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MSDS 
:
 5-(3-Methoxyphenyl)-2-furoic acid
CAS 
:
 54022-96-7
SYNONYMS 
:
 None Known.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 54022-96-7 |2-Aminoacetophenone Hydrochloride | 97+% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Causes burns.

Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Minimize dust generation and accumulation. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use only in
a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 54022-96-7:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: Off white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 168 - 170 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H10O4
Molecular Weight: 218.21

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Amines, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 54022-96-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Aminoacetophenone Hydrochloride -
Not listed by ACGIH, IARC, or NTP.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish: Pseudomonas putida:

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 54022-96-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 54022-96-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 54022-96-7 is not listed on the TSCA inventory.
It is for research and development use only.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 3/23/2005 Revision #1 Date: 4/22/2005

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
NAMECAS
2-Bromo-1-(1-methyl-1H-benzimidazol-2-yl)-1-ethanone 56653-43-1
Dibenzyl Azodicarboxylate, 94+% 2449-05-0
Metanil yellow (tech.), 85% (uv-vis) 587-98-4
6-Quinolinecarboxaldehyde 4113-04-6
5-Pyrimidinecarboxylic acid 4595-61-3
4-Iodopyridine 15854-87-2
5-Methylbenzo[b]thiophene-2-boronic acid 136099-65-5
(2-Piperidino-3-pyridinyl)methanol 690632-84-9
5-Pyrimidinylboronic acid 109299-78-7
5-Methylbenzoxazole, 99.5+%
DL-4-Hydroxymandelic acid monohydrate 184901-84-6
3,5-Dichlorobenzyl Alcohol, 98% 60211-57-6
4-Bromobenzylamine Hydrochloride, 98% 26177-44-6
Ethyl 2-(2-tritylaminothiazole-4-yl)-2-hydroxyiminoacetate 66339-00-2
1,2,5-Oxadiazole-3-carboxylic acid 88598-08-7
(Aminomethyl)Phosphonic Acid, 99% 1066-51-9
2,3-Dihydrobenzo[b]furan-7-methanol 151155-53-2
[2-(4-Methoxyphenoxy)ethyl]ammonium chloride 98959-77-4
2,6-Dichloro-n-hydroxybenzenecarboximidoyl chloride 6579-27-7
5-(3-Methoxyphenyl)-2-furoic acid 54022-96-7
4-Methylthiophene 2-ylmethanol 74395-18-9
2-[2-(Bromomethyl)phenyl]-5,5-dimethyl-1,3,2-dioxaborinane 166821-88-1
1-(4-Methylphenyl)pyrrolidine 91271-80-6
(2s,3s)-(+)-2,3-butanediol,99% 19132-06-0
4-(1,3,2-Dioxaborinan-2-yl)benzaldehyde 160068-88-2
5-Acetyl-2-thiophenecarbaldehyde 4565-29-1
(1-Methyl-1H-imidazol-4-yl)methylamine 486414-83-9
n-Benzyl-3-carbomethoxy-4-piperidone sodium salt,monohydrate, tech.
Gelatin 9000-70-8
3-Methoxy-4-nitrobenzoic acid, 98% 5081-36-7
Gentian Violet 548-62-9
tert-Butyl 4-(4-formylphenyl)tetrahydro-1(2H)-pyrazinecarboxylate 197638-83-8
3-(1H-Imidazol-1-yl)propanoic acid 18999-45-6
tert-Butyl 4-(4-cyanophenyl)tetrahydro-1(2H)-pyrazinecarboxylate 186650-98-6
Barium bromide dihydrate, 99% 7791-28-8
4-[4-(tert-Butoxycarbonyl)piperazino]benzoic acid 162046-66-4
3-(2-Methyl-4-pyrimidinyl)benzenesulfonyl chloride 465514-07-2
(5-Bromobenzo[b]furan-2-yl)methylamine 165736-51-6
Epifluorohydrin, 97% 503-09-3
2-Fluoro-5-methylphenol, 98% 63762-79-8
Trans-Dichlorodiamine Platinum (II), 99.95% 14913-33-8
Terbium tetrafluoride, 99.5%
5-(Bromomethyl)-1,2,3-benzothiadiazole 0-01-1
4-Methylthiophene-2-carbonyl chloride 32990-47-9
(1-Methyl-1H-imidazol-5-yl)methylamine 486414-86-2
5-Methyl-4-isoxazolecarbonyl chloride 67305-24-2
4-Methylthiophene-2-carboxaldehyde 6030-36-0
3-Bromo-2,6-dimethoxybenzoic acid 73219-89-3
3-(1H-1,2,4-Triazol-1-yl)propanoic acid 76686-84-5
Dibenzo[b,d]furan-2-carbaldehyde 5397-82-0

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