hr.; Static conditions,
23 degrees CFish: Goldfish: LC50 = 2700 mg/L; 24 Hr.;
UnspecifiedWater flea Daphnia: LC50 = 2850 mg/L; 24 Hr.;
UnspecifiedGoldfish, LC50=2700mg/24hr.; Atlantic silverside,
TL50=2000ppm/96hr.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36 Irritating to eyes.
Safety Phrases:
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 112-34-5: 1
Canada
CAS# 112-34-5 is listed on Canada's DSL List.
CAS# 112-34-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 112-34-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/09/1999 Revision #4 Date: 4/27/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
6-(Benzyloxy)-2-naphthylboronic acid, 97%
| 152915-83-8 |
|
alpha,alpha,alpha-Trifluorotoluene, 99+%
| 98-08-8 |
|
gamma-Phenyl-gamma-butyrolactone, 97%
| 1008-76-0 |
|
Diethylene glycol monobutyl ether
| 112-34-5 |
|
Pyrocatechol Violet, indicator grade
| 115-41-3 |
|
Diethylene Glycol Monoethyl Ether
| 111-90-0 |
|
4-Bromo-1-methyl-1h-pyrazole-5-carbaldehyde, 95+%
| 473528-88-0 |
|
Nitroguanidine, 99%, Moistened With ca 25% Water
| 556-88-7 |
|
[1,2,4]Triazolo[4,3-a]pyridine-3-thiol, 97%
| 6952-68-7 |
|
2,5-Dimethylbenzenesulfonyl chloride, 97%
| 19040-62-1 |
|
o-Ethyltoluene, 99%
| 611-14-3 |
|
4-Chloro-3-(trifluoromethyl)benzenesulfonyl chloride, 97%
| 32333-53-2 |
|
3-(2-Thienyl)benzoic acid, 97%
| 29886-63-3 |
|
4-(3-Thienyl)benzoic acid, 97%
| 29886-64-4 |
|
5-Chloro-3-methylbenzo[b]thiophene, 97%
| 19404-18-3 |
|
5-Chloro-3-methylbenzo[b]thiophene-2-sulfonyl chloride, 97%
| 166964-33-6 |
|
1-(3-Methylbenzo[b]thiophen-2-yl)ethan-1-one, 95+%
| 18781-31-2 |
|
6-Nitro-1h-1lambda~6~-benzo[b]thiophene-1,1-dione, 97%
| 19983-44-9 |
|
6-Amino-1H-1lambda~6~-benzo[b]thiophene-1,1-dione, tech
| 20503-40-6 |
|
3-(Bromomethyl)-5-chlorobenzo[b]thiophene, 95+%
| 1198-51-2 |
|
2-(5-Chlorobenzo[b]thiophen-3-yl)acetonitrile, 97%
| 23799-60-2 |
|
2-(5-Chlorobenzo[b]thiophen-3-yl)acetic acid, 97%
| 17266-30-7 |
|
Methyl 2-(5-chlorobenzo[b]thiophen-3-yl)acetate, 97%
| 95834-67-6 |
|
2-(3-Methylbenzo[b]thiophen-2-yl)acetic acid, 97%
| 1505-52-8 |
|
5,6-Dihydrouracil, 98%
| 504-07-4 |
|
[(5-Chlorobenzo[b]thiophen-3-yl)methyl](triphenyl)phosphonium
| 175203-96-0 |
|
2-Bromo-1-(3-methylbenzo[b]thiophen-2-yl)ethan-1-one,97%
| 118337-33-0 |
|
DL-Alpha-Phenylglycine, 99%
| 2835-06-5 |
|
2-Bromo-1-(5-chloro-3-methylbenzo[b]thiophen-2-yl)ethan-1-one, 95+%
| 175203-97-1 |
|
1-[(4-Methylphenyl)thio]acetone, 97%
| 1200-13-1 |
|
2-(5-Chloro-3-methylbenzo[b]thiophen-2-yl)acetic acid, 97%
| 51527-19-6 |
|
2-Chloro-1-(5-chloro-3-methylbenzo[b]thiophen-2-yl)ethan-1-one, 97%
| 156801-47-7 |
|
Diethylenetriamine
| 111-40-0 |
|
3-Methylbenzo[b]thiophene-2-carbaldehyde, 95+%
| 22053-74-3 |
|
3-Chloro-5-(2-chlorophenyl)isothiazole-4-carboxylic acid, 97%
| 306935-52-4 |
|
2-(Benzyloxy)-6-methoxybenzonitrile, 95+%
| 167832-66-8 |
|
2-[(2-Chlorobenzyl)oxy]-6-methoxybenzonitrile, 97%
| 175204-02-1 |
|
2-Ethoxy-6-(2,2,2-trifluoroethoxy)benzonitrile, tech
| 175204-04-3 |
|
2-Fluoro-6-[(4-methylbenzyl)oxy]benzonitrile, 97%
| 175204-09-8 |
|
2-[(4-Chlorobenzyl)oxy]-6-fluorobenzonitrile, 97%
| 175204-10-1 |
|
4-[(4-Methylphenyl)thio]-3-nitrobenzaldehyde, 95+%
| 270262-89-0 |
|
2-Amino-3-cyano-4,5-di(fur-2-yl)furan, 97%
| 24386-17-2 |
|
8-Iodo-1-naphthoic acid, 97%
| 13577-19-0 |
|
2-Iodobenzene-1-sulfonamide, 95+%
| 53730-99-7 |
|
(8-Iodo-1-naphthyl)methanol, 97%
| 85864-84-2 |
|
(8-Bromo-1-naphthyl)methanol, 97%
| 14938-58-0 |
|
2-(2-Iodophenyl)acetic acid, 97%
| 18698-96-9 |
|
5-(2-Bromoethoxy)-2,3-dihydro-1,4-benzodioxine, 97%
| 1710-62-9 |
|
N1-(5-oxo-5,6,7,8-tetrahydronaphthalen-2-yl)acetamide
| 88611-67-0 |
|
Dicyclopropyl Ketone, 95%
| 1121-37-5 |
|
|