**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 442-51-3 |Harmine | 98.0 | 207-131-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect.Possible risks of
irreversible effects.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Repeated or prolonged exposure may cause CNS stimulation. Human
systemic effects by intamuscular route include sleep disturbances,
tremors, nausea or vomiting.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Do
not ingest or inhale. Wash clothing before reuse.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 442-51-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 262 - 264 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H12N2O
Molecular Weight: 212.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 442-51-3: UV0175000
LD50/LC50:
Not available.
Intramuscular, Human - man: TDLo = 3 mg/kg ( Sleep disturbances,
tremors, nausea or
Carcinogenicity:
Harmine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 442-51-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 442-51-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 442-51-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/16/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N-Diisopropylisobutyramide
| 6282-98-0 |
|
M-Carborane
| 16986-24-6 |
|
3-Methoxyphenethylamine
| 2039-67-0 |
|
3,4-(Methylenedioxy)phenylacetic Acid, 98.5+% (Titr.)
| 2861-28-1 |
|
6-Amino-2-methyl-2-heptanol, 98%
| 372-66-7 |
|
6-Amino-2-Methyl-2-Heptanol Hydrochloride, 98+% (Titr.)
| 543-15-7 |
|
1-(3-Methoxyphenyl)-piperazine, 98%
| 16015-71-7 |
|
Isopropyl-??-D-thiogalactopyranoside, DNase, RNase, Protease free
| 367-93-1 |
|
Duolite mb6113, non-regenerable mixed bed resin
| 7732-18-5 |
|
Linolenic acid, 99%
| 463-40-1 |
|
Beta-Tetralone, 95%
| 530-93-8 |
|
Girard's Reagent D
| 5787-71-3 |
|
DL-XYLOSE, 98%
| 41247-05-6 |
|
Esculetin, 98%
| 305-01-1 |
|
Scopoletin, 95%
| 92-61-5 |
|
Sarcosine ethyl ester hydrochloride, 97+%
| 52605-49-9 |
|
Rhapontin, 95%
| 155-58-8 |
|
Pentaerythrityl Tetraacetate
| 597-71-7 |
|
L-4-Chlorophenylalanine, 98%
| 14173-39-8 |
|
(+)-Bicuculline, 98%
| 485-49-4 |
|
Phosphoenolpyruvic Acid, Monopotassium Salt, 99%
| 4265-07-0 |
|
N-(2-Aminoethyl)-Piperidine, 98%
| 27578-60-5 |
|
Coumarin 338, Laser Grade, 99% (UV-Vis)
| 62669-75-4 |
|
beta-D-Glucose pentaacetate, 98%
| 604-69-3 |
|
Harmine, 98%
| 442-51-3 |
|
l-Prolinamide, 98%
| 7531-52-4 |
|
Methyl carbamate, 99%
| 598-55-0 |
|
L-Proline methyl ester hydrochloride, 98%
| 2133-40-6 |
|
Phenyl-beta-d-galactopyranoside, 98%
| 2818-58-8 |
|
Dl-cystine, 99%
| 923-32-0 |
|
6-(Carbobenzyloxyamino)caproic acid, 98%
| 1947-00-8 |
|
2,5-Anhydro-D-Mannitol, 99%
| 41107-82-8 |
|
Cytidine 5'-Monophosphate, Disodium Salt Hydrate
| 6757-06-8 |
|
Beta-Alanine Ethyl Ester Hydrochloride, 98 %
| 4244-84-2 |
|
Ethyl (R)-(-)-2-pyrrolidone-5-carboxylate, 99%
| 68766-96-1 |
|
9-Fluorenylmethyl pentafluorophenyl carbonate, 98%
| 88744-04-1 |
|
2,3:5,6-Di-O-isopropylidine-alpha-D-mannofuranose, 98%
| 14131-84-1 |
|
o-(1,2-Dihydro-2-oxo-1-pyridyl)-n,n,n',n'- tetramethyluronium
| 125700-71-2 |
|
(s)-(+)-5-(Hydroxymethyl)-2-pyrrolidinone, 97%
| 17342-08-4 |
|
L-Serinamide hydrochloride, 98%
| 65414-74-6 |
|
o-Benzotriazol-1-yl-n,n,n',n'-tetramethyluronium tetrafluoroborate,
| 125700-67-6 |
|
O-(n-succinimidyl)-n,n,n',n'-tetramethyl uronium tetrafluoroborate,
| 105832-38-0 |
|
Octafluoronaphthalene, 96%
| 313-72-4 |
|
n-(tert-Butoxycarbonyl)-l-laspartic acid, 99%
| 13726-67-5 |
|
n-alpha-Carbobenzyloxy-l-tryptophan, 99%
| 7432-21-5 |
|
l-Cysteine methyl ester hydrochloride, 98%
| 18598-63-5 |
|
N-Acetyl-5-Hydroxytryptamine, 99%
| 1210-83-9 |
|
DL-Tryptophan, 99+%
| 54-12-6 |
|
3-Bromobenzoic hydrazide, 98%
| 39115-96-3 |
|
2-Amino-5-bromobenzoic acid, 97%
| 5794-88-7 |
|
|