**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 112-36-7 |Diethylene glycol diethyl ether | 87% | 203-963-7 |
|----------------|--------------------------------------|----------|-----------|
| 5137-46-2 |Sodium biphenyl | 13% | 225-894-1 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 10 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a dry area. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 112-36-7:
CAS# 5137-46-2:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: dark green
Odor: ethereal odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 54 deg C ( 129.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.100
Molecular Formula: C12H10Na
Molecular Weight: 177.2
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 112-36-7: KN3160000
CAS# 5137-46-2 unlisted.
LD50/LC50:
CAS# 112-36-7: Draize test, rabbit, eye: 50 mg Moderate; Oral, rat:
LD50 = 4970 mg/kg; Skin, rabbit: LD50 = 6700 uL/kg.
CAS# 5137-46-2.
Carcinogenicity:
Diethylene glycol diethyl ether -
Not listed by ACGIH, IARC, or NTP.
Sodium biphenyl -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 112-36-7: No information available.
CAS# 5137-46-2: No information available.
Canada
CAS# 112-36-7 is listed on Canada's DSL List.
CAS# 112-36-7 is listed on Canada's Ingredient Disclosure List.
CAS# 5137-46-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 112-36-7 is listed on the TSCA inventory.
CAS# 5137-46-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 10 Flammable.
R 34 Causes burns.
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Hydroxyethyl disulfide, tech., 90%
| 1892-29-1 |
|
Ethyl isodehydroacetate, 95%
| 3385-34-0 |
|
Pentadecafluorooctanoic acid, 96%
| 335-67-1 |
|
p-Nitrobenzyl acetoacetate
| 61312-84-3 |
|
(2S)-Bornane-10,2-sultam, 98%
| 108448-77-7 |
|
Tris(methylthio)methane, 98%
| 5418-86-0 |
|
1-Bromo-2,3,5,6-tetrafluorobenzene, 99%
| 1559-88-2 |
|
??-Carotene, 95%
| 7235-40-7 |
|
1,5-Dihydroxy-1,2,3,4-tetrahydronaphthalene, tech., 90%
| 40771-26-4 |
|
Azure II Eosinate
| 62342-51-2 |
|
2,2,3,4,4,4-Hexafluorobutyl methacrylate, stabilized with 30-70 ppm
| 36405-47-7 |
|
3,4-Dichlorobenzoic acid, 98+%
| 51-44-5 |
|
Sodium biphenyl, reagent, 13% w/w solution in diethylene glycol
| 112-36-7 |
|
3,5-Dichloroanisole, 98%
| 33719-74-3 |
|
Glyceryl triundecanoate, 99%
| 13552-80-2 |
|
3,5-Dibromophenylboronic acid, 97%
| 117695-55-3 |
|
N-(Diphenylmethylene)glycerine tert-butyl ester, 98%
| 81477-94-3 |
|
(S)-2-Methyl-CBS-oxazaborolidine, 1M solut ion in toluene
| 108-88-3 |
|
(R)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene
| 108-88-3 |
|
tert-Butyl (R)-(+)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate
| 95715-87-0 |
|
Potassium tert-butoxide, 1.0M solution in tetrahydrofuran
| 109-99-9 |
|
N-Dodecyl-dioxyethylene
| 3055-93-4 |
|
Cholesterol cell culture tested in methyl- beta-cyclodextrin, 40mg
| 00-01-1 |
|
Oleic acid cell culture tested in methyl-beta-cyclodextrin, 30mg per
| 00-01-1 |
|
5-Hydroxytryptamine adipate
| 16031-83-7 |
|
1-(5-Chloro-2-hydroxy-4-methylphenyl)-3-phenyl-1,3-propanedione
| 5067-23-2 |
|
1-(5-Bromo-2-hydroxyphenyl)-3-phenyl-1,3-propanedione
| 5067-24-3 |
|
1-(5-Chloro-2-hydroxyphenyl)-3-phenyl-1,3-propanedione
| 5067-25-4 |
|
1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione
| 29976-82-7 |
|
4-Methyl-2-pentenoic acid, 97%
| 10321-71-8 |
|
Methyl 2-pentenoate, 97%
| 818-59-7 |
|
8-Benzyl-4-oxo-phenyl-1,3,8-triazaspiro[4, 5]decane, 99%
| 974-41-4 |
|
4-Isopropylcinnamic acid, 98%
| 3368-21-6 |
|
Chlorogenic Acid, 99% Predominantly Trans (Ex Coffee Seeds)
| 327-97-9 |
|
2-Chloro-6-fluorocinnamic acid, 98%
| 392-22-3 |
|
2,4-Dichlorocinnamic acid, 98%
| 20595-45-3 |
|
Octadecyl Isothiocyanate (Pract)
| 2877-26-1 |
|
1-(2-Hydroxylphenyl)-3-phenyl-1,3-propanedione
| 1469-94-9 |
|
1,1'-(4,6-Dihydroxy-1,3-phenylene)bisethanone
| 2161-85-5 |
|
2,4'-Dibromopropiophenone
| 38786-67-3 |
|
4-Chloro-2-(1H-pyrazol-3-yl)phenol
| 18704-67-1 |
|
Benzyl 2,4-dihydroxyphenyl ketone
| 3669-41-8 |
|
(1S,2R)-(-)-cis-2-(Benzylamino)cyclohexane methanol
| 71581-93-6 |
|
(1R,2S)-(+)-cis-2-(Benzylamino)cyclohexane methanol
| 71581-92-5 |
|
5-Bromo-2-methoxycinnamic acid, 97%
| 40803-53-0 |
|
(2,3-Dimethylphenoxy)acetic acid, 98%
| 2935-63-9 |
|
trans-(4-Ethoxybenzoyl)-3-acrylic acid, 98%
| 29582-31-8 |
|
5-Bromo-2-ethoxybenzaldehyde, 98%
| 79636-94-5 |
|
3-(Dimethylamino)propionitrile, 98%
| 1738-25-6 |
|
2-Hydroxychalcone, 98%
| 644-78-0 |
|
|