**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 38869-46-4 |1-(4-Chlorophenyl)piperazine dihydroch| 95.0 | 254-165-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause digestive
tract disturbances. The toxicological properties of this substance
have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. May cause respiratory tract
irritation. The toxicological properties of this substance have not
been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 38869-46-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: tan - slightly beige
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 275.00 - 278.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H13ClN2.2HCl
Molecular Weight: 269.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 38869-46-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(4-Chlorophenyl)piperazine dihydrochloride, TLC -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 38869-46-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 38869-46-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 38869-46-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/03/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,3-Difluorobenzoyl chloride
| 18355-73-2 |
|
2-Fluoro-5-(trifluoromethyl)benzoyl chloride, 97%
| 207981-46-2 |
|
Lithium aluminium hydride, 4.0M solution in diethyl ether
| 60-29-7 |
|
4-Chlorophenylmagnesium bromide, 1M solution in diethyl ether
| 60-29-7 |
|
4-Fluorophenylmagnesium bromide, 2M solution in diethyl ether
| 60-29-7 |
|
Phenylmagnesium bromide, 1M solution in THF
| 100-58-3 |
|
Ethyl magnesiumbromide, 1M solution in THF
| 109-99-9 |
|
Methylmagnesium bromide, 1M solution in THF
| 75-16-1 |
|
(R)-1-(4-Chlorophenyl)ethylamine, produced by BASF AG
| 27298-99-3 |
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Ethylenediamine Tetraacetic Acid
| 60-00-4 |
|
(S)-1-(4-Chlorophenyl)ethylamine, produced by BASF AG
| 4187-56-8 |
|
DL-2-Amino-3-phenyl-1-propanol, 98%
| 16088-07-6 |
|
DL-2-Phenylglycinol, 98%
| 7568-92-5 |
|
DL-Methioninol
| 502-83-0 |
|
2-Aminopentanol, 98%
| 16369-14-5 |
|
4-Chlorothiobenzamide, 98%
| 2521-24-6 |
|
Acetylpyrazine, 97%
| 22047-25-2 |
|
2-Aminothiobenzamide, 98%
| 2454-39-9 |
|
2,4-Dichlorothiobenzamide, 98%
| 2775-38-4 |
|
2,6-Dichlorothiobenzamide, 98%
| 1918-13-4 |
|
4-Fluorothiobenzamide, 99%
| 22179-72-2 |
|
2-Fluorothiobenzamide, 98%
| 75907-82-3 |
|
3-Iodothiobenezamide
| 106748-26-9 |
|
1,1'-Binaphthyl
| 604-53-5 |
|
2-Bromothiobenzamide, 98%
| 30216-44-5 |
|
2-Chlorothiobenzamide, 98%
| 15717-17-6 |
|
3-Methylthiobenzamide, 98%
| 2362-63-2 |
|
3,4-Dimethoxyphenylthioacetamide, 98%
| 145736-65-8 |
|
2,6-Dimethoxythiobenzamide
| 77378-18-8 |
|
Diphenylthioacetamide, 97%
| 17518-50-2 |
|
(s)-n-boc-2-amino-4-methylpentyl cyanide
| 172695-24-8 |
|
(s)-n-boc-2-amino-3-phenylpropyl cyanide
| 172695-25-9 |
|
3-Bromopropionaldehyde dimethylacetal
| 36255-44-4 |
|
N-BOC-trans-4-Hydroxyl-L-proline methyl ester, 97%
| 74844-91-0 |
|
4-(Benzyloxy)pyridine N-oxide, 97%
| 2683-66-1 |
|
1-(4-Chlorophenyl)piperazine dihydrochloride, 95% (tlc)
| 38869-46-4 |
|
(S)-(-)-N-BOC-2-Amino-1,5-pentanediol
| 162955-48-8 |
|
(S)-(-)-N-BOC-2-Amino-1,4-butanediol
| 128427-10-1 |
|
3,3,3-Trifluoro-(2-tetrahydrofuranylmethyl)propionic acid
| 480438-81-1 |
|
3,3,3-Trifluoro-(2-tetrahydrothienylmethyl)propionic acid
| 480438-83-3 |
|
4,4-Diphenyl-2-cyclohexen-1-one
| |
|
2-Sulfobenzoic acid
| 632-25-7 |
|
1-(4-Bromobutoxy)-2-chlorobenzene
| 23468-00-0 |
|
1-(4-Bromobutoxy)-3-chlorobenzene, 95%
| 23529-80-8 |
|
1-(4-Bromobutoxy)-2,4-dichlorobenzene
| 37395-50-9 |
|
(3-Methylphenoxy)acetic acid
| 1643-15-8 |
|
(4-Methylphenoxy)acetic acid
| 940-64-7 |
|
3-Nitrophenoxyacetic acid, 98%
| 1878-88-2 |
|
4-Nitrophenoxyacetic acid, 95%
| 1798-11-4 |
|
(s)-(-)-1-Phenyl-1-propanol, 95% (98% e.e.)
| 613-87-6 |
|
|