| MSDS | : | SCOTCHCAL BRAND TRANSLUCENT FILM SERIES 363 | | CAS | : | 71-43-2
78-93-3
108-90-7
4461-41-0
71-36-3
1330-20-7
7758-97-6
108-88-3 | | NAME | : | ing 19:deterioration, abnorm sperm morphology & fetal efts. symp of
ing 20:vomit, abdom spasms, weak, anemia, lead-line on gums & coma.
ing 21:normal conditions of usage. note:toluene cas#108-88-3 appears on
ing 22:seek consultation from approp hlth professionals concern latest
benzene (sara iii)
2-butanone; (methyl ethyl ketone)
benzene, chloro-; (chlorobenzene) (sara iii)
2-butene, 2-chloro-; (2-chloro-2-butene)
butyl alcohol; (1-butanol)
xylene (sara iii)
supdat:&/or rptd overexp occurs.lead chromate is considered substance
ing 11:lead cmpds are also addressed by osha std.iarc states that there
ing 12:exptl studies in lab animals exposed to lead chromate. iarc rpts
ing 13:carcin in men occup exposed during chromate production, but
ing 14:occups & for cancer @ other sites to allow for evaluation of
ing 15:mists may cause blood & peripheral nerve dmg. chronic expos to
ing 16:inhal expos to lead chromate is likely to occur only in
ing 17:occur when thermoforming. symps same as ingest. ingest:may cause
ing 18:cummulative poison. lead causes peripheral nerve dmg, kidney,
pigmented plasticized polyvinyl chloride film (pigment may contain
chromic acid, lead (2+) salt (1:1); (lead chromate)
acrylic adhesive (consisting of ients 4 thru 10).
toluene (sara iii)
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3M GENERAL OFFICES -- SCOTCHCAL BRAND TRANSLUCENT FILM SERIES 363
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BNQPG
MSDS NAME: SCOTCHCAL BRAND TRANSLUCENT FILM SERIES 363
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
=======================================================
Ingredients
=======================================================
Name: ING 19:DETERIORATION, ABNORM SPERM MORPHOLOGY & FETAL EFTS. SYMP OF
LEAD ACCUM IN BODY MAY INCL HDCH, NAUS,
-----------------------------
Name: ING 20:VOMIT, ABDOM SPASMS, WEAK, ANEMIA, LEAD-LINE ON GUMS & COMA.
INGEST IS NOT EXPECTED RTE OF EXPOS UNDER
-----------------------------
Name: ING 21:NORMAL CONDITIONS OF USAGE. NOTE:TOLUENE CAS#108-88-3 APPEARS ON
THE NAVY LISTING OF OCCUP REPRO HAZ.
-----------------------------
Name: ING 22:SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERN LATEST
HAZ LIST INFO & SAFE HNDL & EXPOS RECOMND(FP N).
Other REC Limits: NONE SPECIFIED
-----------------------------
Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE (SARA III)
Other REC Limits: 25 PPM, C
OSHA PEL: 1 PPM;5 PPM STEL
ACGIH TLV: 10 PPM
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 78-93-3
RTECS #: EL6475000
Name: 2-BUTANONE; (METHYL ETHYL KETONE)
OSHA PEL: 200 PPM;300 PPM STEL
ACGIH TLV: 200 PPM;300 PPM STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 108-90-7
RTECS #: CZ0175000
Name: BENZENE, CHLORO-; (CHLOROBENZENE) (SARA III)
OSHA PEL: 75 PPM
ACGIH TLV: 10 PPM
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 4461-41-0
RTECS #: EM4265000
Name: 2-BUTENE, 2-CHLORO-; (2-CHLORO-2-BUTENE)
------------------------------
Cas: 71-36-3
RTECS #: EO1400000
Name: BUTYL ALCOHOL; (1-BUTANOL)
OSHA PEL: 100 PPM
ACGIH TLV: S, C 50 PPM; 9293
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA III)
OSHA PEL: 100 PPM;150 PPM STEL
ACGIH TLV: 100 PPM;150 PPM STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Name: SUPDAT:&/OR RPTD OVEREXP OCCURS.LEAD CHROMATE IS CONSIDERED SUBSTANCE
SUSPECT OF CARCIN POTNTL FOR MEN BY ACGIH.
