**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3034-19-3 |2-Nitrophenylhydrazine | 97 | 221-222-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38 5
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Heating may cause
an explosion.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Exposure may cause anemia and other blood
abnormalities.
Inhalation:
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). Causes respiratory tract irritation. Can
produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Exposure to heat may promote violent decomposition.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. This material poses an
explosion hazard when dry. Flammable solid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Wet area to prevent drying out. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Material is heat, shock and/or friction sensitive.
Use care in handling and storage. Avoid breathing dust, vapor, mist,
or gas. Avoid contact with eyes, skin, and clothing. Avoid contact
with skin and eyes. Avoid ingestion and inhalation. Use with adequate
ventilation.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep container closed to
prevent drying out. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 3034-19-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: orange - orange-brown
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 90 - 92 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 92 deg C
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: O2NC6H4NHNH2
Molecular Weight: 153.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However may violently decompose above 150C.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, temperatures
above 55C.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3034-19-3: MV8210000
LD50/LC50:
Not available.
Carcinogenicity:
2-Nitrophenylhydrazine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 5 Heating may cause an explosion.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 3034-19-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3034-19-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3034-19-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3-Diethylpyrazine, 98+%
| 15707-24-1 |
|
Solvent green 3
| 128-80-3 |
|
(S)-(+)-1,1'-Binaphthyl-2,2'-Diyl Hydrogen Phosphate, 99%
| 35193-64-7 |
|
Sodium Sulfate Decahydrate
| 7727-73-3 |
|
Cyclohexanecarboxaldehyde, 98%
| 2043-61-0 |
|
Lithium 3,5-diiodosalicylate, 95% (titr. on the dried substance)
| 653-14-5 |
|
m-Toluidine
| 108-44-1 |
|
Pararosaniline (Fuchsin Basic)
| 632-99-5 |
|
N-(1-Pyrenyl)Maleimide, 99%
| 42189-56-0 |
|
3,3',5,5'-Tetramethylbenzidine dihydrochloride hydrate, 98+%
| 64285-73-0 |
|
3-Maleimido-Proxyl, Free Radical
| 5389-27-5 |
|
4-Methoxybenzenesulfonyl Chloride, 99%
| 98-68-0 |
|
L(-)-p-Bromotetramisole oxalate, 99%
| 62284-79-1 |
|
Aq 29s
| 052319-10- |
|
4-Chloro-2-Fluorobenzaldehyde, 99%
| 0-00-1 |
|
n-Pentadecane, 99%
| 629-62-9 |
|
2-Bromo-2',5'-dimethoxyacetophenone, 97%
| 1204-21-3 |
|
d-4-Fluorophenylalanine
| 18125-46-7 |
|
Aq 38d
| |
|
Diphenyliodonium chloride, 97%
| 1483-72-3 |
|
Cobalt Cyclohexanebutyrate
| 38582-17-1 |
|
5-Hydroxy-Isophthalic Acid 99%
| 618-83-7 |
|
L-Serine Ethyl Ester Hydrochloride, 99%
| 26348-61-8 |
|
9-Chlorophenanthrene, 98%
| 947-72-8 |
|
Terephthalic Acid, 98%
| 100-21-0 |
|
7-Ethylindole, 97%
| 22867-74-9 |
|
Trihexylamine, 98%
| 102-86-3 |
|
3,3-Dimethylglutaric Acid, 98%
| 4839-46-7 |
|
Ethylene/vinyl acetate copolymer, 14 wt. % vinyl acetate
| 24937-78-8 |
|
5-Chloro-1,3-dihydro-1-(4-piperidinyl)-2H-benzimidazol-2-one
| 53786-28-0 |
|
4-Methylhippuric acid, 98%
| 27115-50-0 |
|
5,6-Dimethyl-4,7-Dihydroisobenzofuran 99%
| |
|
2',7'-Dichlorofluorescein Diacetate
| 4091-99-0 |
|
Tert-Butyldimethylsilyl Trifluoromethane Sulfonate, 98%
| 69739-34-0 |
|
L-Cysteine Ethyl Ester Hydrochloride 98%
| 868-59-7 |
|
4-Chlorobenzhydrylamine hydrochloride, 98%
| 5267-39-0 |
|
(-)-1,6-Bis(2-Chlorophenyl)-1,6-Diphenyl- 2,4-Hexadiyne-1,6-Diol,
| 86436-20-6 |
|
4-Aminopyridine.HCl Polystyrene Supported 1 MEQ.Chloride/g of PPC, 2%
| 0-00-1 |
|
2-Nitrophenylhydrazine, 97%
| 3034-19-3 |
|
N-Formyl-2-methoxy-piperidine, 97%
| 61020-07-3 |
|
3,5-Dimethylbenzoic Acid, 99%
| 499-06-9 |
|
1,3-Diphenyltriazene
| 136-35-6 |
|
2,3-Dimethyl-1-Butene, 98+%
| 563-78-0 |
|
9-Acetylanthracene, 95%
| 784-04-3 |
|
1,4-Dicyclohexylbenzene, 99%
| 1087-02-1 |
|
1-Pyrrolidinebutanenitrile 97%
| 35543-25-0 |
|
Dimethyl Acetylenedicarboxylate, 98%
| 762-42-5 |
|
Vancomycin hydrochloride, n.l.t. 900 microgram/mg (on dry substance)
| 1404-93-9 |
|
4-Phenylphenol, 97%
| 92-69-3 |
|
Neutron activation standard, long irradiation ii
| |
|
|