**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 547-58-0 |C.I. acid orange 52 | ca. 100 | 208-925-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed.
Potential Health Effects
Eye:
May cause eye irritation. This product contains an anionic dye.
Similar dyes have not caused injury to the cornea or conjunctiva in
documented exposure cases with human or rabbit eyes.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Wash clothing
before reuse. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
skin and eyes. Keep container tightly closed. Do not ingest or
inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 547-58-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: orange
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in hot water.
Specific Gravity/Density: 1.00
Molecular Formula: C14H14N3O3SNa
Molecular Weight: 327.1661
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen, sulfur
oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 547-58-0: DB6327000
LD50/LC50:
CAS# 547-58-0: Oral, rat: LD50 = 60 mg/kg.
Carcinogenicity:
C.I. acid orange 52 -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DYE, SOLID, TOXIC, N.O.S. (METHYL ORANGE)
Hazard Class: 6.1
UN Number: 3143
Packing Group: III
IMO
Shipping Name: DYE, SOLID, TOXIC, N.O.S. (METHYL ORANGE)
Hazard Class: 6.1
UN Number: 3143
Packing Group: III
RID/ADR
Shipping Name: DYE, SOLID, TOXIC, N.O.S. (METHYL ORANGE)
Hazard Class: 6.1
UN Number: 3143
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
Safety Phrases:
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 547-58-0: 2
Canada
CAS# 547-58-0 is listed on Canada's DSL List.
CAS# 547-58-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 547-58-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/19/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 553-24-2 |
|
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| 723-62-6 |
|
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| 6280-88-2 |
|
1,4-Butanediol-d10, 99+
| 71760-76-4 |
|
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| 7559-04-8 |
|
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| 617-65-2 |
|
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| 1067-71-6 |
|
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| 1936-15-8 |
|
Orcein (Synthetic)
| 1400-62-0 |
|
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| 5710-54-3 |
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| 7072-00-6 |
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| 85-85-8 |
|
4-Mercaptopyridine, 96%(titr.)
| 4556-23-4 |
|
1,10-Phenanthroline monohydrate
| 66-71-7 |
|
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| 479-59-4 |
|
3-Hydroxy-2-Methyl-4-Quinolinecarboxylic Acid, 99%
| 117-57-7 |
|
3-(2-Furyl)acrolein, 99%
| 623-30-3 |
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| 113-24-6 |
|
5,5-Diphenylhydantoin, 99+%
| 57-41-0 |
|
DL-Pipecolinic Acid, 99%
| 4043-87-2 |
|
2-Hydroxy-3-methoxybenzyl alcohol, 95%
| 4383-05-5 |
|
1,2-Diphenoxyethane, 99%
| 104-66-5 |
|
Rose Bengal Disodium Salt
| 632-69-9 |
|
1,3,5-Benzenetrisulfonic acid trisodium salt, trihydrate
| 43052-65-9 |
|
Safranin O
| 477-73-6 |
|
n-Acetyl-dl-tryptophan, 99+%
| 87-32-1 |
|
Veratrole, 99+%
| 91-16-7 |
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Deoxycholic Acid Sodium Salt, 97% (Titr.)
| 302-95-4 |
|
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| 20624-25-3 |
|
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| 85-86-9 |
|
Sudan IV
| 85-83-6 |
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Sudan Black B
| 4197-25-5 |
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| 326-91-0 |
|
|