**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 65-85-0 |Benzoic acid | ca 22% | 200-618-2 |
|----------------|--------------------------------------|----------|-----------|
| 121-91-5 |Isophtalic acid | ca 29% | 204-506-4 |
|----------------|--------------------------------------|----------|-----------|
| 61717-82-6 |2-Iodoxybenzoic acid | ca 49% | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 64297-64-9 |2-Iodoxybenzoic acid, stabilized | | 264-773-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 20/21/22 35 44
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Causes
severe burns. Risk of explosion if heated under confinement.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Violently decomposes when heated under confinement.
Containers may explode if exposed to fire. Risk of explosion if
heated under confinement.
Extinguishing Media:
Use dry powder or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep away from heat, sparks and flame. Use only
in a chemical fume hood.
Storage:
Keep away from heat and flame. Store in a cool, dry place. Store in
a tightly closed container. Corrosives area. Store protected from
light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 65-85-0:
CAS# 121-91-5:
Russia: 0.2 mg/m3 TWA
CAS# 61717-82-6:
CAS# 64297-64-9:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to pale yellow
Odor: Not available.
pH: 1.6
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 280 deg C(decom)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H5IO5
Molecular Weight: 280.01
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Light sensitive. Risk of explosion if heated under confinement.
Conditions to Avoid:
Incompatible materials, light, temperatures above 200C.
Incompatibilities with Other Materials:
Strong oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen iodide, iodine.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 65-85-0: DG0875000
CAS# 121-91-5: NT2007000
CAS# 61717-82-6 unlisted.
CAS# 64297-64-9 unlisted.
LD50/LC50:
CAS# 65-85-0: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >26 mg/m3/1H;
Oral, mouse: LD50 = 1940 mg/kg; Oral, rat: LD50 = 1700 mg/kg; Skin,
rabbit: LD50 = >10 gm/kg.
CAS# 121-91-5: Draize test, rabbit, eye: 500 mg/24H Mild; Oral, rat:
LD50 = 10400 mg/kg.
CAS# 61717-82-6.
CAS# 64297-64-9.
Carcinogenicity:
Benzoic acid -
Not listed by ACGIH, IARC, or NTP.
Isophtalic acid -
Not listed by ACGIH, IARC, or NTP.
2-Iodoxybenzoic acid -
Not listed by ACGIH, IARC, or NTP.
2-Iodoxybenzoic acid, stabilized -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: II
USA RQ: CAS# 65-85-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 35 Causes severe burns.
R 44 Risk of explosion if heated under confinement.
Safety Phrases:
S 15 Keep away from heat.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 65-85-0: 1
CAS# 121-91-5: 0
CAS# 61717-82-6: No information available.
CAS# 64297-64-9: No information available.
Canada
CAS# 65-85-0 is listed on Canada's DSL List.
CAS# 121-91-5 is listed on Canada's DSL List.
CAS# 65-85-0 is listed on Canada's Ingredient Disclosure List.
CAS# 121-91-5 is listed on Canada's Ingredient Disclosure List.
CAS# 61717-82-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 64297-64-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 65-85-0 is listed on the TSCA inventory.
CAS# 121-91-5 is listed on the TSCA inventory.
CAS# 61717-82-6 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 64297-64-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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