**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 326-91-0 |Thenoyltrifluoroacetone | app.100 | 206-316-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.The toxicological properties of this material have not been
fully investigated.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. The toxicological properties of this
substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Can produce delayed
pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Use
agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Place under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use
with adequate ventilation. Handle under an inert atmosphere. Store
protected from air. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below
4C/39F.) Do not expose to air. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 326-91-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: light yellow - yellow - pink
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 96 - 98 deg C @ 8.0
Freezing/Melting Point: 40 - 44 deg C
Autoignition Temperature: Not applicable.
Flash Point: 111 deg C ( 231.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 222.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Air sensitive.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to air, excess
heat, strong oxidants.
Incompatibilities with Other Materials:
Air, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 326-91-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Thenoyltrifluoroacetone -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 326-91-0: No information available.
Canada
CAS# 326-91-0 is listed on Canada's DSL List.
CAS# 326-91-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 326-91-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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tert-Butyl nitrite, tech., 90%
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| 131-56-6 |
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| 2437-29-8 |
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| 5707-04-0 |
|
Docosanedioic Acid, 94+% (GC)
| 505-56-6 |
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Methyl Green
| 7114-03-6 |
|
Alpha,4-Dimethylbenzylalcohol, 98%
| 536-50-5 |
|
Ethylene/ethyl acrylate copolymer
| 9010-86-0 |
|
Methyl Orange
| 547-58-0 |
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| 1064-48-8 |
|
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| 2752-17-2 |
|
Neutral Red
| 553-24-2 |
|
Anthracene-9-Carboxylic Acid, 99%
| 723-62-6 |
|
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| 6280-88-2 |
|
1,4-Butanediol-d10, 99+
| 71760-76-4 |
|
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| 7559-04-8 |
|
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| 617-65-2 |
|
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| 1067-71-6 |
|
Orange G
| 1936-15-8 |
|
Orcein (Synthetic)
| 1400-62-0 |
|
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| 5710-54-3 |
|
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| 7072-00-6 |
|
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| 6399-81-1 |
|
PAN
| 85-85-8 |
|
4-Mercaptopyridine, 96%(titr.)
| 4556-23-4 |
|
1,10-Phenanthroline monohydrate
| 66-71-7 |
|
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| 479-59-4 |
|
3-Hydroxy-2-Methyl-4-Quinolinecarboxylic Acid, 99%
| 117-57-7 |
|
3-(2-Furyl)acrolein, 99%
| 623-30-3 |
|
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| 113-24-6 |
|
5,5-Diphenylhydantoin, 99+%
| 57-41-0 |
|
DL-Pipecolinic Acid, 99%
| 4043-87-2 |
|
2-Hydroxy-3-methoxybenzyl alcohol, 95%
| 4383-05-5 |
|
1,2-Diphenoxyethane, 99%
| 104-66-5 |
|
Rose Bengal Disodium Salt
| 632-69-9 |
|
1,3,5-Benzenetrisulfonic acid trisodium salt, trihydrate
| 43052-65-9 |
|
Safranin O
| 477-73-6 |
|
n-Acetyl-dl-tryptophan, 99+%
| 87-32-1 |
|
Veratrole, 99+%
| 91-16-7 |
|
Deoxycholic Acid Sodium Salt, 97% (Titr.)
| 302-95-4 |
|
Sodium Diethyldithiocarbamate Trihydrate
| 20624-25-3 |
|
Sudan III
| 85-86-9 |
|
Sudan IV
| 85-83-6 |
|
Sudan Black B
| 4197-25-5 |
|
Thenoyltrifluoroacetone
| 326-91-0 |
|
|