**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7758-88-5 |Cerium(III)Fluoride | 99 | 231-841-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 32 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with acids liberates very toxic gas. Irritating to eyes,
respiratory system and skin.Light sensitive.Moisture sensitive.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Inorganic fluorides can
be harmful. Acute exposure to fluorine compounds can lead to
digestive tract burns, and abdominal pain.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Chronic exposure to
fluoride compounds may cause systemic toxicity.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation. Use with adequate
ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7758-88-5:
Russia: 2.5 mg/m3 TWA
Russia: 0.5 mg/m3 STEL
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 2300 deg C
Freezing/Melting Point: 1640 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: CeF3
Molecular Weight: 197.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, dust generation, moisture.
Incompatibilities with Other Materials:
Acids, strong oxidizing agents, active metals.
Hazardous Decomposition Products:
Hydrogen fluoride gas, fluorine.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7758-88-5: FK6125000
LD50/LC50:
CAS# 7758-88-5: Oral, rat: LD50 = >5 gm/kg.
Carcinogenicity:
Cerium(III)Fluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3260
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 32 Contact with acids liberates very toxic gas.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 50 Do not mix with ... (to be specified by the
manufacturer).
WGK (Water Danger/Protection)
CAS# 7758-88-5: 0
Canada
CAS# 7758-88-5 is listed on Canada's DSL List.
CAS# 7758-88-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7758-88-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/14/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4-Difluorophenylacetonitrile, 98%
| 656-35-9 |
|
n-Acetyl-2-fluoro-dl-phenylalanine, 98%
| 66574-84-3 |
|
n- Acetyl-4-Fluoro-DL-Phenylalanine, 98%
| 17481-06-0 |
|
Allylpentafluorobenzene, 97%
| 1736-60-3 |
|
2-Bromo-5-(trifluoromethyl)aniline, 98%
| 454-79-5 |
|
2-Fluoro-3-(trifluoromethyl)aniline, 98%
| 123973-25-1 |
|
4-Amino-2,3,5,6-tetrafluorobenzoic acid, 9 9%
| 944-43-4 |
|
2-Benzoylacetanilide
| 85-99-4 |
|
2-Amino-5-trifluoromethyl-1,3,4-thiadiazol e
| 10444-89-0 |
|
Ammonium hexafluorosilicate, 99.999%
| 16919-19-0 |
|
Ammonium Tetrafluoroborate, 97+%
| 13826-83-0 |
|
1,2,4,5-Benzenetetracarboxylic anhydride, 99%
| 89-32-7 |
|
4-Phenyl-3-Thiosemicarbazide, 99%
| 5351-69-9 |
|
2-Fluorophenethyl alcohol, 99%
| 50919-06-7 |
|
4",4"'-(hexafluoroisopropylidene)bis(4-phe noxyaniline), 98%
| 69563-88-8 |
|
4,4'-(Hexafluoroisopropylidene)dianiline, 98%
| 1095-78-9 |
|
4,4'-(Hexafluoroisopropylidene)ditoluene, 98 wt%
| 1095-77-8 |
|
Bismuth (III) Fluoride, 98%
| 7787-61-3 |
|
Oil Blue N
| 2646-15-3 |
|
3'-Bromo-4'-fluoroacetophenone, 97 wt%
| 1007-15-4 |
|
2-Bromo-4-Fluorophenol, 98%
| 496-69-5 |
|
2-Acetamido-2-Deoxy-alpha-D-Glucopyranose, 99.5+%
| 10036-64-3 |
|
4-Bromo-3-fluorotoluene, 98%
| 452-74-4 |
|
2-Bromo-5-Nitrobenzotrifluoride, 98%
| 367-67-9 |
|
1-Bromo-2,3,4,5-tetrafluorobenzene, 98%
| 1074-91-5 |
|
1-Bromo-2,4,6-trifluorobenzene, 99%
| 2367-76-2 |
|
Cerium(III)Fluoride Anhydrous, 99.9%
| 7758-88-5 |
|
2-Chloro-5-(trifluoromethyl)benzonitrile, 98%
| 328-87-0 |
|
1-Chloro-2,4-difluorobenzene, 98%
| 1435-44-5 |
|
2-Chloro-3,5-difluorophenol, 98%
| |
|
2,5-Difluorophenylacetonitrile, 97%
| 69584-87-8 |
|
2,5-Dimethyl-1,3,4-thiadiazole, 99%
| 27464-82-0 |
|
2,6-Difluorophenylacetonitrile, 98%
| 654-01-3 |
|
2,4-Difluorophenylhydrazine Hydrochloride, 97%
| 51523-79-6 |
|
1,2-DIIODOTETRAFLUOROBENZENE, 99%
| 2708-97-6 |
|
3',5'-Bis(Trifluoromethyl)Acetophenone, 98%
| 30071-93-3 |
|
1,3-Bis(trifluoromethyl)benzene
| 402-31-3 |
|
2,4-Bis(trifluoromethyl)benzoic acid, 98%
| 32890-87-2 |
|
2,6-Bis(Trifluoromethyl)Benzoic Acid, 98%
| 24821-22-5 |
|
3,5-Bis(trifluoromethyl)benzonitrile, 97%
| 27126-93-8 |
|
3,3'-Bis(Trifluoromethyl)Benzophenone, 98%
| 1868-00-4 |
|
3,4'-Bis(Trifluoromethyl)benzophenone, 98%
| 21084-22-0 |
|
3,5-BIS(TRIFLUOROMETHYL)BENZYL CHLORIDE, 98%
| 75462-59-8 |
|
2,4-Bis(Trifluoromethyl)Bromobenzene, 98%
| 327-75-3 |
|
3-Chloro-4-fluorobenzonitrile, 99%
| 117482-84-5 |
|
2-Chloro-4-fluorotoluene, 98%
| 452-73-3 |
|
4-Chloro-8-(trifluoromethyl)quinoline, 97%
| 23779-97-7 |
|
Chromium (II) Fluoride, 99%
| 10049-10-2 |
|
Cobalt(ii) fluoride, 99%
| 10026-17-2 |
|
Cobalt(ii)tetrafluoroborate hexahydrate, 99%
| 15684-35-2 |
|
|