**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 98-13-5 |Phenyltrichlorosilane | 95 | 202-640-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 21 23 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic by inhalation. Causes
burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May be harmful if absorbed through the skin.
Substance is readily absorbed through the skin.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May be fatal if inhaled. Causes chemical burns to the respiratory
tract. Inhalation at high concentrations may cause CNS depression
and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove
victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water hydrolyzes material
liberating acidic gas which in contact with metal surfaces can
generate flammable and/or explosive hydrogen gas. Combustible liquid
and vapor.
Extinguishing Media:
Do NOT use water directly on fire. Use dry chemical, carbon dioxide,
or alcohol-resistant foam. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust. Use a
spark-proof tool. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Do not allow contact with water. Discard contaminated shoes.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Keep from contact
with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 98-13-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear brown
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.5 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 201 deg C @ 760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 91 deg C ( 195.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: hydrolyzes (forming HCl)
Specific Gravity/Density: 1.3210g/cm3
Molecular Formula: C6H5Cl3Si
Molecular Weight: 211.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Forms explosive
mixtures with air. Forms hydrochloric acid with water.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Moisture, water, steam, strong acids, strong bases, strong oxidizing
agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen gas,
silicon dioxide, formaldehyde, chloride fumes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-13-5: VV6650000
LD50/LC50:
CAS# 98-13-5: Draize test, rabbit, skin: 5 mg/24H Severe;
Inhalation, mouse: LC50 = 330 mg/m3/2H; Oral, rat: LD50 = 2390
mg/kg; Skin, rabbit: LD50 = 890 uL/kg.
Skin, rabbit: LD50 = 890 uL/kg or 1170 mg/kg.
LC50 = 330 mg/m3/2H, which is approx 0.66 mg/l/1H.
Carcinogenicity:
Phenyltrichlorosilane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHENYLTRICHLOROSILANE
Hazard Class: 8
UN Number: 1804
Packing Group: II
IMO
Shipping Name: PHENYLTRICHLOROSILANE
Hazard Class: 8
UN Number: 1804
Packing Group: II
RID/ADR
Shipping Name: PHENYLTRICHLOROSILANE
Hazard Class: 8
UN Number: 1804
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 21 Harmful in contact with skin.
R 23 Toxic by inhalation.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 98-13-5: No information available.
Canada
CAS# 98-13-5 is listed on Canada's DSL List.
CAS# 98-13-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 98-13-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #10 Date: 5/23/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(S)-1-Octyn-3-ol, 95%, (98% E.E.)
| 32556-71-1 |
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(R)-1-Octyn-3-ol, 95%, (98% E.E.)
| 32556-70-0 |
|
(2R,5R)-2,5-Hexanediol, 95%, (98% E.E.)
| 17299-07-9 |
|
(R)-2-Aminooctane, 95%, (98% e.e.)
| 693-16-3 |
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(S)-2-Aminooctane, 95%, (98% e.e.)
| 693-16-3 |
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(S)-2-Heptylamine, 95%, (98% E.E.)
| 44745-29-1 |
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(R)-2-Heptylamine, 95%, (98% E.E.)
| 6240-90-0 |
|
(S)-2-Amino-6-methylheptane, 95%, (98% E.E.)
| 70419-10-2 |
|
(R)-2-Amino-6-Methylheptane, 95%, (98% E.E.)
| 70419-11-3 |
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(S)-3-Amino-3-Phenylpropan-1-ol, 95%, (98% E.E.)
| 82769-76-4 |
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(R)-3-Amino-3-phenylpropan-1-ol, 95%, (98% e.e.)
| 170564-98-4 |
|
(S)-Cyclohex-2-enylamine, 95%, (98% E.E.)
| 153922-89-5 |
|
(R)-(+)-1-(4-Bromophenyl)ethylamine, 95%, (98% E.E.)
| 45791-36-4 |
|
(S)-3-Butyn-2-ol, 95%, (98% E.E.)
| 2914-69-4 |
|
(R)-(-)-Benzyl Glycidyl Ether
| 14618-80-5 |
|
(S)-(+)-Benzyl Glycidyl Ether
| 16495-13-9 |
|
(R)-(+)-Trityl Glycidyl Ether
| 65291-30-7 |
|
(S)-(-)-Trityl Glycidyl Ether
| 129940-50-7 |
|
(R)-(-)-Methyl Glycidyl Ether
| 64491-70-9 |
|
Molybdenum hexacarbonyl, 98%
| 13939-06-5 |
|
(S)-(+)-Methyl Glycidyl Ether
| 64491-68-5 |
|
(R)-(+)-Propylene Carbonate
| 16606-55-6 |
|
(S)-(-)-3-Chloro-1,2-propanediol acetonide
| 60456-22-6 |
|
Ethyl-(S)-(-)-Chloro-3-Hydroxybutyrate
| 86728-85-0 |
|
Phenyltrichlorosilane, 95%
| 98-13-5 |
|
Tris (2,2,6,6-Tetramethyl-3,5-Heptanedionato)Yttrium(III)
| 15632-39-0 |
|
(2S,4S)-(-)-2,4-Bis(Diphenylphosphino)Pentane
| 77876-39-2 |
|
2-Indanone, 97%
| 615-13-4 |
|
(2R,3R)-(-)-2,3-Bis(Diphenylphosphino)Bicyclo[2.2.1]Hept-5-ene
| 71042-54-1 |
|
1,2-Bis(Diphenylphosphino)Benzene
| 13991-08-7 |
|
(-)-1,2-Bis((2s,5s)-2,5-dimethylphospholano)ethane
| 136779-26-5 |
|
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane
| 129648-07-3 |
|
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene
| 136705-64-1 |
|
(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene
| 147253-67-6 |
|
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene
| 136735-95-0 |
|
(1R,2R)-(-)-N-(4-Toluenesulfonyl)-1,2-Diphenylethylenediamine
| 144222-34-4 |
|
(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-Diphenylethylenediamine
| 167316-27-0 |
|
(Trimethyl)methylcyclopentadienylplatinum(IV)
| 94442-22-5 |
|
Iridium(III) Chloride Hydrate
| 14996-61-3 |
|
3-Aminopropionitrile fumarate, 99+%
| 2079-89-2 |
|
2-(4-Pyridyl)malondialdehyde
| 51076-46-1 |
|
Iridium(III) Acetylacetonate
| 15635-87-7 |
|
Chlorotricarbonyliridium(I)
| 32594-40-4 |
|
Bis(1,5-Cyclooctadiene)Iridium(I) Tetrafluoroborate
| 35138-23-9 |
|
Bis(tricyclohexylphosphine)palladium(0)
| 33309-88-5 |
|
DL-2-Undecanol, 99%
| 1653-30-1 |
|
Bis(tri-t-butylphosphine)palladium(0)
| 53199-31-8 |
|
Chloronorbornadiene Rhodium(I) Dimer
| 12257-42-0 |
|
Tetrabromophthalic Anhydride, 98%
| 632-79-1 |
|
Dichloro(Pentamethylcyclopentadienyl)Rhodium(III) Dimer
| 12354-85-7 |
|
|