**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 598-21-0 |Bromoacetyl bromide | 98+ | 209-923-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Corrosive.Lachrymator
(substance which increases the flow of tears).Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Causes irritation of
mucous membrane.
Chronic:
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea and
vomiting. Chronic inhalation may cause spasm, inflammation and edema
of the larynx and bronchi, chemical pneumonitis, and pulmonary edema.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. May ignite or
explode on contact with steam or moist air.
Extinguishing Media:
Use dry sand or earth to smother fire. Use foam, dry chemical, or
carbon dioxide. Use agent most appropriate to extinguish fire. DO
NOT USE WATER! Contact professional fire-fighters immediately.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not expose spill to water. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Do not allow water to get into the container
because of violent reaction. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale.
Discard contaminated shoes. Keep from contact with moist air and
steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Keep away from water. Corrosives area. Keep refrigerated.
(Store below 4C/39F.) Water free area - refrigerator.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 598-21-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 3.8 mm Hg @ 25
Viscosity: Not available.
Boiling Point: 147 - 150 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 105 deg C (> 221.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in acetone, carbontetrachloride
Specific Gravity/Density: 2.3170g/cm3
Molecular Formula: C2H2Br2O
Molecular Weight: 201.85
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Combines vigorously or explosively with water.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, alcohols.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 598-21-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Bromoacetyl bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BROMOACETYL BROMIDE
Hazard Class: 8
UN Number: 2513
Packing Group: II
IMO
Shipping Name: BROMOACETYL BROMIDE
Hazard Class: 8
UN Number: 2513
Packing Group: II
RID/ADR
Shipping Name: BROMOACETYL BROMIDE
Hazard Class: 8
UN Number: 2513
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 25 Avoid contact with eyes.
S 30 Never add water to this product.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 598-21-0: No information available.
Canada
CAS# 598-21-0 is listed on Canada's DSL List.
CAS# 598-21-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 598-21-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/17/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Methyl 2-Chlorobenzoylacetate
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4-Chloro-o-xylene, 98%
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2,5-Pyridinedicarboxylic acid 98%
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4-Amino-6-Chloro-2-Methylmercaptopyrimidine, 97%
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Triphenylphosphine selenide, 98%
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3-Methyl-1-pentene, 99%
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2-Amino-4-Phenylthiazole Hydrobromide Monohydrate, 99%
| 52253-69-7 |
|
3',4'-(Dioctyloxy)acetophenone, 99+%
| 111195-33-6 |
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2,5-Dichlorophenylhydrazine, 98%
| 305-15-7 |
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Methyl Green (Cert)
| 14855-76-6 |
|
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1,4-Dibromo-2-Fluorobenzene, 99+%
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Europium (III) Thenoyltrifluoroacetonate, Trihydrate
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Ochratoxin a, 99+%
| 303-47-9 |
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| 42952-29-4 |
|
Alpha, Alpha, Alpha-Trifluoro-M-Toluic Acid, 99%
| 454-92-2 |
|
Tetramethylammonium iodide, 99%
| 75-58-1 |
|
Bromoacetyl bromide, 98+%
| 598-21-0 |
|
6-Nitroveratraldehyde, tech.
| 20357-25-9 |
|
Carbobenzyloxy-L-Alanine, 98%
| 1142-20-7 |
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Phloroglucinol Dihydrate, 99%
| 6099-90-7 |
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8-Anilino-1-naphthalenesulfonic acid, 99% (titr)
| 82-76-8 |
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| 5417-82-3 |
|
l-Methioninol, 99+%
| 2899-37-8 |
|
3-Methyl-3-buten-1-ol, 97%
| 763-32-6 |
|
3,3,5,5-Tetramethylcyclohexanone, 98%
| 14376-79-5 |
|
2-Acetyl-6-Methoxynaphthalene, 98%
| 3900-45-6 |
|
4-Hydroxy-3-methoxybenzonitrile, 98%
| 4421-08-3 |
|
Phenyl Phosphorodichloridite
| 3426-89-9 |
|
4-Dodecyloxybenzaldehyde, 99% (GC)
| 24083-19-0 |
|
2-Butoxyacetic Acid, 99+%
| 2516-93-0 |
|
Alpha-Bromo-2,6-Dichlorotoluene, 99+%(G.C.)
| 20443-98-5 |
|
(Ethyl)triphenylphosphonium bromide, 99+%
| 1530-32-1 |
|
4'-(1H-1,2,4-Triazol-1-yl)phenol, 98%
| 68337-15-5 |
|
p-Methylcinnamic acid, 99%, predominantly trans
| 1866-39-3 |
|
4-Hydroxyphenylacetamide 99%
| 17194-82-0 |
|
3-Phenoxyaniline
| 3586-12-7 |
|
3,4-Difluorobenzoic Acid, 99%
| 455-86-7 |
|
Maltotriose, 93%
| 1109-28-0 |
|
1-Phenylpiperazine, 95% (gc)
| 92-54-6 |
|
Salicylhydroxamic Acid, 99%
| 89-73-6 |
|
2-Hexanol, 99%
| 626-93-7 |
|
N,O-Bis(trimethylsilyl)acetamide
| 10416-59-8 |
|
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| 79-19-6 |
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| 27469-60-9 |
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1-Isoquinolinecarboxylic acid, 99%
| 486-73-7 |
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Janus green b, high purity biological stain
| 2869-83-2 |
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| 700-57-2 |
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| 14481-29-9 |
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