**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 464-48-2 |L(-)-Camphor | >85 | 207-354-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Flammable solid. Vapors
are heavier than air and may travel to a source of ignition and flash
back. Vapors can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
For small fires, use dry chemical, soda ash, lime or sand. For large
fires, use dry sand, dry chemical, soda ash or lime or withdraw from
area and let fire burn.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Remove all sources of ignition. Use a spark-proof
tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames. Use
only with adequate ventilation. Keep away from heat, sparks and
flame. Avoid breathing vapor.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a cool,
dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 464-48-2:
United Kingdom, WEL - TWA: (listed as camphor): 2 ppm TWA; 13 mg/
TWA
United Kingdom, WEL - STEL: (listed as camphor): 3 ppm STEL; 19 m
STEL
United States OSHA: 2 mg/m3 TWA (listed under Camphor).
Belgium - TWA: (listed as camphor): 2 ppm VLE; 12 mg/m3 VLE
Belgium - STEL: (listed as camphor): 3 ppm VLE; 19 mg/m3 VLE
France - VME: (listed as camphor): 2 ppm VME; 12 mg/m3 VME
Germany: (listed as camphor): 2 ppm VME; 12 mg/m3 VME
Malaysia: (listed as camphor): 2 ppm TWA; 12 mg/m3 TWA
Netherlands: (listed as camphor): 2 ppm MAC; 12 mg/m3 MAC
Russia: (listed as camphor): 3 mg/m3 TWA
Spain: (listed as camphor): 2 ppm VLA-ED; 13 mg/m3 VLA-ED
Spain: (listed as camphor): 3 ppm VLA-EC; 19 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Chunks
Color: white
Odor: aromatic odor - characteristic odor
pH: Not available.
Vapor Pressure: 0.65 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 204 deg C @ 760 mm Hg
Freezing/Melting Point: 178 - 180 deg C
Autoignition Temperature: 466 deg C ( 870.80 deg F)
Flash Point: 64 deg C ( 147.20 deg F)
Explosion Limits, lower: 0.6 vol %
Explosion Limits, upper: 3.5 vol %
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 0.992 @ 25C
Molecular Formula: C10H16O
Molecular Weight: 152.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, chlorinated
solvents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 464-48-2: EX1250000
LD50/LC50:
Not available.
Carcinogenicity:
L(-)-Camphor -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CAMPHOR
Hazard Class: 4.1
UN Number: 2717
Packing Group: III
IMO
Shipping Name: CAMPHOR
Hazard Class: 4.1
UN Number: 2717
Packing Group: III
RID/ADR
Shipping Name: CAMPHOR
Hazard Class: 4.1
UN Number: 2717
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 464-48-2: No information available.
Canada
CAS# 464-48-2 is listed on Canada's NDSL List.
CAS# 464-48-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 464-48-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/10/1998 Revision #4 Date: 8/28/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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P-Bromophenethylamine, 98%
| 73918-56-6 |
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Pyridinium Bromide Perbromide, 95 %
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tert-Butylhydrazine hydrochloride, 98%
| 7400-27-3 |
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(+)-cis-1(r),2(s)-1,2-dihydroxy-1,2,3,4- tetrahydronaphthalene, 98+%
| 57495-92-8 |
|
2-Chloroanisole, 98%
| 766-51-8 |
|
2-Nitrobenzoic acid, 98% (titr.)
| 552-16-9 |
|
Triisopropyl phosphite, tech., 90%
| 116-17-6 |
|
Alpha-Tetralone, 98%
| 529-34-0 |
|
4-Bromophenylacetonitrile, 97%
| 16532-79-9 |
|
Pamoic Acid, Disodium Salt, 98%
| 6640-22-8 |
|
5-Hydroxy-2-Indolecarboxylic Acid, 98%
| 21598-06-1 |
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Betaine hydrate
| 17146-86-0 |
|
Dimethyl Glutarate, 98%
| 1119-40-0 |
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4-Bromomethyl-6,7-Dimethoxycoumarin, 95% (Titr.)
| 88404-25-5 |
|
Dysprosium chloride hexahydrate, 99.9%
| 15059-52-6 |
|
Procainamide hydrochloride, 99%
| 614-39-1 |
|
Ethyl Valerate, 99% (GC)
| 539-82-2 |
|
L(-)-Camphor, tech.
| 464-48-2 |
|
(R)-(-)-Phenylsuccinic Acid, 99+%
| 46292-93-7 |
|
L-(+)-2-Amino-6-phosphonohexanoic acid, 98% e.e.
| |
|
Spermidine trihydrochloride, 99+%
| 334-50-9 |
|
4-Nitrophenylacetic acid, 99%
| 104-03-0 |
|
Platinum on 1/8-inch alumina pellets (0.5% pt)
| 7440-06-4 |
|
2-N-propylthiazole, 99%
| 17626-75-4 |
|
4-(Trifluoromethoxy)benzylamine, 97+% (gc)
| 93919-56-3 |
|
S-Carboxymethyl-L-Cysteine, 98%
| 638-23-3 |
|
Tungstic acid, 99+%
| 7783-03-1 |
|
4-Chloro-3-Nitroanisole 98%
| 10298-80-3 |
|
2-Methyl-1-(3-methylphenyl)piperazine
| 35947-10-5 |
|
3,3',4,4'-Benzophenonetetracarboxylic dianhydride, 99% (titr.)
| 2421-28-5 |
|
4-Nitrophthalonitrile
| 31643-49-9 |
|
1,6-Anhydro-Beta-D-Glucopyranose, 99+%
| 498-07-7 |
|
4-Nitrophenylacetonitrile, 98%
| 555-21-5 |
|
2,2,6,6-Tetramethylpiperidine, 98%
| 768-66-1 |
|
2-Piperidinemethanol, Tech., 93%
| 3433-37-2 |
|
L(-)-Borneol, 98%
| 464-45-9 |
|
3-Chloroaniline, 99%
| 108-42-9 |
|
Diglycolic Acid, 98%
| 110-99-6 |
|
4-n-Dodecylresorcinol, 97%
| 24305-56-4 |
|
Poly(acetal)
| 66455-31-0 |
|
Trimethyl Phosphonoacetate , 98%
| 5927-18-4 |
|
n-Undecane, 99%
| 1120-21-4 |
|
Glutathione, Oxidized (GSSG), Hydrate , 98+% (HPLC)
| 121-24-4 |
|
Zirconium silicate, 99%, -325 Mesh
| 10101-52-7 |
|
Sodium hydrogen selenite, p.a.
| 7782-82-3 |
|
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| 134-11-2 |
|
4-Hydroxybenzyl Cyanide, 98%
| 14191-95-8 |
|
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| 37031-30-4 |
|
L-5-Hydroxytryptophan, 99% (TLC)
| 4350-09-8 |
|
6-Methoxytryptamine, 99%
| 3610-36-4 |
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|