**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7580-67-8 |Lithium hydride, in resealable cans | 98% | 231-484-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 14/15 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water liberating extremely flammable gases.
Causes burns.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury.
Skin:
Causes irritation with burning pain, itching, and redness.
Ingestion:
Causes gastrointestinal tract burns. Causes cough, sore throat,
chest pain, and lightheadedness.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water Reactive. Material will react with water and
may release a flammable and/or toxic gas. This material in
sufficient quantity and reduced particle size is capable of creating
a dust explosion. Flammable solid.
Extinguishing Media:
Do NOT use carbon dioxide. Do NOT use halogenated agents. Use
approved class D extinguishing agents or smother with dry sand,
clay, or sodium bicarbonate. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Remove all sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Take precautionary measures against static discharges. Use
only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a tightly closed container. Store in a dry area. Keep under
a nitrogen blanket. Keep away from water. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 7580-67-8:
United Kingdom, WEL - TWA: 0.025 mg/m3 TWA
United Kingdom, WEL - STEL: 0.075 mg/m3 STEL
United States OSHA: 0.025 mg/m3 TWA
Belgium - TWA: 0.025 mg/m3 VLE
France - VME: 0.025 mg/m3 VME
Germany: 0.025 mg/m3 TWA
Malaysia: 0.025 mg/m3 TWA
Netherlands: 0.025 mg/m3 MAC
Spain: 0.025 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: blue - blue-gray
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 680 deg C
Autoignition Temperature: 200 deg C ( 392.00 deg F)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in ether
Specific Gravity/Density: .8200g/cm3
Molecular Formula: LiH
Molecular Weight: 7.95
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Unstable. Substance undergoes color change upon exposure to light
and air.
Conditions to Avoid:
Incompatible materials, light, ignition sources, exposure to air,
exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, alcohols, oxygen, chlorine.
Hazardous Decomposition Products:
Hydrogen gas, lithium hydroxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7580-67-8: OJ6300000
LD50/LC50:
CAS# 7580-67-8: Oral, rat: LD50 = 77500 ug/kg.
Carcinogenicity:
Lithium hydride, in resealable cans -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Do not empty into drains.
Lithium salts: Poisonous effects on fish:
100 mg/l, crabs (16mg/l) and plants (0.2 mg/l)
Hazard to water: class
in accordance with water Water Resources Act (of LiOH) = 1
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 14/15 Reacts violently with water liberating
extremely flammable gases.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7580-67-8: No information available.
Canada
CAS# 7580-67-8 is listed on Canada's NDSL List.
CAS# 7580-67-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7580-67-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/31/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(+)-Himbacine
| 6879-74-9 |
|
Ytterbium(III) triflate hydrate, 99.9%
| 252976-51-5 |
|
Ethyl oleate, mixture of isomers, tech., 90%
| 111-62-6 |
|
Sodium hydride, 60% dispersion in mineral oil, in resealable cans
| 7646-69-7 |
|
3-(Trifluoromethyl)phenylhydrazine, tech.,, 90%
| 368-78-5 |
|
N,N'-Diaminoguanidine Monohydrochloride 98%
| 36062-19-8 |
|
Iron(III) fluoride, anhydrous, 98%
| 7783-50-8 |
|
2-Mercaptobenzothiazole, 99% (Titr.)
| 149-30-4 |
|
3-Amino-2,6-Dimethoxypyridine Monohydrochloride, 95%
| 80789-72-6 |
|
Lithium hydride, in resealable cans, 98%
| 7580-67-8 |
|
1,4-Bis(trimethylsilyl)benzene, 98%
| 13183-70-5 |
|
Carboxymethyl Cellulose, Sodium Salt, Average MW 90.000
| 9004-32-4 |
|
Carboxymethyl Cellulose, Sodium Salt, Average MW 250000 (DS=0.7)
| 9004-32-4 |
|
Carboxymethyl Cellulose, Sodium Salt, Average MW 250000 (DS=0.9)
| 9004-32-4 |
|
Carboxymethyl Cellulose, Sodium Salt, Average MW 250000 (DG=1.2)
| 9004-32-4 |
|
Carboxymethyl Cellulose, Sodium Salt, Average MW 700000
| 9004-32-4 |
|
Tyloxapol
| 25301-02-4 |
|
4-Vinylbenzyl chloride, stabilized with 500 ppm 4-tert-butylcatechol
| 1592-20-7 |
|
Ethyl 3-phenylglycidate, 90%
| 121-39-1 |
|
2-Methyltetrahydrofuran-3-thiol
| 57124-87-5 |
|
Bis(2-methyl-3-furyl)disulphide, 98%
| 28588-75-2 |
|
2-Methylfuran-3-thiolacetate, 80%
| 55764-25-5 |
|
2-Tetrahydrofuroic acid, 99+%(gc)
| 16874-33-2 |
|
2,2,4,4,6,6-Hexamethyl-S-trithiane
| 828-26-2 |
|
MALEIC ACID, DISODIUM SALT, HYDRATE
| 371-47-1 |
|
Neurodye Di-8-ANEPPQ
| 0-01-1 |
|
Neurodye Di-12-ANEPPQ
| 0-01-1 |
|
Neurodye Di-4-ANEPPS
| 90134-00-2 |
|
Neurodye Di-8-ANEPPS
| 157134-33-7 |
|
Thallous formate, 98% (titr.)
| 992-98-3 |
|
Neurodye FM1-84
| 0-01-1 |
|
Neurodye RH-237
| 0-01-1 |
|
Neurodye RH-421
| 107610-19-5 |
|
Neurodye RH-795
| 0-01-1 |
|
Neurodye FM1-43
| 149838-22-2 |
|
Neurodye FM4-64
| 0-01-1 |
|
Neurodye FM2-10
| 0-01-1 |
|
ISOQUINOLINE-N-OXIDE
| 1532-72-5 |
|
1,3-Dithiolane-2,4,5-trithione, oligomer
| 123399-69-9 |
|
Dess-Martin periodinane, 15 wt% solution in dichloromethane
| 75-09-2 |
|
N-BENZYLIDENE-1-NAPTHYLAMINE, 97%
| 890-51-7 |
|
2-METHOXY-1-NAPHTHALENEMETHANOL
| 40696-22-8 |
|
(S)-(+)-Ibuprofen, 99%
| 51146-56-6 |
|
2-ETHOXYNAPHTHALENE, 98%
| 93-18-5 |
|
Trifluoromethanesulphinic acid potassium salt
| 41804-89-1 |
|
5-Chlorobarbituric acid
| 19645-77-3 |
|
n-Butyl (2R,3S)-(-)-2,3-epoxybutyrate, 98%
| 0-01-1 |
|
Diethyl (2R,3R)-(-)-2,3-epoxysuccinate, 98%
| 74243-85-9 |
|
Diethyl (2S,3S)-(+)-2,3-epoxysuccinate, 98%
| 73890-18-3 |
|
Benzo(e)pyrene, 99%
| 192-97-2 |
|
|