LIBERTY CHEMICAL CO -- FORMALDEHYDE SOLUTION, INHIBITED
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Material Safety Data Sheet
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NIIN: 00-291-8392
MSDS Num: BNRFL
MSDS NAME: FORMALDEHYDE SOLUTION, INHIBITED
Responsible Party
Name: LIBERTY CHEMICAL CO
Address: 317 ST PAULS AVE
City: JERSEY CITY NJ 07306-5021
Info Phone: COMPANY OUT OF BUSINESS
Emergency Phone Number: COMPANY OUT OF BUSINESS
Preparer's Name: DGSC-SSH
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LIBERTY CHEMICAL CO
Address: 317 ST PAULS AVE
City: JERSEY CITY NJ 07306-5021
Phone: COMPANY OUT OF BUSINESS
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Item Description Information
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Item Manager: S9G
Item Name: FORMALDEHYDE SOLUTION,ACS
Specification Number: O-C-265B
Type/Grade/Class: ACS
Unit of Issue: DR
Quantitative Expression: 00000000055GL
UI Container Qty: 1
Type of Container: DRUM
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Ingredients
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Cas: 50-00-0
RTECS #: LP8925000
Name: FORMALDEHYDE (SARA III)
% Wt: 37-44%
Other REC Limits: NOT ESTABLISHED
OSHA PEL: SEE 1910.1048
ACGIH TLV: C 0.3 PPM; A2; 9293
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 67-56-1
RTECS #: PC1400000
Name: METHYL ALCOHOL (METHANOL) (SARA III)
% Wt: 5-15%
Other REC Limits: NOT ESTABLISHED
OSHA PEL: S,200PPM/250STEL
ACGIH TLV: S,200PPM/250STEL; 93
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: ORAL RAT LD50 = 800 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INHALATION: MAY CAUSE TISSUE DAMAGE AND SERIOUS
RESPIRATORY TRACT INJURY. SKIN: MAY CAUSE BURNS. EYES: MAY CAUSE PROFUSE
LACRIMATION AND OCULAR DAMAGE. INGESTION: MAY CAUSE BURNING IN THE MOUTH AND
ESOPHAGUS. MAY CAUSE LIVER AND KIDNEY DAMAGE. MAY CAUSE DEATH FROM
CIRCULATORY FAILURE. CHRONIC: SKIN DERMATITIS.
Explanation Of Carcinogenicity: LISTED BY NTP AND IARC AS A CARCINOGEN.
Signs And Symptions Of Overexposure: INHALATION: MAY CAUSE EYE, NOSE &
THROAT IRRITATION. MAY CAUSE DIFFICULTY IN BREATHING, BURNING OF THE NOSE
& THROAT; OR EVEN PULMONARY EDEMA AND PNEUMONITIS. SKIN & EYES:
IRRITATION, SENSITIZATION DE RMATITIS, LOSS OF VISION. INGESTION: JAUNDICE,
ALBUMINURIA, HEMATURIA, ANURIA AND ACIDOSIS. MAY CAUSE DEATH.
Medical Cond Aggravated By Exposure: PERSONS WITH A HISTORY OF SKIN OR EYE
DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. PERSONS WITH LIVER, KIDNEY
AND RESPIRATORY DISORDERS MAY ALSO BE AT INCREASED RISK.
First Aid: INHALATION: REMOVE TO FRESH AIR IMMEDIATELY. IF BREATHING HAS
STOPPED, GIVE CPR. GET IMMEDIATE MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED
CLOTHING & SHOES. WASH AFFECTED AREA WITH SOAP & WATER. GET MEDICAL
ATTENTION. EYE: WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: INDUCE VOMITING. GET
IMMEDIATE MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL. APPLY
UNIVERSAL GELLING AGENT TO IMMOBILIZE SPILL AS REQUIRED. VENTILATE AND
EVACUATE AREA. ELIMINATE ALL SOURCES OF IGNITION. NEUTRALIZE & WASH
RESIDUE WITH WATER. PLACE INTO DISPOSAL CONTAINER.
Neutralizing Agent: CEMENT POWDER OR FLY ASH
Waste Disposal Methods: DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS. INCINERATION RECOMMENDED.
Handling And Storage Precautions: STORE IN A COOL, DRY, WELL VENTILATED AREA
AWAY FROM IGNITION SOURCES. KEEP CONTAINER CLOSED WHEN NOT IN USE. PROTECT
AGAINST PHYSICAL DAMAGE.
Other Precautions: MAY BE IGNITED BY HEAT, SPARKS OR FLAMES. CONTAINER MAY
EXPLODE IN HEAT OF FIRE. VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS OR IN
SEWERS. RUN-OFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >140F,>60C
Lower Limits: 7
Upper Limits: 73
Extinguishing Media: USE CARBON DIOXIDE, ALCOHOL FOAM, DRY CHEMICAL. DO NOT USE
WATER TO FIGHT FIRE.
Fire Fighting Procedures: FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO
COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard: EXTINGUISH ALL NEARBY SOURCES OF IGNITION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: SELECT NIOSH/MSHA APPROVED RESPIRATOR BASED ON
CONTAMINATION LEVELS FOUND IN THE WORK PLACE USING NIOSH POCKET GUIDE TO
CHEMICAL HAZARDS. SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED FOR MOST
CAS ES.
