**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13590-82-4 |Cerium(IV) sulfate | 100 | 237-029-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI O
Risk Phrases: 36/37/38 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Contact with
combustible material may cause fire.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause permanent corneal opacification.
May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause acute pulmonary
edema, asphyxia, chemical pneumonitis, and upper airway obstruction
caused by edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Oxidizer. Greatly increases the
burning rate of combustible materials. Some oxidizers may react
explosively with hydrocarbons(fuel). May accelerate burning if
involved in a fire. Containers may explode when heated.
Extinguishing Media:
Do NOT get water inside containers. Contact professional
fire-fighters immediately. For small fires, do NOT use dry chemicals,
carbon dioxide, halon or foams. USE WATER ONLY. For large fires
flood fire with water from a distance.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Do not get water
inside containers. Do not use combustible materials such as paper
towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid breathing dust, vapor, mist, or gas. Keep
container tightly closed. Avoid contact with clothing and other
combustible materials. Do not get on skin or in eyes. Avoid ingestion
and inhalation. Use with adequate ventilation. Do not allow contact
with water. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 13590-82-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure. Wear appropriate
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: yellow-orange
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 195 deg C (dec.)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Decomposes.
Specific Gravity/Density:
Molecular Formula: CeS2O8
Molecular Weight: 332.23
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Ceric sulfate tetrahydrate loses water on
heating, becoming anhydrous at 180-200C; decomposes above 350C
forming CeOSO4. It is soluble in a small quantity of water but
decomposes in a large quantity of water with separation of a basic
salt.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture,
excess heat, combustible materials, reducing agents, exposure to
moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, moisture.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13590-82-4: WS6960000
LD50/LC50:
Not available.
Carcinogenicity:
Cerium(IV) sulfate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 13590-82-4: No information available.
Canada
CAS# 13590-82-4 is listed on Canada's DSL List.
CAS# 13590-82-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13590-82-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/25/1999 Revision #7 Date: 2/16/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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n,n-bis(Cyanoethyl)aniline, 95%
| 1555-66-4 |
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N,N'-Bis(2-Hydroxyethyl)piperazine, 99%
| 122-96-3 |
|
1,5-Dihydroxy-4,8-bisá2-á(2-hydroxyethoxy)
| 7376-52-5 |
|
Benzo[a]pyrene-7-d, 98%
| 68041-22-5 |
|
Benzo[a]pyrene-8-d, 98%
| 0-01-1 |
|
Benzo[a]pyrene-7,8-d2, 98%
| 0-01-1 |
|
Ethyl nitroacetate
| 626-35-7 |
|
5-Bromo-2-hydroxy-3-methoxybenzaldehyde
| 5034-74-2 |
|
2,3-Dibromo-4-hydroxy-5-methoxybenzaldehyde
| 2973-75-3 |
|
2,5-Dimethoxy-3-nitrobenzoic acid
| 17894-26-7 |
|
N-trans-Cinnamoylimidazole, 97%
| 1138-15-4 |
|
Valeronitrile, 98%
| 110-59-8 |
|
Cerium(IV) sulfate, reagent powder
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|
3-(4-Carboxyphenyl)propionic acid
| 70170-91-1 |
|
Hydroquinone-O,O'-diacetic acid
| 2245-53-6 |
|
4-Benzyloxy-3,5-dimethylbenzoic acid
| 97888-80-7 |
|
4-Benzyloxy-3,5-dimethylbenzaldehyde
| 144896-51-5 |
|
Chloranilic Acid, 99+%
| 87-88-7 |
|
Phenylpropargyl Aldehyde Diethyl Acetal, 98%
| 6142-95-6 |
|
3,4-Dimethylbenzaldehyde
| 5973-71-7 |
|
Di-n-heptyl phthalate
| 3648-21-3 |
|
1-Methyl-3,6-(1H,2H)-pyridazinedione
| 5436-01-1 |
|
4-Cyanobenzophenone
| 1503-49-7 |
|
2-Phenylbutyryl chloride
| 36854-57-6 |
|
Ethyl 5-benzyloxyindole-2-carboxylate, Astra-Zeneca custom grade
| 37033-95-7 |
|
3-Amino-4-Hydroxybenzoic Acid
| 1571-72-8 |
|
2-Bromo-4'-methylacetophenone, 90%
| 619-41-0 |
|
5-Phenyltetrazole, 99%
| 18039-42-4 |
|
3,5-Dichlorophenol, 99%
| 591-35-5 |
|
Corynanthine hydrochloride hydrate
| 483-10-3 |
|
Xylenes, reagent ACS
| 1330-20-7 |
|
2,4'-Dichloroacetophenone, 99+%
| 937-20-2 |
|
Xylenol Orange, water soluble
| 3618-43-7 |
|
9-Bromoanthracene, 96%
| 1564-64-3 |
|
Yttrium(iii)-nitrate hexahydrate, 99.9%
| 13494-98-9 |
|
4-Azabenzimidazole, 99%
| 273-21-2 |
|
Zinc Bromide 99.999%
| 7699-45-8 |
|
Zinc Chloride, P.A.
| 7646-85-7 |
|
Zinc Nitrate Hexahydrate, 98%
| 10196-18-6 |
|
L-Aspartic Acid Alpha-(7-Amido-4-Methylcoumarin), Trifluoroacetic
| 0-01-1 |
|
2,6-Pyridinedicarboxylic Acid, 99%
| 499-83-2 |
|
5,7-Dimethylisatin, 95%
| 39603-24-2 |
|
5-Chloroisatin, 95%
| 17630-76-1 |
|
Zinc oxide, reagent ACS, powder, 99+%
| 1314-13-2 |
|
Heptyloxyethanol
| 7409-44-1 |
|
S-Phenyl-L-Cysteine
| |
|
n-Carbobenzyloxy-s-phenyl-l-cysteine, 98%
| 159453-24-4 |
|
2,6-Dibromophenol, 98%
| 608-33-3 |
|
Methyl 4,5-Dimethoxy-3-Hydroxybenzoate, 98%
| 83011-43-2 |
|
Zinc sulfate heptahydrate, reagent acs (crystals)
| 7446-20-0 |
|
|