-----------------------------
Name: ING 11:LEAD CMPDS ARE ALSO ADDRESSED BY OSHA STD.IARC STATES THAT THERE
IS SUFFICIENT EVID OF CARCIN PROVIDED BY
-----------------------------
Name: ING 12:EXPTL STUDIES IN LAB ANIMALS EXPOSED TO LEAD CHROMATE. IARC RPTS
THAT THERE IS SUFFICIENT EVID OF RESP
-----------------------------
Name: ING 13:CARCIN IN MEN OCCUP EXPOSED DURING CHROMATE PRODUCTION, BUT
INSUFFICIENT DATA ON LUNG CANCER IN OTHER
-----------------------------
Name: ING 14:OCCUPS & FOR CANCER @ OTHER SITES TO ALLOW FOR EVALUATION OF
POTNTL RISK OF CANCER IN HUMANS. EXPOS TO
-----------------------------
Name: ING 15:MISTS MAY CAUSE BLOOD & PERIPHERAL NERVE DMG. CHRONIC EXPOS TO
LEAD MAY ALSO CAUSE PERIPHERAL NERVE DMG.
-----------------------------
Name: ING 16:INHAL EXPOS TO LEAD CHROMATE IS LIKELY TO OCCUR ONLY IN
AEROSOL/MIST FORM & WOULD NOT BE EXPECTED TO
-----------------------------
Name: ING 17:OCCUR WHEN THERMOFORMING. SYMPS SAME AS INGEST. INGEST:MAY CAUSE
DIGEST SYS IRRIT. LEAD IF INGESTED IS
-----------------------------
Name: ING 18:CUMMULATIVE POISON. LEAD CAUSES PERIPHERAL NERVE DMG, KIDNEY,
LIVER & BLOOD DMG, ENCEPHALOPATHY, MENTAL
-----------------------------
Name: PIGMENTED PLASTICIZED POLYVINYL CHLORIDE FILM (PIGMENT MAY CONTAIN
INGREDIENT 2)
% Wt: 70-90
-----------------------------
Cas: 7758-97-6
RTECS #: GB2975000
Name: CHROMIC ACID, LEAD (2+) SALT (1:1); (LEAD CHROMATE)
Other REC Limits: 0.012 MG/M3 (CR)
OSHA PEL: 0.1 PPM (CRO*3)
ACGIH TLV: 0.05 MG/M3 (PB)
------------------------------
Name: ACRYLIC ADHESIVE (CONSISTING OF INGREDIENTS 4 THRU 10).
% Wt: 10-30
-----------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA III)
OSHA PEL: 200 PPM/150 STEL
ACGIH TLV: 50 PPM; 9293
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: EYE:VAPS FROM THERMOFORMING MAY CAUSE IRRIT. SKIN:BURNS
MAY RESULT FROM CONT W/HOT/MOLTEN PROD. INHAL:DURING THERMOFORMING, VAPS WILL
CAUSE IRRIT & IN HIGH CONCS ARE TOX. HAZ DECOMP BY-PRODS MAY CAUSE
DIZZ/SUFFOCATION. CHRONIC OVEREXP TO CO2 MAY CAUSE SIGNIFICANT PHYSIOLOGICAL
EFTS, DETERIORATION OF (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: LEAD CHROMATE:IARC 1, NTP 1, ACGIH A2.
BENZENE:IARC 1, NTP 1, ACGIH A2, OSHA REG.
Signs And Symptions Of Overexposure: HLTH HAZ:OF PERFORMANCE/DEATH. MAY CAUSE
DMG TO LUNG, LIVER, KIDNEY, HEART & STRIATED MUSCLE & CAUSE CHANGES
IN BLOOD & URINE COMPOSITION. TRACE QTYS OF ALIPHATIC & AROMATIC
HYDROCARBONS HAVE BEEN IDE NTIFIED AS BEING RELS DURING HEATING. EXAMPLES OF
THESE HYDROCARBONS ARE TOLUENE, BENZENE, XYLENE, 1-BUTANOL & (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE:IMMED FLUSH W/PLENTY OF WATER & CONTINUE FOR @ LST 15
MINUTES HOLDING EYELIDS OPEN. CALL MD. SKIN:WASH W/SOAP & WATER. FOR
BURNS, CONTACT MD IMMED. INHAL:REMOVE PERSON TO FRESH AIR. IF BRTHG IS DF
CLT, ADMIN O2. IF BRTHG HAS STOPPED, GIVE ARTF RESP. KEEP PERSON WARM &
QUIET. CALL MD. INGEST:DO NOT INDUCE VOMITING. GIVE 1 TO 2 GLASSES OF WATER.