Ventilation: PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET THE
PUBLISHED EXPOSURE LIMITS. USE EXPLOSION-PROOF EQUIP.
Protective Gloves: BUTYL OR NITRILE RUBBER.
Eye Protection: SPLASH PROOF SAFETY GOGGLES/FACESHIELD.
Other Protective Equipment: PROTECTIVE CLOTHING AND EQUIPMENT TO PREVENT ANY
POSSIBLITY OF SKIN CONTACT. EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices: WASH THOROUGHLY AFTER USE AND BEFORE EATING OR
SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: THIS MATERIAL CONTAINS METHANOL WHICH MAY CAUSE
BLINDNESS AND/OR DEATH IF INGESTED.
=======================================================
Physical/Chemical Properties
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HCC: V4
B.P. Text: >207F,>97C
M.P/F.P Text: UNKNOWN
Decomp Text: UNKNOWN
Vapor Pres: 1
Vapor Density: 1.03
Spec Gravity: 1.08-1.10
Viscosity: UNKNOWN
Evaporation Rate & Reference: >1 (BUTYL ACETATE=1)
Solubility in Water: 100
Appearance and Odor: CLEAR, COLORLESS LIQUID; PUNGENT ODOR
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES,
TEMPERATURES BELOW 68 DEG. FAHRENHEIT.
Materials To Avoid: ACIDS, ALKALIS, ANHYDRIDES, ISOCYANATES, UREA, PHENOL,
OXIDIZING MATERIALS, AND OXIDES.
Hazardous Decomposition Products: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
UNBURNED FORMALDEHYDE, UNBURNED METHYL ALCOHOL, AND OXIDES OF CARBON.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: MAY UNDERGO A NON-HAZARDOUS SELF-
POLYMERIZATION TO FORM PARAFORMALDEHYDE WHICH PRECIPITATES OUT OF SOLUTION
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 68021
MSDS NAME: FORMALDEHYDE SOLUTION, INHIBITED
MSDS Prepared Date: 09/04/1992
Review Date: 09/04/1992
Net Unit Weight: 491 LBS.
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 1
Type Of Container: DRUM
Additional Data: NONE
=======================================================
Detail DOT Information
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DOT PSN Code: GNF
DOT Proper Shipping Name: FORMALDEHYDE, SOLUTIONS
DOT PSN Modifier: WITH NOT LESS THAN 25 PERCENT FORMALDEHYDE
Hazard Class: 8
UN ID Num: UN2209
DOT Packaging Group: III
Label: CORROSIVE
Special Provision: T1
Packaging Exception: 154
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: HLZ
IMO Proper Shipping Name: FORMALDEHYDE SOLUTION,
IMO PSN Modifier: WITH NOT LESS THAN 25% FORMALDEHYDE
IMDG Page Number: 8176-1
UN Number: 2209
UN Hazard Class: 8
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 8-07
MED First Aid Guide NUM: 300
=======================================================
Detail IATA Information
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IATA PSN KH
IATA UN ID Num: 2209
IATA Proper Shipping Name: FORMALDEHYDE SOLUTION
IATA PSN Modifier: WITH NOT LESS THAN 25% FORMALDEHYDE
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: III
Packing Note Passenger: 818
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 820
=======================================================
Detail AFI Information
=======================================================
AFI PSN KH
AFI Proper Shipping Name: FORMALDEHYDE, SOLUTIONS
AFI PSN Modifier: ,WITH NOT LESS THEN 25% FORMALDEHYDE
AFI Hazard Class: 8
AFI UN ID NUM: UN2209
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A12.3
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: FORMALDEHYDE SOLUTION, INHIBITED
Company: LIBERTY CHEMICAL CO
Street: 317 ST PAULS AVE
City: JERSEY CITY NJ
Zipcode: 07306-5021
Health Emergency Phone: COMPANY OUT OF BUSINESS
Label Required IND: Y
Date Of Label Review: 09/04/1992
Status Code: C
Label Date: 09/04/1992
Year Procured: 1983
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: IF INHALED, MAY BE HARMFUL; CONTACT MAY CAUSE BURNS TO
SKIN AND EYES. FIRE MAY PRODUCE IRRITATING OR POISONOUS GASES. RUNOFF FROM
FIRE CONTROL OR DILUTION WATER MAY CAUSE POLLUTION. ACUTE: INHALATION: MAY
CAUSE TISSUE DAMAGE AND SERIOUS RESPIRATORY TRACT INJURY. SKIN: MAY CAUSE
BURNS. EYES: MAY CAUSE PROFUSE LACRIMATION AND OCULAR DAMAGE. INGESTION: MAY
CAUSE BURNING IN THE MOUTH AND ESOPHAGUS. MA Y CAUSE LIVER AND KIDNEY DAMAGE.
MAY CAUSE DEATH FROM CIRCULATORY FAILURE. CHRONIC: SKIN DERMATITIS. STORE IN
A COOL, DRY, WELL VENTILATED AREA AWAY FROM IGNITION SOURCES. KEEP CONTAINER
CLOSED WHEN N OT IN USE. PROTECT AGAINST PHYSICAL DAMAGE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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