**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 38222-83-2 |2,6-Di-tert-butyl-4-methylpyridine | 98 | 253-834-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive.Air
sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Dust can be an explosion hazard when exposed
to heat or flame. Flammable solid. May burn rapidly with flare
burning effect. May re-ignite after fire is extinguished.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Scoop up with a nonsparking tool, then
place into a suitable container for disposal. Avoid generating dusty
conditions. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Avoid contact with skin and eyes. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Use with adequate ventilation. Store
protected from light. Handle under an inert atmosphere. Store
protected from air. Wash clothing before reuse. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Keep refrigerated. (Store below
4C/39F.) Store in a tightly closed container. Store in a dry area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 38222-83-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: colorless to light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 233 deg C @760mmHg
Freezing/Melting Point: 33 - 36 deg C
Autoignition Temperature: Not available.
Flash Point: 83 deg C ( 181.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H23N
Molecular Weight: 205.34
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Air sensitive. Light
sensitive.
Conditions to Avoid:
Incompatible materials, light, ignition sources, dust generation,
exposure to air, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 38222-83-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,6-Di-tert-butyl-4-methylpyridine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
IMO
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 38222-83-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 38222-83-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 38222-83-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/24/2003 Revision #4 Date: 5/27/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1,3-Benzodioxol-5-ylmethyl isothiocyanate, 95%+
| 4430-47-1 |
|
3-Chloro-4-fluorobenzene-1-carbothioamide, tech
| 130560-97-3 |
|
2-(1-Methylhydrazino)-4-(trifluoromethyl)pyridine, 97%
| 208720-09-6 |
|
2-(Methylsulfanyl)-5,6-dihydro-4H-1,3-thiazine, 97%
| 58842-19-6 |
|
4-Chlorophenyl isothiocyanate, 97%
| 2131-55-7 |
|
1-[2,6-Dichloro-4-(trifluoromethyl)phenyl]hydrazine, 95+%
| 86398-94-9 |
|
2-Methylbenzene-1-sulfonamide, 97%
| 88-19-7 |
|
Ethyl 2-(4-chlorophenoxy)-2-methylpropanoate, 97%
| 637-07-0 |
|
Silicagel, functionalized, pyridinium chlorochromate
| 00-01-1 |
|
Silicagel, functionalized, (cyclohexylcarbodiimido)propyl
| 0-01-1 |
|
Silicagel, functionalized,(trimethylammonium)propyl cyanoborohydride
| 0-01-1 |
|
(s)-(+)-Octen-3-ol
| 24587-53-9 |
|
Triisopropyl phosphite
| 116-17-6 |
|
Methyl 2-methyl-3-furyl disulfide, 98%
| 65505-17-1 |
|
6-Chloroimidazo[2,1-b][1,3]thiazole-5-sulfonyl chloride, 95+%
| 150020-64-7 |
|
2,4-Dimethoxybenzenesulfonyl chloride, 97%
| 63624-28-2 |
|
4-(Trimethylsilyl)morpholine
| 13368-42-8 |
|
Methyl 3-(4-hydroxyphenyl)propionate
| 5597-50-2 |
|
Bis(tributylstannyl)acetylene
| 994-71-8 |
|
3,6-Difluorophthalic anhydride
| 652-40-4 |
|
2,4-Dimethoxybenzoyl chloride
| 39828-35-8 |
|
Tributylphenyltin
| 960-16-7 |
|
4-Mercaptophenol
| 637-89-8 |
|
Chlorodimethyloctadecylsilane, 90%
| 18643-08-8 |
|
Triisopropylsilane, 95%
| 6485-79-6 |
|
6-Chloro-3-indoxyl butyrate
| 159954-34-4 |
|
2-Cyanobenzaldehyde
| 7468-67-9 |
|
(Methoxycarbonylsulfamoyl)triethylammonium hydroxide, inner salt
| 29684-56-8 |
|
(S)-(-)-1-Phenylethylamine, produced by BASF AG
| 2627-86-3 |
|
(R)-(+)-1-Phenylethylamine, produced by BASF AG
| 3886-69-9 |
|
tert-Butyl 2,2,2-trichloroacetimidate
| 98946-18-0 |
|
2,4-Dimethoxybenzylamine
| 20781-20-8 |
|
N-Ethylisopropylamine
| 19961-27-4 |
|
Pentacosane
| 629-99-2 |
|
BOC-L-Isoglutamine
| 18800-74-3 |
|
Sodium hydroxide, 0.05 N solution
| 1310-73-2 |
|
2,4,5-Trichlorophenol
| 95-95-4 |
|
2,6-Di-tert-butyl-4-methylpyridine
| 38222-83-2 |
|
3,5-Dimethyl-1-hexyn-3-ol
| 107-54-0 |
|
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, mix ture of (delta1) and meso,
| 126-86-3 |
|
2,2-Dimethyl-4-pentenal, stabilized
| 123-31-9 |
|
D-(-)-Erythrose, 65% aqueous solution
| 583-50-6 |
|
DL-3-Hydroxy-4-methoxymandelic acid, 95%
| 3695-24-7 |
|
(S)-4-tert-Butyldimethylsilyloxy-2-cyclopenten-1-one, 90%
| 61305-36-0 |
|
N-Carbobenzyloxy-L-Proline, 99%
| 1148-11-4 |
|
(R)-(+)-Citronellal, 90%
| 2385-77-5 |
|
5,7-Dichloro-8-quinaldinol, 98%
| 72-80-0 |
|
Bromodiphenylmethane, 90%
| 776-74-9 |
|
Cyclohexylmethyl bromide, 96%
| 2550-36-9 |
|
NADPH tetrasodium salt, 95%
| 2646-71-1 |
|
|