CALL MD.
=======================================================
Handling and Disposal
=======================================================
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATION IN PERMITTED HAZARDOUS WASTE FACILITY
CAPABLE OF MEETING APPLICABLE REGULATORY REQUIREMENTS FOR DESTRUCTION &
REMOVAL IS PREFERRED. OTHERWISE, DISPOSE OF I/A/W APPLIC FEDERAL, STATE &
LOC AL REGULATIONS.
Handling And Storage Precautions: DURING THERMOFORMING, AVOID PROLONGED
EXPOSURE TO ELEVATED CONCENTRATIONS OF VAPORS. DO NOT EXCEED TEMPERATURE OF
390F.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: CO2, FOAM, DRY CHEMICALS OR WATER.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR NIOSH/MSHA APPRVD ORG VAP RESP (OR EQUIV) FOR SUPP
PROT IF ADEQUATE LOCAL & GENERAL VENT CANNOT BE MAINTAINED. IF EXPOS
LEVELS ARE UNKNOWN CONTACT CERTIFIED INDUS HYGIENIST FOR AIR MONITORING TO
BE PERFORMED & VENT TO BE REVIEWED.
Ventilation: LOCAL VENTILATION SHOULD BE EMPLOYED AS NEEDED TO MAINTAIN VAPOR
LEVELS W/IN ESTABLISHED TLV.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MFR'S TRADE NAME/PART NO:(THERMOFORMED). EFTS
OF OVEREXP:2-BUTANONE. CHLORINATED HYDROCARBONS MAY ALSO BE RELS DURING
HEATING & COULD INCL CHLOROBENZENE & 2-CHLORO-2-BUTENE. BENZENE IS
POTNTL CANCER H AZ. THESE CHEMS MAY ALSO CAUSE NERV SYSEFTS, IMMUNE SYS EFTS,
ADRENAL EFTS, REPRO EFTS & LUNG DMG WHEN PRLNG
=======================================================
Physical/Chemical Properties
=======================================================
HCC: N1
Solubility in Water: NIL
Appearance and Odor: COLORED, ADHESIVE COATED FILM.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE KNOWN
Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY PRODUCE CO, CO2 &
HCL GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 34997
MSDS NAME: SCOTCHCAL BRAND TRANSLUCENT FILM SERIES 363
MSDS Prepared Date: 02/21/1991
Review Date: 09/09/1992
Multiple KIT Number: 0
Review IND: Y
Additional Data: NOT REGULATED FOR TRANSPORTATION
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SCOTCHCAL BRAND TRANSLUCENT FILM SERIES 363
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 04/29/1992
Status Code: C
Label Date: 04/29/1992
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: THERMAL DECOMP PRODS ARE HAZ. ACUTE:VAP FROM
THERMOFORMING MAY CAUSE EYE IRRIT. BURNS MAY RESULT FROM CONT W/HOT/MOLTEN
PROD. HIGH VAP CONC ARE TOXIC. DMG TO LUNG, LIVER, KIDNEY, HEART, STRIATED
MUSCL E & CAUSE CHANGES IN BLOOD & URINE. MAYALSO CAUSE NERV SYS,
IMMUNE SYS, ADRENAL & REPRO EFTS, LUNG DMG, DETERIORATION OF PERFORMANCE,
DEATH. CHRONIC:PERIPHERAL NERVE DMG, LEAD POISONING:BLOOD/KIDNEY/L IVER DMG,
ENCEPHALOPATHY, ABNORMAL SPERM, MENTAL DETERIORATION, FETAL EFTS, HDCH, NAUS,
VOMIT, WEAK, ANEMIA, LEAD LINE ON GUMS, COMA. CONTAINS LEAD & BENZENE
WHICH MAY CAUSE CANCER.TOLUENE IS CONSIDER ED BY THE NAVY TO AN OCCUP REPRO
HAZ.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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