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MSDS 
:
 Yttrium(iii)-nitrate hexahydrate, 99.9%
CAS 
:
 13494-98-9
SYNONYMS 
:
 Nitric acid, yttrium(3+) salt, hexahydrate; Yttrium nitrate     hexahydrate (1:3:6)
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13494-98-9 |Yttrium Nitrate Hexahydrate | 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O
Risk Phrases: 8

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Contact with combustible material may cause fire.Hygroscopic
(absorbs moisture from the air).

Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. May cause
permanent corneal opacification.
Skin:
Causes skin irritation. May cause severe irritation and possible
burns.
Ingestion:
May cause severe irritation of the digestive tract. May cause
nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Dust is irritating to the respiratory tract. Causes irritation of
the mucous membrane. May cause acute pulmonary edema, asphyxia,
chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Strong oxidizer. Contact with
other material may cause fire. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Use water with caution and in flooding amounts.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately. Do
NOT use dry chemicals, CO2, Halon or foams.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately,
observing precautions in the Protective Equipment section. Cover
with sand, dry lime or soda ash and place in a closed container for
disposal. Provide ventilation. Keep combustibles (wood, paper, oil,
etc.,) away from spilled material.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Do not get in eyes, on skin, or on
clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Keep from contact with clothing and other combustible materials.
Discard contaminated shoes.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Keep away from acids. Keep away from reducing
agents. Keep containers tightly closed. Store in a cool, dry area
away from incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 13494-98-9:

Belgium - TWA: (listed as yttrium compounds): 1 mg/m3 VLE (as Y)
Malaysia: (listed as yttrium compounds): 1 mg/m3 TWA (as Y)
Netherlands: (listed as yttrium compounds): 1 mg/m3 MAC (as Y)
Spain: (listed as yttrium compounds): 1 mg/m3 VLA-ED (as Y)

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to
prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Powder and chunks
Color: white
Odor: Odorless.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: soluble
Specific Gravity/Density: 2.68
Molecular Formula: N3O9.Y.6H2O
Molecular Weight: 383.01

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation,
combustible materials, reducing agents.
Incompatibilities with Other Materials:
Strong reducing agents, strong acids, cyanides (e.g. potassium
cyanide, sodium cyanide), thiocyanates, isocyanates, hypophosphites,
organic matter, phosphinates + heat, aluminum powder + water + metal
nitrate may explode, mixtures of metal nitrates with alkyl esters
may explode.
Hazardous Decomposition Products:
Oxides of nitrogen.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 13494-98-9: ZG3750000
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Yttrium Nitrate Hexahydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
IMO
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
RID/ADR
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing group: II

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 13494-98-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13494-98-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13494-98-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 6/21/1999 Revision #3 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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