**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 45791-36-4 |(R)-(+)-1-(4-Bromophenyl)ethylamine | 95% | 256-245-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Air sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Place under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Handle under an inert atmosphere. Store protected from air.
Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Do not expose to air. Store under argon.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 45791-36-4:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 140 - 145 deg C @ 30 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.390
Molecular Formula: C8H10BrN
Molecular Weight: 200.08
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Air sensitive.
Conditions to Avoid:
Exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 45791-36-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(R)-(+)-1-(4-Bromophenyl)ethylamine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 45791-36-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 45791-36-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 45791-36-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #2 Date: 2/24/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(S)-1-Octyn-3-ol, 95%, (98% E.E.)
| 32556-71-1 |
|
(R)-1-Octyn-3-ol, 95%, (98% E.E.)
| 32556-70-0 |
|
(2R,5R)-2,5-Hexanediol, 95%, (98% E.E.)
| 17299-07-9 |
|
(R)-2-Aminooctane, 95%, (98% e.e.)
| 693-16-3 |
|
(S)-2-Aminooctane, 95%, (98% e.e.)
| 693-16-3 |
|
(S)-2-Heptylamine, 95%, (98% E.E.)
| 44745-29-1 |
|
(R)-2-Heptylamine, 95%, (98% E.E.)
| 6240-90-0 |
|
(S)-2-Amino-6-methylheptane, 95%, (98% E.E.)
| 70419-10-2 |
|
(R)-2-Amino-6-Methylheptane, 95%, (98% E.E.)
| 70419-11-3 |
|
(S)-3-Amino-3-Phenylpropan-1-ol, 95%, (98% E.E.)
| 82769-76-4 |
|
(R)-3-Amino-3-phenylpropan-1-ol, 95%, (98% e.e.)
| 170564-98-4 |
|
(S)-Cyclohex-2-enylamine, 95%, (98% E.E.)
| 153922-89-5 |
|
(R)-(+)-1-(4-Bromophenyl)ethylamine, 95%, (98% E.E.)
| 45791-36-4 |
|
(S)-3-Butyn-2-ol, 95%, (98% E.E.)
| 2914-69-4 |
|
(R)-(-)-Benzyl Glycidyl Ether
| 14618-80-5 |
|
(S)-(+)-Benzyl Glycidyl Ether
| 16495-13-9 |
|
(R)-(+)-Trityl Glycidyl Ether
| 65291-30-7 |
|
(S)-(-)-Trityl Glycidyl Ether
| 129940-50-7 |
|
(R)-(-)-Methyl Glycidyl Ether
| 64491-70-9 |
|
Molybdenum hexacarbonyl, 98%
| 13939-06-5 |
|
(S)-(+)-Methyl Glycidyl Ether
| 64491-68-5 |
|
(R)-(+)-Propylene Carbonate
| 16606-55-6 |
|
(S)-(-)-3-Chloro-1,2-propanediol acetonide
| 60456-22-6 |
|
Ethyl-(S)-(-)-Chloro-3-Hydroxybutyrate
| 86728-85-0 |
|
Phenyltrichlorosilane, 95%
| 98-13-5 |
|
Tris (2,2,6,6-Tetramethyl-3,5-Heptanedionato)Yttrium(III)
| 15632-39-0 |
|
(2S,4S)-(-)-2,4-Bis(Diphenylphosphino)Pentane
| 77876-39-2 |
|
2-Indanone, 97%
| 615-13-4 |
|
(2R,3R)-(-)-2,3-Bis(Diphenylphosphino)Bicyclo[2.2.1]Hept-5-ene
| 71042-54-1 |
|
1,2-Bis(Diphenylphosphino)Benzene
| 13991-08-7 |
|
(-)-1,2-Bis((2s,5s)-2,5-dimethylphospholano)ethane
| 136779-26-5 |
|
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane
| 129648-07-3 |
|
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene
| 136705-64-1 |
|
(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene
| 147253-67-6 |
|
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene
| 136735-95-0 |
|
(1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-Diphenylethylenediamine
| 144222-34-4 |
|
(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-Diphenylethylenediamine
| 167316-27-0 |
|
(Trimethyl)methylcyclopentadienylplatinum(IV)
| 94442-22-5 |
|
Iridium(III) Chloride Hydrate
| 14996-61-3 |
|
3-Aminopropionitrile fumarate, 99+%
| 2079-89-2 |
|
2-(4-Pyridyl)malondialdehyde
| 51076-46-1 |
|
Iridium(III) Acetylacetonate
| 15635-87-7 |
|
Chlorotricarbonyliridium(I)
| 32594-40-4 |
|
Bis(1,5-Cyclooctadiene)Iridium(I) Tetrafluoroborate
| 35138-23-9 |
|
Bis(tricyclohexylphosphine)palladium(0)
| 33309-88-5 |
|
DL-2-Undecanol, 99%
| 1653-30-1 |
|
Bis(tri-t-butylphosphine)palladium(0)
| 53199-31-8 |
|
Chloronorbornadiene Rhodium(I) Dimer
| 12257-42-0 |
|
Tetrabromophthalic Anhydride, 98%
| 632-79-1 |
|
Dichloro(Pentamethylcyclopentadienyl)Rhodium(III) Dimer
| 12354-85-7 |
|
|