**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3878-44-2 |Triphenylphosphine selenide | 98% | 223-406-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed. Danger of cumulative
effects.Toxic.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Poison by ingestion. The toxicological properties of this substance
have not been fully investigated.
Inhalation:
Toxic if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 3878-44-2:
United Kingdom, WEL - TWA: (listed as selenium compounds): 0.1 mg
TWA (except hydrogen selenide, as Se)
United Kingdom, WEL - STEL: (listed as selenium compounds): 0.3 m
STEL (except hydrogen selenide, as Se)
United States OSHA: 0.2 mg/m3 TWA (as Se) (listed under Selenium
compounds).
Belgium - TWA: (listed as selenium compounds): 0.2 mg/m3 VLE (as
Japan: (listed as selenium compounds): 0.1 mg/m3 OEL (except SeH2
SeF6, as Se)
Malaysia: (listed as selenium compounds): 0.2 mg/m3 TWA (as Se)
Netherlands: (listed as selenium compounds): 0.1 mg/m3 MAC (as Se
Spain: (listed as selenium compounds): 0.1 mg/m3 VLA-ED (except
hydrogen selenide, as Se)
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist
respirator or European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 187 - 189 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble in water.
Specific Gravity/Density:
Molecular Formula: C18H15PSe
Molecular Weight: 341.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, selenium/selenium oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3878-44-2: SZ2455000
LD50/LC50:
Not available.
Carcinogenicity:
Triphenylphosphine selenide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3878-44-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3878-44-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3878-44-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
5-Chloro-2-Nitrodiphenylamine, 98%
| 25781-92-4 |
|
Methyl 2-Chlorobenzoylacetate
| |
|
4-Chloro-o-xylene, 98%
| 615-60-1 |
|
2,5-Pyridinedicarboxylic acid 98%
| 100-26-5 |
|
4-Amino-6-Chloro-2-Methylmercaptopyrimidine, 97%
| 1005-38-5 |
|
Triphenylphosphine selenide, 98%
| 3878-44-2 |
|
3-Methyl-1-pentene, 99%
| 760-20-3 |
|
2-Amino-4-Phenylthiazole Hydrobromide Monohydrate, 99%
| 52253-69-7 |
|
3',4'-(Dioctyloxy)acetophenone, 99+%
| 111195-33-6 |
|
2,5-Dichlorophenylhydrazine, 98%
| 305-15-7 |
|
Methyl Green (Cert)
| 14855-76-6 |
|
2-Chloro-4,6-Diamino-1,3,5-Triazine, 97%
| 3397-62-4 |
|
1,4-Dibromo-2-Fluorobenzene, 99+%
| 1435-52-5 |
|
Europium (III) Thenoyltrifluoroacetonate, Trihydrate
| 14054-87-6 |
|
Ochratoxin a, 99+%
| 303-47-9 |
|
1-Ethyl-2-Methylnaphtho(1,2-D)Thiazolium P-Toluenesulfonate, 95%
| 42952-29-4 |
|
Alpha, Alpha, Alpha-Trifluoro-M-Toluic Acid, 99%
| 454-92-2 |
|
Tetramethylammonium iodide, 99%
| 75-58-1 |
|
Bromoacetyl bromide, 98+%
| 598-21-0 |
|
6-Nitroveratraldehyde, tech.
| 20357-25-9 |
|
Carbobenzyloxy-L-Alanine, 98%
| 1142-20-7 |
|
Phloroglucinol Dihydrate, 99%
| 6099-90-7 |
|
8-Anilino-1-naphthalenesulfonic acid, 99% (titr)
| 82-76-8 |
|
(1-Ethoxyethylidene)-Malononitrile, 99+%
| 5417-82-3 |
|
l-Methioninol, 99+%
| 2899-37-8 |
|
3-Methyl-3-buten-1-ol, 97%
| 763-32-6 |
|
3,3,5,5-Tetramethylcyclohexanone, 98%
| 14376-79-5 |
|
2-Acetyl-6-Methoxynaphthalene, 98%
| 3900-45-6 |
|
4-Hydroxy-3-methoxybenzonitrile, 98%
| 4421-08-3 |
|
Phenyl Phosphorodichloridite
| 3426-89-9 |
|
4-Dodecyloxybenzaldehyde, 99% (GC)
| 24083-19-0 |
|
2-Butoxyacetic Acid, 99+%
| 2516-93-0 |
|
Alpha-Bromo-2,6-Dichlorotoluene, 99+%(G.C.)
| 20443-98-5 |
|
(Ethyl)triphenylphosphonium bromide, 99+%
| 1530-32-1 |
|
4'-(1H-1,2,4-Triazol-1-yl)phenol, 98%
| 68337-15-5 |
|
p-Methylcinnamic acid, 99%, predominantly trans
| 1866-39-3 |
|
4-Hydroxyphenylacetamide 99%
| 17194-82-0 |
|
3-Phenoxyaniline
| 3586-12-7 |
|
3,4-Difluorobenzoic Acid, 99%
| 455-86-7 |
|
Maltotriose, 93%
| 1109-28-0 |
|
1-Phenylpiperazine, 95% (gc)
| 92-54-6 |
|
Salicylhydroxamic Acid, 99%
| 89-73-6 |
|
2-Hexanol, 99%
| 626-93-7 |
|
N,O-Bis(trimethylsilyl)acetamide
| 10416-59-8 |
|
Thiosemicarbazide, 99%
| 79-19-6 |
|
1-Bis(4-fluorophenyl)methyl piperazine
| 27469-60-9 |
|
1-Isoquinolinecarboxylic acid, 99%
| 486-73-7 |
|
Janus green b, high purity biological stain
| 2869-83-2 |
|
2-Adamantanol, 98%
| 700-57-2 |
|
Ammonium Ferrocyanide Hydrate, 90-95%
| 14481-29-9 |
|
|