**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 92-69-3 |4-Phenylphenol | 97.0 | 202-179-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI N
Risk Phrases: 38 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to skin. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out
with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid
contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Use with adequate
ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 92-69-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Flakes - Powder
Color: white to light yellow
Odor: weak odor
pH: 7.0
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 307 deg C @ 760.00mm Hg
Freezing/Melting Point: 165 deg C
Autoignition Temperature: 250 deg C ( 482.00 deg F)
Flash Point: 165 deg C ( 329.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble in water : 0.7 g/l (20??c)
Specific Gravity/Density:
Molecular Formula: C12H10O
Molecular Weight: 170.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Materials containing similar structural groups are normally stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 92-69-3: DV5850000
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
4-Phenylphenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish toxicity : LC50 (96hr) bluegill sunfish 6 mg/l (Holcombe,G.W. et
al Environ.Pollut,Ser.A1984) Invertebrate toxicity : EC50 (2 day)
Tetrahymena pyriformis 13.7 mg/l (Schultz,T.W. Ecotoxicol. Environ.
Saf. 1987) EC50 (5 min) Photobacterium phosphoreum 2.05 ppm Microtox
test (Kaiser,K.L.E. water pollut. res. J.Can.1991)
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 38 Irritating to skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 36 Wear suitable protective clothing.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 92-69-3: 2
Canada
CAS# 92-69-3 is listed on Canada's DSL List.
CAS# 92-69-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 92-69-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/15/1999 Revision #3 Date: 3/11/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3-Diethylpyrazine, 98+%
| 15707-24-1 |
|
Solvent green 3
| 128-80-3 |
|
(S)-(+)-1,1'-Binaphthyl-2,2'-Diyl Hydrogen Phosphate, 99%
| 35193-64-7 |
|
Sodium Sulfate Decahydrate
| 7727-73-3 |
|
Cyclohexanecarboxaldehyde, 98%
| 2043-61-0 |
|
Lithium 3,5-diiodosalicylate, 95% (titr. on the dried substance)
| 653-14-5 |
|
m-Toluidine
| 108-44-1 |
|
Pararosaniline (Fuchsin Basic)
| 632-99-5 |
|
N-(1-Pyrenyl)Maleimide, 99%
| 42189-56-0 |
|
3,3',5,5'-Tetramethylbenzidine dihydrochloride hydrate, 98+%
| 64285-73-0 |
|
3-Maleimido-Proxyl, Free Radical
| 5389-27-5 |
|
4-Methoxybenzenesulfonyl Chloride, 99%
| 98-68-0 |
|
L(-)-p-Bromotetramisole oxalate, 99%
| 62284-79-1 |
|
Aq 29s
| 052319-10- |
|
4-Chloro-2-Fluorobenzaldehyde, 99%
| 0-00-1 |
|
n-Pentadecane, 99%
| 629-62-9 |
|
2-Bromo-2',5'-dimethoxyacetophenone, 97%
| 1204-21-3 |
|
d-4-Fluorophenylalanine
| 18125-46-7 |
|
Aq 38d
| |
|
Diphenyliodonium chloride, 97%
| 1483-72-3 |
|
Cobalt Cyclohexanebutyrate
| 38582-17-1 |
|
5-Hydroxy-Isophthalic Acid 99%
| 618-83-7 |
|
L-Serine Ethyl Ester Hydrochloride, 99%
| 26348-61-8 |
|
9-Chlorophenanthrene, 98%
| 947-72-8 |
|
Terephthalic Acid, 98%
| 100-21-0 |
|
7-Ethylindole, 97%
| 22867-74-9 |
|
Trihexylamine, 98%
| 102-86-3 |
|
3,3-Dimethylglutaric Acid, 98%
| 4839-46-7 |
|
Ethylene/vinyl acetate copolymer, 14 wt. % vinyl acetate
| 24937-78-8 |
|
5-Chloro-1,3-dihydro-1-(4-piperidinyl)-2H-benzimidazol-2-one
| 53786-28-0 |
|
4-Methylhippuric acid, 98%
| 27115-50-0 |
|
5,6-Dimethyl-4,7-Dihydroisobenzofuran 99%
| |
|
2',7'-Dichlorofluorescein Diacetate
| 4091-99-0 |
|
Tert-Butyldimethylsilyl Trifluoromethane Sulfonate, 98%
| 69739-34-0 |
|
L-Cysteine Ethyl Ester Hydrochloride 98%
| 868-59-7 |
|
4-Chlorobenzhydrylamine hydrochloride, 98%
| 5267-39-0 |
|
(-)-1,6-Bis(2-Chlorophenyl)-1,6-Diphenyl- 2,4-Hexadiyne-1,6-Diol,
| 86436-20-6 |
|
4-Aminopyridine.HCl Polystyrene Supported 1 MEQ.Chloride/g of PPC, 2%
| 0-00-1 |
|
2-Nitrophenylhydrazine, 97%
| 3034-19-3 |
|
N-Formyl-2-methoxy-piperidine, 97%
| 61020-07-3 |
|
3,5-Dimethylbenzoic Acid, 99%
| 499-06-9 |
|
1,3-Diphenyltriazene
| 136-35-6 |
|
2,3-Dimethyl-1-Butene, 98+%
| 563-78-0 |
|
9-Acetylanthracene, 95%
| 784-04-3 |
|
1,4-Dicyclohexylbenzene, 99%
| 1087-02-1 |
|
1-Pyrrolidinebutanenitrile 97%
| 35543-25-0 |
|
Dimethyl Acetylenedicarboxylate, 98%
| 762-42-5 |
|
Vancomycin hydrochloride, n.l.t. 900 microgram/mg (on dry substance)
| 1404-93-9 |
|
4-Phenylphenol, 97%
| 92-69-3 |
|
Neutron activation standard, long irradiation ii
| |
|
|