**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 700-17-4 |2,3,5,6-Tetrafluoroaniline | 98% | 211-840-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death. The
toxicological properties of this substance have not been fully
investigated. May cause central nervous system depression.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death. The toxicological properties of this substance have not
been fully investigated. Aspiration may lead to pulmonary edema. May
cause cardiac abnormalities. Inhalation at high concentrations may
cause CNS depression and asphixiation.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. Effects
may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode
when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Use with adequate ventilation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 700-17-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Mass
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 158 deg C @ 760.00mmHg
Freezing/Melting Point: 31.00 - 32.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 62 deg C ( 143.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H3F4N
Molecular Weight: 165.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 700-17-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3,5,6-Tetrafluoroaniline -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 700-17-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 700-17-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 700-17-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(R)-(-)-sec-Butanol, 99%
| 78-92-2 |
|
4-Acetamidobenzoic acid
| 556-08-1 |
|
5,6-Dimethyl-1H-Benzotriazole Hydrate, 99%
| 4184-79-6 |
|
Alpha-Methyl-1-Piperidineethanol, 97%
| 934-90-7 |
|
3-Bromobenzyl Bromide, 95%
| 823-78-9 |
|
d-(-)-Quinic acid, 98%
| 77-95-2 |
|
3-(Chlorosulfonyl)benzoyl Chloride, 98% (Titr.)
| 4052-92-0 |
|
3-Chloro-4-Hydroxyphenylacetic Acid 99%
| 33697-81-3 |
|
n-Tosyl-3-pyrrolecarboxylic acid, 96%
| 106058-86-0 |
|
Methylenedithiocyanate, 98%
| 6317-18-6 |
|
Tri-n-butylphosphine, 95%
| 998-40-3 |
|
Neocuproine, 99%
| 484-11-7 |
|
M-Tolylurea, 96%
| 63-99-0 |
|
Nonadecanol, 99+%
| 1454-84-8 |
|
Lithium sulfate, anhydrous, 99%
| 10377-48-7 |
|
6-Acetamidohexanoic Acid, 99%
| 57-08-9 |
|
5,5-Dimethyloxazolidine-2,4-Dione, 99%
| 695-53-4 |
|
Tetramethylammonium nitrate
| 1941-24-8 |
|
1,2:5,6-Di-O-Cyclohexylidene-Alpha-D-Gluco Furanose, 96%
| 23397-76-4 |
|
Ethyl benzoylacetate, 97%
| 94-02-0 |
|
3-(1-Hydroxyethyl)aniline, 98%
| 2454-37-7 |
|
2-Deoxy-D-Glucose, 99%
| 154-17-6 |
|
1-Pyrrolidino-1-cyclopentene, 98%
| 7148-07-4 |
|
1,1',3,3,3',3'-Hexamethylindodicarbocyanine iodide, laser grade, 99%
| 36536-22-8 |
|
3-Amino-5-methylthio-1h-1,2,4-triazole
| 45534-08-5 |
|
Triptycene, 99% (HPLC)
| 477-75-8 |
|
2-Bromoanisole, 97%
| 578-57-4 |
|
2-Phenylphenol, 99+%
| 90-43-7 |
|
3-Acetylthiophene, 98%
| 1468-83-3 |
|
2,5-Diphenyl-1,3,4-oxadiazole, 97%
| 725-12-2 |
|
(D,L)-1-Aminoethylphosphonic Acid, 97%
| 6323-97-3 |
|
2,3,5,6-Tetrafluoroaniline, 98%
| 700-17-4 |
|
4'-Nitroacetanilide (Pract)
| 104-04-1 |
|
4-Aminobenzophenone, 98%
| 1137-41-3 |
|
3-Acetylbenzenesulfonyl fluoride, 99%
| 709-60-4 |
|
1,2:5,6-Di-O-Cyclohexylidene-3-O-Methyl-Alpha-D-Glucofuranose, 98%
| 13440-19-2 |
|
Potassium tetrachloroplatinate(II)
| 10025-99-7 |
|
Diethyl Benzylphosphonate, 99%
| 1080-32-6 |
|
4-Aminophthalimide, 97% (UV-Vis)
| 3676-85-5 |
|
1-Heptanesulfonic acid sodium salt pre- mixed concentrate
| 0-00-0 |
|
4-(2-Aminoethyl)-Benzenesulfonamide Monohydrochloride, 99+%
| 42286-14-6 |
|
Tetraheptylammonium Bromide, 99%
| 4368-51-8 |
|
Methyl Valerate, 99% (GC)
| 624-24-8 |
|
Duolite c 206a
| |
|
4'-Aminoacetophenone, 99%
| 99-92-3 |
|
Ricinoleic Acid (Pract), 85% Castor Oil Fatty Acid
| 141-22-0 |
|
3-Chlorobenzyl Chloride, 98%
| 620-20-2 |
|
Carbonyl Cyanide M-Chlorophenylhydrazone, 99+%
| 555-60-2 |
|
1,3-Dimethyladamantane, 99+%
| 702-79-4 |
|
Dl-1,4-dibromo-2,3-butanediol,95%
| 299-70-7 |
|
|