**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 42152-46-5 |Copper(I) trifluoromethanesulfonate be| | 255-686-6 |
| |nzene complex | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and
skin.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Use water spray to keep fire-exposed containers cool. Flammable
solid. Containers may explode if exposed to fire.
Extinguishing Media:
In case of fire, use carbon dioxide, dry chemical powder or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Remove all sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Flammables-area. Store protected from light. Store under
argon.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local explosion-proof ventilation to keep airborne levels
to acceptable levels.
Exposure Limits
CAS# 42152-46-5:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 160 deg C(decom)
Autoignition Temperature: Not available.
Flash Point: 7 deg C ( 44.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H6Cu2F6O6S2
Molecular Weight: 503.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents, air.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride
gas, oxides of copper.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 42152-46-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Copper(I) trifluoromethanesulfonate benzene complex -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.*
Hazard Class: 4.1
UN Number: 1325
Packing Group: III
IMO
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 42152-46-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 42152-46-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 42152-46-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/10/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,5-Dichloro-4-pyridone-1-acetic acid
| 56187-37-2 |
|
Bis(4-methoxyphenyl)disulfide
| 5335-87-5 |
|
1-Benzyl-4-(4,4,5,5-tetramethyl-1,3,2-diox aborolan-2-yl)-1H-pyrazole
| 00-01-1 |
|
3-Biphenylcarboxylic acid
| 716-76-7 |
|
5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan- 2-yl)-1H-indole
| 269410-24-4 |
|
1-Methyl-4-iodo-1H-pyrazole
| 39806-90-1 |
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L-alpha-Cyclohexylglycine
| 14328-51-9 |
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D-alpha-Cyclohexylglycine
| 14328-52-0 |
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Isopropylboronic acid
| 80041-89-0 |
|
n-Propylboronic acid
| 17745-45-8 |
|
Ethylboronic acid
| 4433-63-0 |
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Bacitracin, Potency Min. 60 units/mg (On the Dry Substance)
| 1405-87-4 |
|
Bis(pyridine)iodonium tetrafluoroborate
| 15656-28-7 |
|
Methyl O,O'-bis(2,2,2-trifluoroethyl)phosphonoacetate
| 88738-78-7 |
|
Platinum(II) acetylacetonate
| 15170-57-7 |
|
Ethylenebis(triphenylphosphine)platinum(0)
| 12120-15-9 |
|
Chlorobis(cyclooctene)rhodium(I), dimer
| 12279-09-3 |
|
Chlorobis(cyclooctene)iridium(I), dimer
| 12246-51-4 |
|
trans-Benzyl(chloro)bis(triphenylphosphine )palladium(II)
| 22784-59-4 |
|
Hexaammineruthenium(II) chloride
| 15305-72-3 |
|
Ruthenium(III) acetylacetonate
| 14284-93-6 |
|
Benzeneruthenium(II) chloride, dimer
| 37366-09-9 |
|
cis-Bis(2,2'-bipyridine)dichlororuthenium(II) hydrate
| 98014-14-3 |
|
3-Oxabicyclo[3.1.0]hexane-2,4-dione
| 5617-74-3 |
|
Ethyl trans-4-bromocinnamate
| 24393-53-1 |
|
1-(4-Methylphenyl)piperazine
| 39593-08-3 |
|
Phenyltrimethoxysilane
| 2996-92-1 |
|
5-Bromo-N-(carboxymethyl)anthranilic acid
| 32253-75-1 |
|
Copper(I) trifluoromethanesulfonate benzene complex
| 42152-46-5 |
|
Dihydridotetrakis(triphenylphosphine)ruthenium(II)
| 19529-00-1 |
|
Methyl 1-cyclohexene-1-carboxylate
| 18448-47-0 |
|
2-Bromo-5-nitroanisole
| 77337-82-7 |
|
Isosorbide dimethyl ether
| 5306-85-4 |
|
2-Aminobenzenesulfonamide
| 3306-62-5 |
|
4-(4-Methoxyphenyl)butyric acid
| 4521-28-2 |
|
(S)-2-Amino-5-diethylaminopentane
| 67459-52-3 |
|
Ethyl 2,2-diethoxyacetate, 97%
| 6065-82-3 |
|
N-(3-Aminopropyl)pyrrolidine
| 23159-07-1 |
|
Piperonyloyl chloride
| 25054-53-9 |
|
1,3-Diaminocyclohexane, mixture of isomers
| 3385-21-5 |
|
(R)-2-Amino-5-diethylaminopentane
| 67459-50-1 |
|
Tris(dibenzylideneacetone)dipalladium-chloroform adduct
| 0-01-1 |
|
2-Chloro-N-methoxy-N-methylacetamide
| 67442-07-3 |
|
Methyl 10-chloro-10-oxodecanoate
| 14065-32-8 |
|
1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid, 97%
| 67123-97-1 |
|
1,3-Dimethyl-1H-pyrazol-5-amine, 97%
| 3524-32-1 |
|
6-Chloroimidazo[2,1-b][1,3]thiazole, 97%
| 23576-81-0 |
|
2-Amino-6,7-dimethyl-4-pteridinol, 97%
| 611-55-2 |
|
5-chloro-2-(methylthio)aniline
| 16423-54-4 |
|
2-chloro-6-(trifluoromethyl)pyridine, 97%
| 39890-95-4 |
|
|