LIQUID CARBONIC INDUSTRIES COR -- CARBON DIOXIDE
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Material Safety Data Sheet
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NIIN: 00-682-6841
MSDS Num: CCCBS
MSDS NAME: CARBON DIOXIDE
Responsible Party
Name: LIQUID CARBONIC INDUSTRIES CORP
Address: 810 JORIE BLVD
City: HINSDALE IL 60521
Info Phone: 708-572-7000
Emergency Phone Number: 708-572-7000/800-424-9300(CHEMTREC)
Preparer's Name: UNKNOWN
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LIQUID CARBONIC INDUSTRIES CORP
Address: 810 JORIE BLVD
City: HINSDALE IL 60521-2216
Phone: 708-572-7000
Name: NAPA, A DIVISION OF LINCOLN AUTOMOTIVE
Address: ONE LINCOLN WAY
City: ST. LOUIS MO 63120-1578
Phone: 414-255-5520
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Item Description Information
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Unit of Issue: LB
UI Container Qty: 0
Type of Container: METAL
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Ingredients
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Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE
% Wt: >99.5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 5000 PPM
ACGIH TLV: 5000PPM/30000STEL;96
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Health Hazards Data
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LD50 LC50 Mixture: TLV IS 5000 PPM.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TARGET ORGANS:LUNGS, HEART, CNS, EYES. ACUTE- GAS MAY
CAUSE EYE IRRITATION. ASPHYXIANT. INHALATION MAY CAUSE RESPIRATORY ACIDOSIS.
HIGH CONCENTRATIONS MAY CAUSE RAPID CIRCULATORY INSUFFICIENCY LEADING TO
DEATH. INGESTION UNLIKELY. CHRONIC-UNKNOWN.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, HEADACHE, DROWSINESS,
DIZZINESS, STINGING OF THE EYES, NOSE AND THROAT, EXCITATION, RAPID BREATHING
AND HEART RATE, EXCESS SALIVATION, SHORTNESS OF BREATH, MUSCULAR WEAKNESS,
RINGING IN TH E EAR, UNCONSCIOUSNESS, COMA, NAUSEA, VOMITING, WATERY EYES
(FORMATION OF WEAK CABONIC ACID)
Medical Cond Aggravated By Exposure: PERSONNEL WITH PRE-EXISTING CHRONIC
RESPIRATORY DISEASES OR HEART DISORDERS SHOULD REFRAIN FROM BREATHING
EXCESSIVE CARBON DIOXIDE.
First Aid: INHALATION:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
EYES:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEE AN
OPHTHALMOLOGIST. SKIN:UNLIKELY. PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL
CASES OF OVEREXPOSURE TO CARBON DIOXIDE. RESCUE PERSONNEL SHOULD BE EQUIPPED
WITH SELF CONTAINED BREATHING APPARATUS. ORAL:UNLIKELY.
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Handling and Disposal
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Spill Release Procedures: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. VENTILATE
AREA OF LEAK WITH EXTRA FANS. CARBON DIOXIDE IS HEAVIER THAN AIR AND WILL
COLLECT IN LOW AREAS. CLEAN UP PERSONNEL SHOULD WEAR SELF-CONTAINED BREAT
HING APPARATUS TO ENTER LEAKING CYLINDER AREA.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: SLOWLY RELEASE INTO ATMOSPHERE OUTDOORS. DISPOSAL
SHOULD BE IN COMPLIANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
DEFECTIVE CYLINDERS SHOULD BE TAGGED TO INDICATE A DEFECT.
Handling And Storage Precautions: STORE IN A COOL, WELL-VENTILATED PLACE. NEVER
WORK ON A PRESSURIZED SYSTEM. IF THERE IS A LEAK, CLOSE THE CYLINDER VALVE
AND BLOW DOWN THE SYSTEM.
Other Precautions: KEEP AWAY FROM SOURCES OF HEAT. CAUTION! CAN CAUSE RAPID
SUFFOCATION DUE TO OXYGEN DEFICIENCY. USE WITH ADEQUATE VENTILATION. CO2 IS
HEAVIER THAN AIR AND TENDS TO ACCUMULATE NEAR THE FLOOR IN CLOSED S PACES.
READ ALL LABEL INSTRUCTIONS.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Extinguishing Media: CARBON DIOXIDE CANNOT CATCH FIRE. USE WATER FOG, CARBON
DIOXIDE, FOAM, OR DRY CHEMICAL FOR SURROUNDING FIRE.
Fire Fighting Procedures: WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
NIOSH-APPROVED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY. EVACUATE AREA.
Unusual Fire/Explosion Hazard: CYLINDERS MAY EXPLODE DUE TO HEAT OF FIRE.
