LILLY INDUSTIES INC -- 119-313 PHTHALO GREEN
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Material Safety Data Sheet
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MSDS Num: BXMMP
MSDS NAME: 119-313 PHTHALO GREEN
Responsible Party
Name: LILLY INDUSTIES INC
Address: 2601 EAST HENRY AVENUE
City: TAMPA FL 33610-5000
Info Phone: 813-236-5594
Emergency Phone Number: 813-236-5594
Preparer's Name: E F GODBEY
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Name: LILLY INDUSTIES INC
Address: 2601 EAST HENRY AVENUE
City: TAMPA FL 33610-5000
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Contractor Summary
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Name: LILLY INDUSTIES INC
Address: 2601 EAST HENRY AVENUE
City: TAMPA FL 33610-5000
Phone: 813-236-5594
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Ingredients
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Cas: 78-93-3
RTECS #: EL6475000
Name: 2-BUTANONE (METHYL ETHYL KETONE) (MEK)
% Wt: 7
Other REC Limits: 590 MG/CUM
OSHA PEL: 200 PPM
ACGIH TLV: 300 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 141-78-6
RTECS #: AH5425000
Name: ETHYL ACETATE
% Wt: 5
Other REC Limits: 400 PPM
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 108-65-6
RTECS #: AI8925000
Name: PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE, 1-METHOXY-2-PROPANOL ACETATE
% Wt: 13
Other REC Limits: NOT ESTABLISHED
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Cas: 100-41-4
RTECS #: DA0700000
Name: ETHYL BENZENE *95-2*
% Wt: 6
Other REC Limits: 100 PPM
OSHA PEL: 435 MG/CUM
ACGIH TLV: 434 MG/CUM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *95-2*
% Wt: 12
Other REC Limits: 100 PPM
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM, SKIN
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (IARC CARC- GROUP 3) *95-2*
% Wt: 14
Other REC Limits: 375 MG/CUM
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION: MAY CAUSE NAUSEA & RESPIRATORY IRRITATION,
CNS EFFECTS & POSSIBLE UNCONSCIOUSNESS LEADING TO POSSIBLE
ASPHYXIATION.SKIN: MODERATE IRRITATION, DEFATTING DERMATITIS. INGESTION: GI
IRRITATION . ASPIRATION OF MATERIAL INTO LUNGS CANCAUSE CHEMICAL PNEUMONIA
WHICH CAN BE FATAL. (SEE SUPP)
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, DIZZINESS, WEAKNESS, FATIGUE,
HEADACHE, UNCONSCIOUSNESS, REDDNESS, TEARING, BLURRED VISION, DEFATTING,
NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated By Exposure: PRE-EXISTING EYE, SKIN, LIVER, KIDNEY
& RESPIRATORY DISORDERS.
First Aid: EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: THOROUGHLY
WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED.
INGESTION: ASPIRATION HAZARD. DON'T INDUCE VOMITING. KEEP W ARM & QUIET.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
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Handling and Disposal
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Spill Release Procedures: STAY UPWIND & AWAY UNLESS WEARING APPROPRIATE
PROTECTIVE EQUIPMENT. STOP &/CONTAIN DISCHARGE SAFELY. KEEP FROM IGNITION
SOURCES. VENTILATE AREA. USE NON-SPARKING TOOLS FOR CLEAN UP.
Waste Disposal Methods: DON'T FLUSH TO SEWER, WATERSHED/WATERWAY. DISPOSE OF
IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE CLOSED
CONTAINERS. UN1263.
Handling And Storage Precautions: DON'T STORE >120F. STORE LARGE QUANTITIES
IN BUILDING DESIGNED TO COMPLY W/OSHA. KEEP AWAY FROM HEAT/SPARKS/FLAME. FOR
INDUSTRIAL USE ONLY.
