acrylic acid, 2-cyano-, methyl ester; (methyl 2-cyanoacrylate) polymethylmethacrylate; (poly (methyl methacrylate)) hydroquinone (sara 302/313) (cercla) volatile organic compound: 92.6% (epa method 24) supdat: will open w/out further action, typically in 1-4 days. there will ing 5: eyes by manipulation. adhesive on eyeball: cyanoacrylate ing 6: protein & will disassoc from it over intermittent periods ing 7: periods of weeping until clearance is achieved. during period of ing 8: together w/lacrim eft, & it is important to understand cause ing 9: even w/gross contam. mouth: if lips stuck together, apply lots of ing 10: wetting & pressure from saliva inside mouth. peel/roll lips ing 11: opposing action. it is almost imposs to swallow cyanoacrylate. ing 12:saliva will lift adhesive in 1/2 to 2 days. in case lump forms in ing 13: of lump when it detaches. burns: cyanoacrylates give off heat on ing 14: will incr in temp enough to cause burn. burns should be treated ing 15: relsd from tiss as described above. surgery: it should never be ing 16: separate accidentally bonded skin.
LOCTITE CORP -- SUPERBONDER 496 INSTANT ADHESIVE, 49661
=======================================================
Material Safety Data Sheet
=======================================================
NIIN: 01-043-7537
MSDS Num: BYTBG
MSDS NAME: SUPERBONDER 496 INSTANT ADHESIVE, 49661
Responsible Party
Name: LOCTITE CORP
Address: 705 N MOUNTAIN RD
City: NEWINGTON CT 06111
Info Phone: 203-278-1280
Emergency Phone Number: 203-278-1280
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORP
Address: 705 N MT RD
City: NEWINGTON CT 06111
Phone: 312-689-6200
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Item Description Information
=======================================================
Item Manager: GSA
Item Name: ADHESIVE
Unit of Issue: LB
UI Container Qty: 0
=======================================================
Ingredients
=======================================================
Cas: 137-05-3
RTECS #: AS7000000
Name: ACRYLIC ACID, 2-CYANO-, METHYL ESTER; (METHYL 2-CYANOACRYLATE)
% Wt: 90-95
OSHA PEL: 2 PPM
ACGIH TLV: 2 PPM; 4 STEL
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY (METHYL METHACRYLATE))
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA 302/313) (CERCLA)
% Wt: 0.1-0.5
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: 92.6% (EPA METHOD 24)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: WILL OPEN W/OUT FURTHER ACTION, TYPICALLY IN 1-4 DAYS. THERE WILL
BE NO RESIDUAL DMG. DO NOT TRY TO OPEN
-----------------------------
Name: ING 5: EYES BY MANIPULATION. ADHESIVE ON EYEBALL: CYANOACRYLATE
INTRODUCED INTO EYES WILL ATTACH ITSELF TO EYE
-----------------------------
Name: ING 6: PROTEIN & WILL DISASSOC FROM IT OVER INTERMITTENT PERIODS
GENERALLY COVERING SEVERAL HRS. THIS CAUSES
-----------------------------
Name: ING 7: PERIODS OF WEEPING UNTIL CLEARANCE IS ACHIEVED. DURING PERIOD OF
CONTAM, DOUBLE VISION MAY BE EXPERIENCED
-----------------------------
Name: ING 8: TOGETHER W/LACRIM EFT, & IT IS IMPORTANT TO UNDERSTAND CAUSE
& REALIZE DISASSOC WILL NORM OCCUR W/IN HRS
-----------------------------
Name: ING 9: EVEN W/GROSS CONTAM. MOUTH: IF LIPS STUCK TOGETHER, APPLY LOTS OF
WARM WATER TO LIPS & ENCOURAGE MAXIMUM
-----------------------------
Name: ING 10: WETTING & PRESSURE FROM SALIVA INSIDE MOUTH. PEEL/ROLL LIPS
APART. DO NOT TRY TO PULL LIPS W/DIRECT
-----------------------------
Name: ING 11: OPPOSING ACTION. IT IS ALMOST IMPOSS TO SWALLOW CYANOACRYLATE.
