**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 8008-20-6 |Kerosene | >99 | 232-366-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 65
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful: may cause lung damage if swallowed.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may
cause defatting of the skin and dermatitis. May be absorbed through
damaged or abraded skin in harmful amounts.
Ingestion:
Aspiration hazard. May cause severe digestive tract irritation with
abdominal pain, nausea, vomiting and diarrhea. Aspiration of
material into the lungs may cause chemical pneumonitis, which may be
fatal. May cause central nervous system depression.
Inhalation:
Causes respiratory tract irritation. Irritation may lead to chemical
pneumonitis and pulmonary edema. Exposure produces central nervous
system depression. Aspiration may cause respiratory swelling and
pneumonitis. Aspiration may lead to pulmonary edema.
Chronic:
Prolonged or repeated inhalation of dusts may cause neurological
damage. Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause anemia and other blood cell abnormalities.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Containers
may explode in the heat of a fire. Liquid will float and may reignite
on the surface of water. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. For large fires,
use water spray, fog or regular foam. For small fires, use dry
chemical, carbon dioxide, water spray or regular foam. Cool
containers with flooding quantities of water until well after fire is
out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Wear a self contained breathing apparatus and appropriate personal
protection. (See Exposure Controls, Personal Protection section).
Scoop up with a nonsparking tool, then place into a suitable
container for disposal. Remove all sources of ignition. Absorb spill
using an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust.
Provide ventilation. Water spray may reduce vapor but may not prevent
ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not ingest or inhale. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 8008-20-6:
Russia: 300 mg/m3 TWA (as C)
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: pale yellow
Odor: odorless
pH: Not available.
Vapor Pressure: 5 mm Hg @ 38C
Viscosity: >1.3 CST @ 40C
Boiling Point: 304-574F
Freezing/Melting Point: 0 deg F
Autoignition Temperature: 410 deg F ( 210.00 deg C)
Flash Point: 43-79C
Explosion Limits, lower: 0.7
Explosion Limits, upper: 5.0
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 0.8 (water=1)
Molecular Formula: Not applicable.
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizers.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrocarbons.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 8008-20-6: OA5500000
LD50/LC50:
CAS# 8008-20-6: Draize test, rabbit, skin: 500 mg Severe; Draize
test, rabbit, skin: 100%/24H Moderate; Oral, rabbit: LD50 = 2835
mg/kg.
Carcinogenicity:
Kerosene -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bluegill (fresh water) TLm=2990ppm/24H
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 65 Harmful: may cause lung damage if swallowed.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24 Avoid contact with skin.
S 62 If swallowed, do not induce vomiting: seek
medical advice immediately and show this container or
label.
WGK (Water Danger/Protection)
CAS# 8008-20-6: No information available.
Canada
CAS# 8008-20-6 is listed on Canada's DSL List.
CAS# 8008-20-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 8008-20-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 6/26/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|