Other Precautions: KEEP CONTAINERS CLOSED WHEN NOT IN USE & IN AN UPRIGHT
POSITION TO PREVENT LEAKAGE. CONTAINERS SHOULD BE GROUNDED WHEN POURING.
DON'T TAKE INTERNALLY. DON'T CUT/PUNCTURE/WELD ON/NEAR EMPTIED CONTAINER S.
KEEP OUT OF REACH OF CHILDREN.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point Text: 21F
Lower Limits: 1
Upper Limits: 13.1
Extinguishing Media: FOAM, CO2, DRY CHEMICAL, WATER FOG
Fire Fighting Procedures: WEAR FULL PROTECTIVE EQUIPMENT INCLUDING SCBA. WATER
SPRAY W/FOG NOZZLES IF PREFERABLE TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE IN EXTREME HEAT.
VAPORS ARE >THAN AIR & MAY TRAVEL ALONG FLOOR BEFORE IGNITION, FLASH
BACK TO VAPOR SOURCES. (SEE SUPP)
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Control Measures
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Respiratory Protection: NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED
IN ABSENCE OF PROPER ENVIROMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER
NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE).
Ventilation: MECHANICAL (GENERAL &/LOCAL EXHAUST) VENTILATION.
Protective Gloves: NITRILE RUBBER
Eye Protection: CHEMICAL SPLASH GOGGLES
Other Protective Equipment: IMPERVIOUS BOOTS & CLOTHING.
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH THOROUGHLY AFTER HANDLING, BEFORE EATING & SMOKING.
Supplemental Safety and Health: HEALTH HAZARDS CONT'D: REPORTS HAVE ASSOCIATED
REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & CNS
DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING
CONTENTS MAY BE H ARMFUL/FATAL & MAY CAUSE LIVER/KIDNEY DAMAGE. UNUSUAL
FIRE CONT'D: EMPTIED CONTAINERS MAY RETAIN HAZARDOUS RESIDUE.
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Physical/Chemical Properties
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B.P. Text: 172-279F
Vapor Density: >1
VOC Grams/Liter: 577
Evaporation Rate & Reference: SLOWER THAN ETHER
Solubility in Water: INSOLUBLE
Appearance and Odor: VISCOUS LIQUID W/SOLVENT ODOR
Percent Volatiles by Volume: 65.33
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HEAT, OPEN FLAMES, STATIC ELECTRICITY, ELECTRIC
EQUIPMENT, SPARKS, EXTREME HEAT.
Materials To Avoid: STRONG ACIDS, ALKALIES & OXIDIZERS.
Hazardous Decomposition Products: FUMES CONTAINING ORGANIC ACIDS, CO2, CO &
SMOKE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Other Information: VOLATILE ORGANIC CONTENT TOTAL: COATING/MATERIAL-577 G/L.
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HAZCOM Label
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MSDS NAME: 119-313 PHTHALO GREEN
Company: LILLY INDUSTIES INC
Street: 2601 EAST HENRY AVENUE
City: TAMPA FL
Zipcode: 33610-5000
Health Emergency Phone: 813-236-5594
Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
Label Date: 12/16/1998
Origination Code: G
Hazard And Precautions: INHALATION: MAY CAUSE NAUSEA & RESPIRATORY
IRRITATION, CNS EFFECTS & POSSIBLE UNCONSCIOUSNESS LEADING TO POSSIBLE
ASPHYXIATION.SKIN: MODERATE IRRITATION, DEFATTING DERMATITIS. INGESTION: GI
IRRITATION . ASPIRATION OF MATERIAL INTO LUNGS CANCAUSE CHEMICAL PNEUMONIA
WHICH CAN BE FATAL. (SEE SUPP) IRRITATION, DIZZINESS,
WEAKNESS, FATIGUE, HEADACHE, UNCONSCIOUSNESS, REDDNESS, TE ARING, BLURRED
VISION, DEFATTING, NAUSEA, VOMITING, DIARRHEA.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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