**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 88-74-4 |2-Nitroaniline | 98 | 201-855-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 33 52/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects. Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. If absorbed, causes symptoms similar to
those of ingestion. Substance is readily absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death. May be
harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death. The toxicological properties of this substance have not
been fully investigated.
Chronic:
Chronic ingestion may cause liver damage. May cause
methemoglobinemia, which is characterized by chocolate-brown colored
blood, headache, weakness, dizziness, breath shortness, cyanosis
(bluish skin due to deficient oxygenation of blood), rapid heart
rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Effects may be delayed. Treat symptomatically and supportively. For
methemoglobinemia, administer oxygen alone or with Methylene Blue
depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. May
polymerize explosively when involved in a fire. May decompose
explosively when heated or involved in a fire. Contact with metals
may evolve flammable hydrogen gas. Containers may explode when
heated. Combustible material; may burn but does not ignite readily.
Extinguishing Media:
Cool containers with flooding quantities of water until well after
fire is out. Use water spray, dry chemical, carbon dioxide, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use only in
a chemical fume hood.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Poison room locked. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 88-74-4:
Russia: 0.5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: yellow orange
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 284 deg C
Freezing/Melting Point: 71.0 - 73.0 deg C
Autoignition Temperature: Not applicable.
Flash Point: 168 deg C ( 334.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 280 deg C
Solubility in water: 1.1 g/l (20 c)
Specific Gravity/Density:
Molecular Formula: C6H6N2O2
Molecular Weight: 138.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May explode when
heated.
Conditions to Avoid:
High temperatures, incompatible materials, dust generation.
Incompatibilities with Other Materials:
Acids, nitric acid, sulfuric acid, acetylene, chloroformates, acid
chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 88-74-4: BY6650000
LD50/LC50:
CAS# 88-74-4: Inhalation, rat: LC50 = >2529 mg/m3/4H; Oral, mouse:
LD50 = 1070 mg/kg; Oral, rat: LD50 = 1600 mg/kg.
Carcinogenicity:
2-Nitroaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITROANILINES
Hazard Class: 6.1
UN Number: 1661
Packing Group: II
IMO
Shipping Name: NITROANILINES (O-, M-, P-)
Hazard Class: 6.1
UN Number: 1661
Packing Group: II
RID/ADR
Shipping Name: NITROANILINES
Hazard Class: 6.1
UN Number: 1661
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 88-74-4: 2
Canada
CAS# 88-74-4 is listed on Canada's DSL List.
CAS# 88-74-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-74-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/11/1998 Revision #4 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Trolox, 97%
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Poly(2,2-Dimethyl-1,3-Propylene Succinate) Approximate M.W. 16.000
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1-Benzyl-2-methylimidazole, 95%(gc)
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2-Phenyl-2-imidazoline, 98+%
| 936-49-2 |
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Pyridazine, 98+%
| 289-80-5 |
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Butyraldehyde, P.A. Contains Less Than 1% Butyric Acid
| 123-72-8 |
|
2,3-Dimethoxyphenol, 99%
| 5150-42-5 |
|
4-Octylbenzaldehyde, 99% (GC)
| 49763-66-8 |
|
4-Aminophenethyl alcohol, 97% (gc)
| 104-10-9 |
|
2,6-Dinitrotoluene, 99%
| 606-20-2 |
|
Methanethiol, 99.5+%
| 74-93-1 |
|
Benzanilide 98%
| 93-98-1 |
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2-Amino-6,8-Dihydroxypurine, Tech., ca.85% (HPLC)
| 5614-64-2 |
|
2-Dimethylaminoethyl Methacrylate, 99% (GC), Stabilized
| 150-76-5 |
|
Butyric Acid, Sodium Salt, 99%
| 156-54-7 |
|
N,n',n",n"'-tetraacetylglycoluril, 98+%
| 10543-60-9 |
|
2-Ethylhexyl Acetate, 99% (GC)
| 103-09-3 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Toluic Acid, 98%
| 433-97-6 |
|
Deuterium Oxide, 99.8 Atom % D
| 7789-20-0 |
|
Phenothiazine-10-carbonyl chloride 98%
| 18956-87-1 |
|
4-Chloro-2-Nitrotoluene, 99%
| 89-59-8 |
|
1,12-Dodecanedicarboxylic Acid, 98%
| 821-38-5 |
|
Lead(II) carbonate, basic, -325 mesh
| 1319-46-6 |
|
4'-Chloro-2'-Fluoroacetanilide , 99+%(TLC)
| 59280-70-5 |
|
2-Benzoylbenzoic acid, 98+%
| 85-52-9 |
|
d-(+)-Galactosamine Hydrochloride, 99%
| 1772-03-8 |
|
2-Benzylpyridine, 98%
| 101-82-6 |
|
Trypan Blue
| 72-57-1 |
|
Ethyl caprylate, 99+%
| 106-32-1 |
|
4-(Hydroxymercury)benzoic acid sodium salt
| 138-85-2 |
|
(2S,3S),(2S,3R)-2-Amino-3-Hydroxy-4-Methyl Pentanoic Acid, 99+% e.e.
| 0-01-1 |
|
Ethylenediamine-N,N'-diacetic acid, 98+%
| 5657-17-0 |
|
2-Acetoxy-3,3-dichlorotetrahydrofuran 98+%
| |
|
2-Nitroaniline, 98%
| 88-74-4 |
|
DL-Homatropine Hydrobromide, 98.5-100.5% (on Dry Subst.)
| 51-56-9 |
|
4-Methyl-3-nitroanisole, 99%
| 17484-36-5 |
|
Chromotrope 2b
| 548-80-1 |
|
3-Hydroxytyramine hydrobromide, 99%
| 51-61-6 |
|
1,4-Bis(2-Hydroxyethoxy)-2-Butyne
| 1606-85-5 |
|
Oxonic acid, potassium salt, 97.5%
| 2207-75-2 |
|
(-)-Chiracamphox
| 165038-32-4 |
|
Iminodiacetonitrile, 98%
| 628-87-5 |
|
Heptanoyl chloride, 99%(titr.)
| 2528-61-2 |
|
Azocarmine G (Cert)
| 25641-18-3 |
|
New Coccine
| 2611-82-7 |
|
(2-Fluorophenyl)(4-methoxy-3-nitrophenyl) methanone, 95%
| |
|
1-Chloropropane, 99%
| 540-54-5 |
|
2-Methylglutaric acid, 99%
| 18069-17-5 |
|
3,4,5-Trimethoxyaniline, 97%
| 24313-88-0 |
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5-Chloro-2-(trichloromethyl)benzimidazole , 95%
| 3584-66-5 |
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|