**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 69584-87-8 |2,5-Difluorophenylacetonitrile | 97% | 274-051-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin. May
be metabolized to cyanide which in turn acts by inhibiting cytochrome
oxidase impairing cellular respiration.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully
investigated. Metabolism may release cyanide, which may result in
headache, dizziness, weakness, collapse, unconsciousness and
possible death.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. The
toxicological properties of this substance have not been fully
investigated. May be metabolized to cyanide which in turns act by
inhibiting cytochrome oxidase impairing cellular respiration.
Chronic:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration. Exposure to small
amounts of cyanide compounds over long periods of time is reported
to cause loss of appetite, headache, weakness, nausea, dizziness, and
symptoms of irritation of the upper respiratory tract and eyes.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin,
and clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 69584-87-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2330g/cm3
Molecular Formula: F2C6H3CH2CN
Molecular Weight: 153.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide, hydrogen
fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 69584-87-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,5-Difluorophenylacetonitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRILES, LIQUID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 69584-87-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 69584-87-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 69584-87-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/07/1999 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4-Difluorophenylacetonitrile, 98%
| 656-35-9 |
|
n-Acetyl-2-fluoro-dl-phenylalanine, 98%
| 66574-84-3 |
|
n- Acetyl-4-Fluoro-DL-Phenylalanine, 98%
| 17481-06-0 |
|
Allylpentafluorobenzene, 97%
| 1736-60-3 |
|
2-Bromo-5-(trifluoromethyl)aniline, 98%
| 454-79-5 |
|
2-Fluoro-3-(trifluoromethyl)aniline, 98%
| 123973-25-1 |
|
4-Amino-2,3,5,6-tetrafluorobenzoic acid, 9 9%
| 944-43-4 |
|
2-Benzoylacetanilide
| 85-99-4 |
|
2-Amino-5-trifluoromethyl-1,3,4-thiadiazol e
| 10444-89-0 |
|
Ammonium hexafluorosilicate, 99.999%
| 16919-19-0 |
|
Ammonium Tetrafluoroborate, 97+%
| 13826-83-0 |
|
1,2,4,5-Benzenetetracarboxylic anhydride, 99%
| 89-32-7 |
|
4-Phenyl-3-Thiosemicarbazide, 99%
| 5351-69-9 |
|
2-Fluorophenethyl alcohol, 99%
| 50919-06-7 |
|
4",4"'-(hexafluoroisopropylidene)bis(4-phe noxyaniline), 98%
| 69563-88-8 |
|
4,4'-(Hexafluoroisopropylidene)dianiline, 98%
| 1095-78-9 |
|
4,4'-(Hexafluoroisopropylidene)ditoluene, 98 wt%
| 1095-77-8 |
|
Bismuth (III) Fluoride, 98%
| 7787-61-3 |
|
Oil Blue N
| 2646-15-3 |
|
3'-Bromo-4'-fluoroacetophenone, 97 wt%
| 1007-15-4 |
|
2-Bromo-4-Fluorophenol, 98%
| 496-69-5 |
|
2-Acetamido-2-Deoxy-alpha-D-Glucopyranose, 99.5+%
| 10036-64-3 |
|
4-Bromo-3-fluorotoluene, 98%
| 452-74-4 |
|
2-Bromo-5-Nitrobenzotrifluoride, 98%
| 367-67-9 |
|
1-Bromo-2,3,4,5-tetrafluorobenzene, 98%
| 1074-91-5 |
|
1-Bromo-2,4,6-trifluorobenzene, 99%
| 2367-76-2 |
|
Cerium(III)Fluoride Anhydrous, 99.9%
| 7758-88-5 |
|
2-Chloro-5-(trifluoromethyl)benzonitrile, 98%
| 328-87-0 |
|
1-Chloro-2,4-difluorobenzene, 98%
| 1435-44-5 |
|
2-Chloro-3,5-difluorophenol, 98%
| |
|
2,5-Difluorophenylacetonitrile, 97%
| 69584-87-8 |
|
2,5-Dimethyl-1,3,4-thiadiazole, 99%
| 27464-82-0 |
|
2,6-Difluorophenylacetonitrile, 98%
| 654-01-3 |
|
2,4-Difluorophenylhydrazine Hydrochloride, 97%
| 51523-79-6 |
|
1,2-DIIODOTETRAFLUOROBENZENE, 99%
| 2708-97-6 |
|
3',5'-Bis(Trifluoromethyl)Acetophenone, 98%
| 30071-93-3 |
|
1,3-Bis(trifluoromethyl)benzene
| 402-31-3 |
|
2,4-Bis(trifluoromethyl)benzoic acid, 98%
| 32890-87-2 |
|
2,6-Bis(Trifluoromethyl)Benzoic Acid, 98%
| 24821-22-5 |
|
3,5-Bis(trifluoromethyl)benzonitrile, 97%
| 27126-93-8 |
|
3,3'-Bis(Trifluoromethyl)Benzophenone, 98%
| 1868-00-4 |
|
3,4'-Bis(Trifluoromethyl)benzophenone, 98%
| 21084-22-0 |
|
3,5-BIS(TRIFLUOROMETHYL)BENZYL CHLORIDE, 98%
| 75462-59-8 |
|
2,4-Bis(Trifluoromethyl)Bromobenzene, 98%
| 327-75-3 |
|
3-Chloro-4-fluorobenzonitrile, 99%
| 117482-84-5 |
|
2-Chloro-4-fluorotoluene, 98%
| 452-73-3 |
|
4-Chloro-8-(trifluoromethyl)quinoline, 97%
| 23779-97-7 |
|
Chromium (II) Fluoride, 99%
| 10049-10-2 |
|
Cobalt(ii) fluoride, 99%
| 10026-17-2 |
|
Cobalt(ii)tetrafluoroborate hexahydrate, 99%
| 15684-35-2 |
|
|