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Control Measures
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Respiratory Protection: NONE REQUIRED UNDER NORMAL USE. HOWEVER, AIR-SUPPLIED
RESPIRATORS ARE REQUIRED WHILE WORKING IN CONFINED SPACES WITH THIS PRODUCT.
THE RESPIRATORY PROTECTION USE MUST CONFORM WITH OSHA RULES AS SPECIF IED IN
29 CFR 1910.134.
Ventilation: SUFFICIENT TO PREVENT ACCUMULATION ABOVE TLV. LOCAL EXHAUST
LOCATED NEAR THE FLOOR.
Protective Gloves: COTTON OR LEATHER
Eye Protection: SAFETY GOGGLES/GLASSES
Other Protective Equipment: EYE WASH STATION, SAFETY SHOWER, INDUSTRIAL-TYPE
WORK CLOTHING, SAFETY SHOES AND APRON AS REQUIRED.
Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
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Physical/Chemical Properties
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HCC: G3
NRC/State LIC No: NOT RELEVANT
B.P. Text: -109F SUBLI
M.P/F.P Text: -70F@3929MM
Decomp Text: UNKNOWN
Vapor Pres: 44255 @70F
Vapor Density: 1.65
Spec Gravity: 1.10 @ -35F
PH: ACIDIC
Viscosity: NOT RELEVANT
Evaporation Rate & Reference: NOT RELEVANT
Solubility in Water: VERY SOLUBLE
Appearance and Odor: COLORLESS, SLIGHT PUNGENT ODOR
Percent Volatiles by Volume: 100
Corrosion Rate: UNKNOWN
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: OVERHEATING CYLINDERS
Materials To Avoid: MATERIALS THAT REACT WITH CABONIC ACID SUCH AS ALKALIES,
REACTIVE METALS (SODIUM, POTASSIUM, MAGNESIUM) & THEIR HYDRIDES
Hazardous Decomposition Products: CAN DECOMPOSE TO CARBON MONOXIDE AND OXYGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 82188
MSDS NAME: CARBON DIOXIDE
MSDS Prepared Date: 04/01/1994
Review Date: 11/05/1996
Radioactivity: NOT RELEVANT
Net Unit Weight: 50 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: LB
Container QTY: 0
Type Of Container: METAL
Additional Data: THE UN ID NUMBER, PER MSDS.
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Detail DOT Information
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DOT PSN Code: CUX
DOT Proper Shipping Name: CARBON DIOXIDE
Hazard Class: 2.2
UN ID Num: UN1013
Label: NONFLAMMABLE GAS
Packaging Exception: 306
Non Bulk Pack: 302,304
Bulk Pack: 302,314,315
Max Qty Pass: 75 KG
Max Qty Cargo: 150 KG
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: DOH
IMO Proper Shipping Name: CARBON DIOXIDE
IMDG Page Number: 2111
UN Number: 1013
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-09
MED First Aid Guide NUM: 615
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Detail IATA Information
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IATA PSN Code: FHH
IATA UN ID Num: 1013
IATA Proper Shipping Name: CARBON DIOXIDE +
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 200
Max Quant Pass: 75KG
Max Quant Cargo: 150KG
Packaging Note Cargo: 200
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Detail AFI Information
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AFI PSN Code: FHH
AFI Proper Shipping Name: CARBON DIOXIDE
AFI Hazard Class: 2.2
AFI UN ID NUM: UN1013
Special Provisions: P5
Back Pack Reference: A6.3,A6.5,A6.6
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HAZCOM Label
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MSDS NAME: CARBON DIOXIDE
Company: LIQUID CARBONIC INDUSTRIES CORP
Street: 810 JORIE BLVD
City: HINSDALE IL
Zipcode: 60521-2216
Health Emergency Phone: 708-572-7000/800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 11/05/1996
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 11/05/1996
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS:LUNGS, HEART, CNS, EYES. ACUTE- MAY CAUSE
EYE IRRITATION. ASPHYXIANT. INHALATION MAY CAUSE RESPIRATORY ACIDOSIS. HIGH
CONCENTRATIONS MAY CAUSE RAPID CIRCULATORY INSUFFICIENCY LEADING TO DEATH.
INGESTION UNLIKELY. CHRONIC- UNKNOWN. STORE IN COOL, VENTILATED PLACE. IF
LEAKING, VENTILATE AREA. USE EXTRA FANS. FIRST AID- INHALED:REMOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLU SH WITH WATER FOR 15 MINUTES.
CONSULT PHYSICIAN. SKIN:UNLIKELY. PROMPT MEDICAL ATTENTION IS MANDATORY IN
ALL CASES OF OVEREXPOSURE TO CARBON DIOXIDE. RESCUE PERSONNEL SHOULD BE
EQUIPPED WITH SELF CONT AINED BREATHING APPARATUS. ORAL:UNLIKELY.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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