**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6317-18-6 |Methylenedithiocyanate | 98% | 228-652-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI N
Risk Phrases: 36/37/38 43 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. May cause
sensitization by skin contact. Very toxic to aquatic
organisms.Lachrymator (substance which increases the flow of
tears).Toxic.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Lachrymator
(substance which increases the flow of tears). May cause
conjunctivitis, ulceration and turbidity of the cornea.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause liver and kidney damage. May
cause central nervous system depression.
Inhalation:
Causes respiratory tract irritation. May cause liver and kidney
damage. Exposure produces central nervous system depression. May
cause lung damage. At high concentrations, isocyanates affect mucous
membranes of the respiratory tract and may lead to fatal pulmonary
edema. Exposure to low and often even unmeasurable isocyanate
concentration results in sensitization. Can produce delayed pulmonary
edema. In rare instances, exposure may cause sensitization, resulting
in inflammation of the mucous membranes and in eczematous eruptions.
Chronic:
May cause liver and kidney damage. Effects may be delayed. May cause
lung damage. Repeated or prolonged exposure may cause allergic
reactions in sensitive individuals. Inhalation of product may
aggravate existing chronic repiratory problems such as asthma,
emphysema or bronchitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
For ingestion, the stomach sould be intubated, aspirated, and
lavaged with a slurry of activated charcoal--protect the airway from
aspiration of gastric contents. Treat symptomatically and
supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. Containers may explode if exposed to fire.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce irritating, corrosive and/or toxic fumes.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 6317-18-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 102.00 - 106.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C3H2N2S2
Molecular Weight: 130.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide, sulfur oxides (SOx),
including sulfur oxide and sulfur dioxide, hydrocarbons.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6317-18-6: XL1560000
LD50/LC50:
CAS# 6317-18-6: Oral, rat: LD50 = 55 mg/kg.
LD50/LC50 - LETHAL DOSE/CONC 50% KILL
55 mg/kg
Carcinogenicity:
Methylenedithiocyanate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 6317-18-6: 2
Canada
CAS# 6317-18-6 is listed on Canada's DSL List.
CAS# 6317-18-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6317-18-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(R)-(-)-sec-Butanol, 99%
| 78-92-2 |
|
4-Acetamidobenzoic acid
| 556-08-1 |
|
5,6-Dimethyl-1H-Benzotriazole Hydrate, 99%
| 4184-79-6 |
|
Alpha-Methyl-1-Piperidineethanol, 97%
| 934-90-7 |
|
3-Bromobenzyl Bromide, 95%
| 823-78-9 |
|
d-(-)-Quinic acid, 98%
| 77-95-2 |
|
3-(Chlorosulfonyl)benzoyl Chloride, 98% (Titr.)
| 4052-92-0 |
|
3-Chloro-4-Hydroxyphenylacetic Acid 99%
| 33697-81-3 |
|
n-Tosyl-3-pyrrolecarboxylic acid, 96%
| 106058-86-0 |
|
Methylenedithiocyanate, 98%
| 6317-18-6 |
|
Tri-n-butylphosphine, 95%
| 998-40-3 |
|
Neocuproine, 99%
| 484-11-7 |
|
M-Tolylurea, 96%
| 63-99-0 |
|
Nonadecanol, 99+%
| 1454-84-8 |
|
Lithium sulfate, anhydrous, 99%
| 10377-48-7 |
|
6-Acetamidohexanoic Acid, 99%
| 57-08-9 |
|
5,5-Dimethyloxazolidine-2,4-Dione, 99%
| 695-53-4 |
|
Tetramethylammonium nitrate
| 1941-24-8 |
|
1,2:5,6-Di-O-Cyclohexylidene-Alpha-D-Gluco Furanose, 96%
| 23397-76-4 |
|
Ethyl benzoylacetate, 97%
| 94-02-0 |
|
3-(1-Hydroxyethyl)aniline, 98%
| 2454-37-7 |
|
2-Deoxy-D-Glucose, 99%
| 154-17-6 |
|
1-Pyrrolidino-1-cyclopentene, 98%
| 7148-07-4 |
|
1,1',3,3,3',3'-Hexamethylindodicarbocyanine iodide, laser grade, 99%
| 36536-22-8 |
|
3-Amino-5-methylthio-1h-1,2,4-triazole
| 45534-08-5 |
|
Triptycene, 99% (HPLC)
| 477-75-8 |
|
2-Bromoanisole, 97%
| 578-57-4 |
|
2-Phenylphenol, 99+%
| 90-43-7 |
|
3-Acetylthiophene, 98%
| 1468-83-3 |
|
2,5-Diphenyl-1,3,4-oxadiazole, 97%
| 725-12-2 |
|
(D,L)-1-Aminoethylphosphonic Acid, 97%
| 6323-97-3 |
|
2,3,5,6-Tetrafluoroaniline, 98%
| 700-17-4 |
|
4'-Nitroacetanilide (Pract)
| 104-04-1 |
|
4-Aminobenzophenone, 98%
| 1137-41-3 |
|
3-Acetylbenzenesulfonyl fluoride, 99%
| 709-60-4 |
|
1,2:5,6-Di-O-Cyclohexylidene-3-O-Methyl-Alpha-D-Glucofuranose, 98%
| 13440-19-2 |
|
Potassium tetrachloroplatinate(II)
| 10025-99-7 |
|
Diethyl Benzylphosphonate, 99%
| 1080-32-6 |
|
4-Aminophthalimide, 97% (UV-Vis)
| 3676-85-5 |
|
1-Heptanesulfonic acid sodium salt pre- mixed concentrate
| 0-00-0 |
|
4-(2-Aminoethyl)-Benzenesulfonamide Monohydrochloride, 99+%
| 42286-14-6 |
|
Tetraheptylammonium Bromide, 99%
| 4368-51-8 |
|
Methyl Valerate, 99% (GC)
| 624-24-8 |
|
Duolite c 206a
| |
|
4'-Aminoacetophenone, 99%
| 99-92-3 |
|
Ricinoleic Acid (Pract), 85% Castor Oil Fatty Acid
| 141-22-0 |
|
3-Chlorobenzyl Chloride, 98%
| 620-20-2 |
|
Carbonyl Cyanide M-Chlorophenylhydrazone, 99+%
| 555-60-2 |
|
1,3-Dimethyladamantane, 99+%
| 702-79-4 |
|
Dl-1,4-dibromo-2,3-butanediol,95%
| 299-70-7 |
|
|