**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 27064-94-4 |Chloro bis-(4-fluorophenyl)methane | 98 | 248-201-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin.Moisture
sensitive.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis and corneal
damage. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. May cause irritation and dermatitis. May
cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Aspiration may lead to
pulmonary edema. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Do NOT get water inside containers.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not allow contact with water. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Keep from contact with
moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 27064-94-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 88 deg C @ 0.1 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 1.2550 g/cm3
Molecular Formula: C13H9ClF2
Molecular Weight: 238.66
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 27064-94-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Chloro bis-(4-fluorophenyl)methane -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
Safety Phrases:
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 37/39 Wear suitable gloves and eye/face
protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
WGK (Water Danger/Protection)
CAS# 27064-94-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 27064-94-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 27064-94-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4'-Isocyanato-5'-nitrobenzo-15-crown-5, 99.5%
| 83935-64-2 |
|
Trimethylacetonitrile, 98%
| 630-18-2 |
|
Thallium(iii) oxide, 99+%
| 1314-32-5 |
|
Methyl laurate, 96%
| 111-82-0 |
|
4-Methylsulphonylphenol,95%
| 14763-60-1 |
|
Triphenylmethanol, 97%
| 76-84-6 |
|
Methyl P-Nitrobenzenesulfonate
| 6214-20-6 |
|
4-Pentylbiphenyl, 99%
| 7116-96-3 |
|
Alpha, 4-Dimethyl-3-Hydroxyphenethylamine Hydrochloride, 98%
| 29440-90-2 |
|
2-Bromo-5-nitrotoluene, 99%
| 7149-70-4 |
|
4-Chloro-o-phenylenediamine, tech., 80+%
| 95-83-0 |
|
2-Hydroxyphenylacetic Acid, 99%
| 614-75-5 |
|
Tetramethylammonium tetrafluoroborate,97%
| 661-36-9 |
|
Hydroxyguanidine sulfate, hydrate, 99% (on the dry basis)
| 6345-29-5 |
|
1-Naphthylacetic acid, 99%
| 86-87-3 |
|
2,3',6-Trichloroindophenol sodium salt (pract)
| 6273-47-8 |
|
2-tert-Butyl-4-methylphenol, 99%
| 2409-55-4 |
|
1,3-Diacetylbenzene, 99%
| 6781-42-6 |
|
Diphenic Acid, 98%
| 482-05-3 |
|
L-Thyroxine, Sodium Salt Pentahydrate, 99%
| 6106-07-6 |
|
3-Amino-5,6-Dimethyl-1,2,4-Triazine, 97%
| 17584-12-2 |
|
1,1,2,2-Tetraethoxyethane, 99+%
| 3975-14-2 |
|
Coumarin 120, Laser Grade, 99% (UV-VIS)
| 26093-31-2 |
|
Toluidine Red
| 2425-85-6 |
|
Carbon tetrabromide, 99%
| 558-13-4 |
|
4,4'-Methylenebis(2-isopropyl-6-methylaniline), 98% (Titr.)
| 16298-38-7 |
|
3-Methylglutaric acid, 99%
| 626-51-7 |
|
2-Methyl-2-Butene
| 513-35-9 |
|
2,4-Difluoroaniline, 99%
| 367-25-9 |
|
3-Iodobenzoic acid, 98%
| 618-51-9 |
|
N,N-Dibutylformamide, 99+%
| 761-65-9 |
|
DL-Camphoroquinone, 99%
| 10373-78-1 |
|
4-Phenyltoluene, 98%
| 644-08-6 |
|
Chloro bis-(4-fluorophenyl)methane, 98%
| 27064-94-4 |
|
Diethylzinc, 15 wt.% solution in hexane
| 110-54-3 |
|
3-Phenoxybenzoic acid, 99%
| 3739-38-6 |
|
2-Chloro-5-(Fluorosulfonyl)-Benzoic Acid 99+%
| 21346-66-7 |
|
Cycloheptanone, 98%
| 502-42-1 |
|
DL-3-aminoisobutyric acid monohydrate , 99%
| 10569-72-9 |
|
3-Bromo-1,2-Propanediol, 97%
| 4704-77-2 |
|
3-Methylcholanthrene, 99%
| 56-49-5 |
|
Chrome Azurol S
| 1667-99-8 |
|
Amberlite xad-7 hp
| 37380-43-1 |
|
Trans-1-Methoxy-3-Trimethylsilyloxy-1,3- Butadiene
| 54125-02-9 |
|
2,3-Dibromothiophene,97%
| 3140-93-0 |
|
4-Nitrodiphenylamine, 98+%
| 836-30-6 |
|
Cesium nitrate, 99.99%
| 7789-18-6 |
|
(2R,3R)-1-Carboxy-2,3-Dihydroxy-4-Methylcyclohexa-3,5-Diene, 95%
| 0-01-1 |
|
1-Hexene, 97%
| 592-41-6 |
|
4,4'Diaminodiphenylamine Sulfate, Tech., 85%
| 53760-27-3 |
|
|