**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 123-31-9 |Hydroquinone | 0.1 | 204-617-8 |
|----------------|--------------------------------------|----------|-----------|
| 5497-67-6 |2,2-Dimethyl-4-pentenal | 99.9 | 226-834-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep away from heat, sparks and flame.
Avoid breathing vapor or mist.
Storage:
Keep away from sources of ignition. Keep refrigerated. (Store below
4C/39F.) Store in a tightly closed container. Keep under a
nitrogen blanket. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 123-31-9:
United Kingdom, WEL - TWA: 0.5 mg/m3 TWA
United Kingdom, WEL - STEL: 1.5 mg/m3 STEL
United States OSHA: 2 mg/m3 TWA
Belgium - TWA: 2 mg/m3 VLE
France - VME: 2 mg/m3 VME
Germany: 2 mg/m3 TWA (inhalable fraction)
Malaysia: 2 mg/m3 TWA
Netherlands: 2 mg/m3 MAC
Spain: 2 mg/m3 VLA-ED
CAS# 5497-67-6:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 124 - 125 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 18 deg C ( 64.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.825
Molecular Formula: C7H12O
Molecular Weight: 112.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 123-31-9: MX3500000
CAS# 5497-67-6 unlisted.
LD50/LC50:
CAS# 123-31-9: Oral, mouse: LD50 = 245 mg/kg; Oral, mouse: LD50 =
350 mg/kg; Oral, rabbit: LD50 = 200 mg/kg; Oral, rat: LD50 = 302
mg/kg; Oral, rat: LD50 = 320 mg/kg.
CAS# 5497-67-6.
Carcinogenicity:
Hydroquinone -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
2,2-Dimethyl-4-pentenal -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
USA RQ: CAS# 123-31-9: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 123-31-9: 2
CAS# 5497-67-6: No information available.
Canada
CAS# 123-31-9 is listed on Canada's DSL List.
CAS# 123-31-9 is listed on Canada's Ingredient Disclosure List.
CAS# 5497-67-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 123-31-9 is listed on the TSCA inventory.
CAS# 5497-67-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and
skin.
R 40 Limited evidence of a carcinogenic effect.
R 41 Risk of serious damage to eyes.
R 43 May cause sensitization by skin contact.
R 50 Very toxic to aquatic organisms.
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,3-Benzodioxol-5-ylmethyl isothiocyanate, 95%+
| 4430-47-1 |
|
3-Chloro-4-fluorobenzene-1-carbothioamide, tech
| 130560-97-3 |
|
2-(1-Methylhydrazino)-4-(trifluoromethyl)pyridine, 97%
| 208720-09-6 |
|
2-(Methylsulfanyl)-5,6-dihydro-4H-1,3-thiazine, 97%
| 58842-19-6 |
|
4-Chlorophenyl isothiocyanate, 97%
| 2131-55-7 |
|
1-[2,6-Dichloro-4-(trifluoromethyl)phenyl]hydrazine, 95+%
| 86398-94-9 |
|
2-Methylbenzene-1-sulfonamide, 97%
| 88-19-7 |
|
Ethyl 2-(4-chlorophenoxy)-2-methylpropanoate, 97%
| 637-07-0 |
|
Silicagel, functionalized, pyridinium chlorochromate
| 00-01-1 |
|
Silicagel, functionalized, (cyclohexylcarbodiimido)propyl
| 0-01-1 |
|
Silicagel, functionalized,(trimethylammonium)propyl cyanoborohydride
| 0-01-1 |
|
(s)-(+)-Octen-3-ol
| 24587-53-9 |
|
Triisopropyl phosphite
| 116-17-6 |
|
Methyl 2-methyl-3-furyl disulfide, 98%
| 65505-17-1 |
|
6-Chloroimidazo[2,1-b][1,3]thiazole-5-sulfonyl chloride, 95+%
| 150020-64-7 |
|
2,4-Dimethoxybenzenesulfonyl chloride, 97%
| 63624-28-2 |
|
4-(Trimethylsilyl)morpholine
| 13368-42-8 |
|
Methyl 3-(4-hydroxyphenyl)propionate
| 5597-50-2 |
|
Bis(tributylstannyl)acetylene
| 994-71-8 |
|
3,6-Difluorophthalic anhydride
| 652-40-4 |
|
2,4-Dimethoxybenzoyl chloride
| 39828-35-8 |
|
Tributylphenyltin
| 960-16-7 |
|
4-Mercaptophenol
| 637-89-8 |
|
Chlorodimethyloctadecylsilane, 90%
| 18643-08-8 |
|
Triisopropylsilane, 95%
| 6485-79-6 |
|
6-Chloro-3-indoxyl butyrate
| 159954-34-4 |
|
2-Cyanobenzaldehyde
| 7468-67-9 |
|
(Methoxycarbonylsulfamoyl)triethylammonium hydroxide, inner salt
| 29684-56-8 |
|
(S)-(-)-1-Phenylethylamine, produced by BASF AG
| 2627-86-3 |
|
(R)-(+)-1-Phenylethylamine, produced by BASF AG
| 3886-69-9 |
|
tert-Butyl 2,2,2-trichloroacetimidate
| 98946-18-0 |
|
2,4-Dimethoxybenzylamine
| 20781-20-8 |
|
N-Ethylisopropylamine
| 19961-27-4 |
|
Pentacosane
| 629-99-2 |
|
BOC-L-Isoglutamine
| 18800-74-3 |
|
Sodium hydroxide, 0.05 N solution
| 1310-73-2 |
|
2,4,5-Trichlorophenol
| 95-95-4 |
|
2,6-Di-tert-butyl-4-methylpyridine
| 38222-83-2 |
|
3,5-Dimethyl-1-hexyn-3-ol
| 107-54-0 |
|
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, mix ture of (delta1) and meso,
| 126-86-3 |
|
2,2-Dimethyl-4-pentenal, stabilized
| 123-31-9 |
|
D-(-)-Erythrose, 65% aqueous solution
| 583-50-6 |
|
DL-3-Hydroxy-4-methoxymandelic acid, 95%
| 3695-24-7 |
|
(S)-4-tert-Butyldimethylsilyloxy-2-cyclopenten-1-one, 90%
| 61305-36-0 |
|
N-Carbobenzyloxy-L-Proline, 99%
| 1148-11-4 |
|
(R)-(+)-Citronellal, 90%
| 2385-77-5 |
|
5,7-Dichloro-8-quinaldinol, 98%
| 72-80-0 |
|
Bromodiphenylmethane, 90%
| 776-74-9 |
|
Cyclohexylmethyl bromide, 96%
| 2550-36-9 |
|
NADPH tetrasodium salt, 95%
| 2646-71-1 |
|
|