carbon dioxide supdat:twa. co*2 vapors are approximately one and one-half times heavier
LIQUID CARBONIC INDUSTRIES -- CARBON DIOXIDE, SOLID
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Material Safety Data Sheet
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NIIN: 01-165-6174
MSDS Num: BYTBS
MSDS NAME: CARBON DIOXIDE, SOLID
Responsible Party
Name: LIQUID CARBONIC INDUSTRIES
Address: 810 JORIE BLVD
City: OAK BROOK IL 60621-2216
Info Phone: 708-572-7500
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
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Contractor Summary
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Name: LIQUID CARBONIC INDUSTRIES CORP
Address: 810 JORIE BLVD
City: HINSDALE IL 60521-2216
Phone: 708-572-7000
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Item Description Information
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Item Manager: S9G
Item Name: CARBON DIOXIDE,TECHNICAL
Unit of Issue: EA
UI Container Qty: 0
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Ingredients
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Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE
% Wt: 99+
OSHA PEL: 5000 PPM
ACGIH TLV: 5000 PPM/30000 STEL
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Name: SUPDAT:TWA. CO*2 VAPORS ARE APPROXIMATELY ONE AND ONE-HALF TIMES HEAVIER
THAN AIR.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHAL:AT 2-3% CONC SYMPS OF SIMPLE ASPHXYIA OCCUR,
3-5% CAUSES INCREASED RESPIRATION & HEADACHE; UP TO 15% CAUSES HEADACHE,
NAUSEA, VOMITING & UNCONSCIOUSNESS. HIGHER CONCENTRATIONS CAUSE RAPID
CIRCULATORY INSUFFICIENCY LEADING TO COMA & DEATH. CO*2 IS THE MOST
POWERFUL CEREBRAL VASODILATOR (EFFECTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:KNOWN. SKIN:CONTINUOUS DERMAL
CONT W/SOLID CO*2 COULD CAUSE FROSTBITE OR CRYOGENIC "BURNS". PERSONS IN ILL
HEALTH WHERE SUCH ILLNESS WOULD BE AGGRAVATED BY EXPOSURE TO SOLID CARBON
DIOXIDE SH OULD NOT BE ALLOWED TO WORK WITH OR HANDLE THIS PRODUCT.
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOS TO SOLID CARBON DIOXIDE SHOULD NOT BE ALLOWED TO
WORK WITH OR HANDLE THIS PRODUCT.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). EYES:IMMEDIATELY FLUSH W/POTABLE
WATER FOR MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD (FP N).
INHAL:CONSCIOUS PERSONS SHOULD BE ASSISTED TO UNCONTAMD AREA & INHA LE
FRESH AIR. IF UNCON, PROVIDE ASSISTED RESPIRATION & SUPPLEMENTAL OXYG.
FURTHER TREATMENT SHOULD BE SYMPTOMATIC & SUPPORTIVE. NIOSH/MSHA APPRVD
SCBA SHOULD BE AVAIL FOR RESCUE PERS. (SUPDAT)
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Handling and Disposal
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Spill Release Procedures: BE CERTAIN THERE IS ADEQ VENT. PLACE OUTSIDE IN
PROTECTED AREA W/GOOD VENT & ALLOW TO SUBLIME. AVOID PRLNGD CONTACT WITH
SKIN.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: SEE SPILL RELEASE PROCEDURES. DISPOSAL MUST BE I/A/W
FEDERAL, STATE & LOCAL REGULATIONS (FP N).
Handling And Storage Precautions: SOLID CO*2 IS GENERALLY DELIVERED TO
CUSTOMERS IN DRAFT-PAPER-WRAPPED BLOCKS WHICH WEIGH APPROX. 50 POUNDS ONE
HALF CUBIC FOOT IN VOLUME.
Other Precautions: PRODS SHOULD BE STORED IN INSULATED CNTNRS WHICH OPEN FROM
TOP HAVING LOOSE-FITTING LIDS SO THAT CO*2 VAP FROM SUBLIMATION OF SOLID MAY
BE ALLOWED TO ESCAPE INTO ATM. INSULATED STOR CNTNR SHOULD BE LO CATED IN
AREA WHERE THERE IS (SUPDAT)
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Fire and Explosion Hazard Information
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Extinguishing Media: NONFLAMMABLE SOLID. MEDIA SUITABLE FOR SURROUNDING FIRE
(FP N).