ADHESIVE SOLIDIFIES & ADHERES IN MOUTH.
-----------------------------
Name: ING 12:SALIVA WILL LIFT ADHESIVE IN 1/2 TO 2 DAYS. IN CASE LUMP FORMS IN
MOUTH, POSITION PATIENT TO PVNT INGEST
-----------------------------
Name: ING 13: OF LUMP WHEN IT DETACHES. BURNS: CYANOACRYLATES GIVE OFF HEAT ON
SOLIDIFICATION. IN RARE CASES LG DROP
-----------------------------
Name: ING 14: WILL INCR IN TEMP ENOUGH TO CAUSE BURN. BURNS SHOULD BE TREATED
NORMALLY AFTER LUMP OF CYANOACRYLATE IS
-----------------------------
Name: ING 15: RELSD FROM TISS AS DESCRIBED ABOVE. SURGERY: IT SHOULD NEVER BE
NECESSARY TO USE SUCH A DRASTIC METH TO
-----------------------------
Name: ING 16: SEPARATE ACCIDENTALLY BONDED SKIN.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE IRRITANT.
VAPOR IS IRRITATING TO EYES AND MUCOUS MEMBRANES ABOVE TLV. PROLONGED AND
REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE ALLERGIC REACTIONS WITH AS
THMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHAL: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. CYANOACRYLATE
ADHESIVE IS VERY FAST SETTING & STRONG ADHESIVE. IT BONDS HUMAN TISS INCL
SKIN IN SECONDS. EXPERIENCE HAS SHOWN THAT ACCIDENTS DUE TO C YANOACRYLATES
ARE HANDLED BEST BY PASSIVE, NONSURGICAL FIRST AID. TREATMENT OF SPECIFIC
TYPES OF ACCIDENTS ARE: SKIN ADHESION: FIRST IMMERSE BONDED SURFS IN WARM
SOAPY WATER. PEEL OR ROLL (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE. SOAK UP WITH AN INERT
ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: POLYMERIZE AS ABOVE. INCINERATE IN ACCORDANCE WITH EPA,
FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE AT OR BELOW 75F TO MAXIMIZE SHELF LIFE.
Other Precautions: AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPORS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: POLYETHYLENE. DO NOT USE COTTON GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EMERGENCY EYE WASH FOUNTAIN & DELUGE
SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRST AID PROC: SURFS APART W/AID OF BLUNT
EDGE, EG SPATULA/TSP HANDLE; THEN REMOVE ADHESIVE FROM SKIN W/SOAP &
WATER. DO NOT TRY TO PULL SURFS APART W/DIRECT OPPOSING ACTION. EYELID TO
EYELID OR EYEB ALL ADHESION: IF EYELIDS STUCK TOGETHEROR BONDED TO EYEBALL,
WASH THORO W/WARM WATER & APPLY GAUZE PATCH. EYE
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >300F,>149C
Vapor Pres: <0.2 @ 75F
Vapor Density: APPROX 3
Spec Gravity: 1.09 @ 75F
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: CLEAR LIQUID; SHARP IRRITATING ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES,
ALKALIES.
Hazardous Decomposition Products: BY FIRE OR THERMAL DECOMPOSITION: IRRITATING
ORGANIC FRAGMENTS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: SUPERBONDER 496 INSTANT ADHESIVE, 49661
Company: LOCTITE CORP
Street: 705 N MT RD
City: NEWINGTON CT
Zipcode: 06111
Health Emergency Phone: 203-278-1280
Label Required IND: Y
Date Of Label Review: 07/20/1995
Status Code: C
Label Date: 07/20/1995
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: ACUTE: BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE
IRRITANT. VAPOR IS IRRITATING TO EYES AND MUCOUS MEMBRANES ABOVE TLV.
PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE ALLERGIC REACTIONS
WITH ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS. CHRONIC: NONE LISTED BY
MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.