Fire Fighting Procedures: NONFLAMMABLE SOLID. USE NIOSH/MSHA APPROVED SCBA
& FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONFLAMMABLE SOLID.
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Control Measures
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Respiratory Protection: NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS
SHOULD BE AVAILABLE FOR EMERGENCY USE.
Ventilation: LOCAL EXHAUST:TO PVNT ACCUM ABOVE TWA. MECHANICAL (GENERAL):STEL
OR PEL.
Protective Gloves: LOOSE FITTING, INSULATED GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: SAFETY SHOES, PORTABLE CO*2 ANALYZER. ANSI APPRVD
EMERGENCY EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MATLS TO AVOID:MAGNESIUM) & THEIR HYDRIDES.
FIRST AID PROC:SKIN (FROSTBITE):FLUSH AFFECTED AREAS W/LUKEWARM WATER. DO NOT
USE HOT WATER. PHYS SHOULD SEE PATIENT PROMPTLY IF CRYOGENIC "BURN" HAS RSLTD
IN BLISTERING OF DERMAL SURF/DEEP TISS FREEZING. OTHER PREC:ADEQ VENT SO AS
TO PVNT ACCUM OF CO*2 VAPS ABOVE
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Physical/Chemical Properties
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Vapor Density: 1.65 @ 70F
Solubility in Water: VAPOR IS SOLUBLE
Appearance and Odor: WHITE, OPAQUE SOLID EMITTING COLORLESS GAS WITH SLIGHT,
PUNGENT ODOR.
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: REACTS W/ALKALINE MATLS TO FORM CARBONATES & BICARBONATES.
CAN BE EXPLO W/REACTIVE METALS (SODIUM, POTASSIUM, (SUPDAT)
Hazardous Decomposition Products: CARBON MONOXIDE AT HIGH TEMPERATURES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 112466
MSDS NAME: CARBON DIOXIDE, SOLID
MSDS Prepared Date: 04/01/1994
Review Date: 05/14/1996
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: EA
Container QTY: 0
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Detail DOT Information
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DOT PSN Code: CVO
Symbols: AW
DOT Proper Shipping Name: CARBON DIOXIDE, SOLID OR DRY ICE
Hazard Class: 9
UN ID Num: UN1845
DOT Packaging Group: III
Label: NONE
Special Provision: B12
Non Bulk Pack: 217
Bulk Pack: 240
Max Qty Pass: 200 KG
Max Qty Cargo: 200 KG
Vessel Stow Req: C
Water/Ship/Other Req: 40
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Detail IMO Information
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IMO PSN Code: DOF
IMO Proper Shipping Name: CARBON DIOXIDE, SOLID
IMDG Page Number: 9025
UN Number: 1845
UN Hazard Class: 9
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 8-08
MED First Aid Guide NUM: 615
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Detail IATA Information
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IATA PSN Code: FHR
IATA UN ID Num: 1845
IATA Proper Shipping Name: CARBON DIOXIDE, SOLID +
IATA UN Class: 9
IATA Label: MISCELLANEOUS
UN Packing Group: III
Packing Note Passenger: 904
Max Quant Pass: 200KG
Max Quant Cargo: 200KG
Packaging Note Cargo: 904
Exceptions: A48
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Detail AFI Information
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AFI PSN Code: FHR
AFI Proper Shipping Name: CARBON DIOXIDE, SOLID OR DRY ICE
AFI Hazard Class: 9
AFI UN ID NUM: UN1845
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A13.9
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HAZCOM Label
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MSDS NAME: CARBON DIOXIDE, SOLID
Company: LIQUID CARBONIC INDUSTRIES CORP
Street: 810 JORIE BLVD
City: HINSDALE IL
Zipcode: 60521-2216
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 06/23/1995
Status Code: C
Label Date: 06/23/1995
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHAL:AT 2-3% CONC SYMPS OF SIMPLE ASPHXYIA
OCCUR, 3-5% CAUSES INCREASED RESPIRATION & HEADACHE; UP TO 15% CAUSES
HEADACHE, NAUSEA, VOMITING & UNCONSCIOUSNESS. HIGHER CONCENTRATIONS CAUSE
RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA & DEATH. CO*2 IS THE
MOST POWERFUL CEREBRAL VASODILATOR KNOWN. SKIN:CONTINUOUS DERMAL CONT W/SOLID
CO*2 COULD CAUSE FROSTBITE/CRYOGENIC "BURNS". CHRONIC:NONE SPECIFIED BY
MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.